Multifunctional and robust covalent organic framework–nanoparticle hybrids

2014 ◽  
Vol 2 (21) ◽  
pp. 7944-7952 ◽  
Author(s):  
Pradip Pachfule ◽  
Manas K. Panda ◽  
Sharath Kandambeth ◽  
S. M. Shivaprasad ◽  
David Díaz Díaz ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Coupling Reactions ◽  
Heck Coupling ◽  
Covalent Organic Framework ◽  
Acidic Conditions ◽  
Biaryl Synthesis ◽  
Supported Pd ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

Highly stable COF supported Pd(0) and Pd(ii) nanoparticles (i.e.Pd(0)@Tppa-1 and Pd(ii)@TpPa-1) have been synthesized. Pd(0)@TpPa-1 serves as a robust and efficient heterogeneous catalyst for copper free Sonogashira and Heck coupling reactions under basic conditions, whereas Pd(ii)@TpPa-1 satisfactorily catalyzes intramolecular oxidative biaryl synthesis under acidic conditions.

A new superacid hafnium-based metal–organic framework as a highly active heterogeneous catalyst for the synthesis of benzoxazoles under solvent-free conditions

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Highly Active ◽  
Solvent Free Conditions ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.

scholarly journals Sulfonic acid functionalized metal–organic framework (S-IRMOF-3): a novel catalyst for sustainable approach towards the synthesis of acrylonitriles

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 15749-15762 ◽  
Author(s):  
Ryhan Abdullah Rather ◽  
Zeba N. Siddiqui
Keyword(s):  
Reaction Time ◽  
Heterogeneous Catalyst ◽  
Sulfonic Acid ◽  
Metal Organic Framework ◽  
High Yield ◽  
Time Period ◽  
Metal Organic ◽  
Novel Catalyst ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

Sulfonic acid functionalized metal–organic framework (S-IRMOF-3) as an efficient heterogeneous catalyst has been synthesized and employed for sustainable approach towards the synthesis of acrylonitriles in high yield and shorter reaction time period.

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