Two nanocage anionic metal–organic frameworks with rht topology and {[M(H2O)6]6}12+ charge aggregation for rapid and selective adsorption of cationic dyes

Two new VMOPs with cuboctahedral geometries were synthesized based on [V6O6(OCH3)9X] (X = VO4 or SO4) and the rigid tridentate carboxylate ligand H3TATB, which present selective adsorption toward cationic dyes in aqueous solution.

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Selective adsorption and separation of illegal cationic dyes from foodstuffs with anionic polyelectrolyte functionalised metal-organic frameworks

Food Additives & Contaminants Part A ◽

10.1080/19440049.2018.1492154 ◽

2018 ◽

Vol 35 (10) ◽

pp. 1870-1880 ◽

Cited By ~ 2

Author(s):

Xue Wang ◽

Hui-Ling Duan ◽

Shi-Yao Ma ◽

Jun Wang ◽

Han-Ying Zhan ◽

...

Keyword(s):

Selective Adsorption ◽

Metal Organic Frameworks ◽

Cationic Dyes ◽

Anionic Polyelectrolyte ◽

Metal Organic

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Metallocycle-Supported POM-Based Metal-Organic Frameworks Assembled from Isomeric N-Rich Ligands: Structures and Selective Adsorption and Separation of Cationic Dyes

European Journal of Inorganic Chemistry ◽

10.1002/ejic.201900086 ◽

2019 ◽

Vol 2019 (13) ◽

pp. 1839-1846 ◽

Cited By ~ 4

Author(s):

Lei Liu ◽

Hai-Yan Zhang ◽

Hai-Jun Wang ◽

Song Chen ◽

Jing-Han Wang ◽

...

Keyword(s):

Selective Adsorption ◽

Metal Organic Frameworks ◽

Cationic Dyes ◽

Metal Organic

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Selective adsorption of cationic dyes from aqueous solution by polyoxometalate-based metal–organic framework composite

Applied Surface Science ◽

10.1016/j.apsusc.2015.11.151 ◽

2016 ◽

Vol 362 ◽

pp. 517-524 ◽

Cited By ~ 98

Author(s):

Xiaoxia Liu ◽

Wenpeng Gong ◽

Jing Luo ◽

Chentao Zou ◽

Yun Yang ◽

...

Keyword(s):

Aqueous Solution ◽

Selective Adsorption ◽

Metal Organic Framework ◽

Cationic Dyes ◽

Metal Organic ◽

Organic Framework

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Highly sensitive detection of nitrobenzene by a series of fluorescent 2D zinc(ii) metal–organic frameworks with a flexible triangular ligand

RSC Advances ◽

10.1039/d1ra03737d ◽

2021 ◽

Vol 11 (39) ◽

pp. 23975-23984

Author(s):

Xue Yang ◽

Yixia Ren ◽

Hongmei Chai ◽

Xiufang Hou ◽

Zhixiang Wang ◽

...

Keyword(s):

Aqueous Solution ◽

Metal Organic Frameworks ◽

High Sensitivity ◽

Fluorescent Sensors ◽

Sensitive Detection ◽

Donor Ligands ◽

Highly Sensitive ◽

Metal Organic ◽

Highly Sensitive Detection

Four fluorescent 2D Zn-MOFs based on a flexible triangular ligand and linear N-donor ligands are hydrothermally prepared and used to detect nitrobenzene in aqueous solution with high sensitivity, demonstrating their potential as fluorescent sensors.

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Adsorption of organic compounds from aqueous solution by pyridine-2-carboxaldehyde grafted MIL-101(Cr)-NH2 metal-organic frameworks

Journal of Environmental Chemical Engineering ◽

10.1016/j.jece.2021.105275 ◽

2021 ◽

pp. 105275

Author(s):

Malcom Frimpong Dapaah ◽

Baojian Liu ◽

Liang Cheng

Keyword(s):

Aqueous Solution ◽

Organic Compounds ◽

Metal Organic Frameworks ◽

Metal Organic

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Synthesis of metal–organic frameworks (MOFs) MIL-100(Fe) functionalized with thioglycolic acid and ethylenediamine for removal of eosin B dye from aqueous solution

SN Applied Sciences ◽

10.1007/s42452-021-04163-w ◽

2021 ◽

Vol 3 (1) ◽

Author(s):

Adedibu C. Tella ◽

Janet T. Bamgbose ◽

Vincent O. Adimula ◽

Mary Omotoso ◽

Sunday E. Elaigwu ◽

...

Keyword(s):

Aqueous Solution ◽

Thioglycolic Acid ◽

Metal Organic Frameworks ◽

Thiol Group ◽

Spectroscopic Techniques ◽

Base Interaction ◽

Adsorption Capacities ◽

Melting Point Analysis ◽

Eosin B ◽

Metal Organic

AbstractThe interaction of eosin B dye from aqueous solution with MIL-100(Fe) and functionalized MIL-100(Fe) metal–organic frameworks (MOFs) is reported in this study. MIL-100(Fe) was prepared and functionalized with thioglycolic acid (TH) and ethylenediammine (ED) separately by incorporating the thiol (–SH) and the amine (–NH2) group of the functionalizing agents into the open metal sites of the MIL-100(Fe) to obtain the acidic (TH-MIL-100) and basic (ED-MIL-100) forms of the MOF respectively. Characterization of the MOFs was done by melting point analysis, elemental analysis, spectroscopic techniques, scanning electron microscopy (SEM), and powdered X-ray diffraction (PXRD) analysis. The adsorption experiments were carried out at different conditions such as pH, adsorbent dosage, contact time, temperature, and initial concentration of the dye to estimate the optimum conditions and the maximum adsorption capacities. Adsorption capacities were observed to increase in the order of ED-MIL-100 < MIL-100 < TH-MIL-100, while the TH-MIL-100 was the most effective in the removal process due to acid–base interaction between the acidic thiol group (–SH) and the alkaline medium of eosin B dye solution. The Langmuir Isotherm was seen to fit well to adsorption data obtained for all three adsorbent materials studied, and adsorption processes followed the pseudo-second order kinetics. This study, therefore, indicates the suitability of functionalization of MIL-100(Fe) towards improving its adsorption capacity.

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3D Ln-MOFs as multi-responsive luminescent probe for efficient sensing of Fe3+, Cr2O72‒, and antibiotics in aqueous solution

CrystEngComm ◽

10.1039/d1ce00399b ◽

2021 ◽

Author(s):

Yuanshan Xue ◽

Ji Ding ◽

Dan-Ling Sun ◽

Weiwei Cheng ◽

Xuanrong Chen ◽

...

Keyword(s):

Aqueous Solution ◽

Metal Organic Frameworks ◽

Luminescent Probe ◽

Metal Organic ◽

Lanthanide Metal

Two families of lanthanide metal-organic frameworks (Ln-MOFs), namely {[Ln2L2(DMF)4]·xDMF·yH2O}n (Ln = Ce(1), Pr(2), Sm(3), Eu(4), Gd(5); x = 0,1; y = 0,1), and {[Ln2L2(H2O)2.5]}n (Ln = Dy(6), Ho(7)), have been...

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