Synthesis of high-silica AEI zeolites with enhanced thermal stability by hydrothermal conversion of FAU zeolites, and their activity in the selective catalytic reduction of NOx with NH3

2015 ◽  
Vol 3 (2) ◽  
pp. 857-865 ◽  
Author(s):  
Takushi Sonoda ◽  
Toshihiro Maruo ◽  
Yoshitaka Yamasaki ◽  
Nao Tsunoji ◽  
Yasuyuki Takamitsu ◽  
...  

Cu-loaded AEI catalysts with different P/Al ratios showed a good catalytic performance for NH3-SCR of NOx.

2016 ◽  
Vol 6 (17) ◽  
pp. 6688-6696 ◽  
Author(s):  
Zhiming Liu ◽  
Yuxian Liu ◽  
Biaohua Chen ◽  
Tianle Zhu ◽  
Lingling Ma

The redox cycle (Ce4+ + Fe2+ ↔ Ce3+ + Fe3+) over the Fe–Ce–Ti catalyst contributes to the activation of NOx and NH3 and thus the formation of reaction intermediates, leading to the high catalytic performance for the NH3-SCR of NOx.


Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 55
Author(s):  
Katarzyna Świrk ◽  
Ye Wang ◽  
Changwei Hu ◽  
Li Li ◽  
Patrick Da Costa ◽  
...  

Copper and iron promoted ZrO2 catalysts were prepared by one-pot synthesis using urea. The studied catalysts were characterized by XRD, N2 physisorption, XPS, temperature-programmed desorption of NH3 (NH3-TPD), and tested by the selective catalytic reduction by ammonia (NH3-SCR) of NO in the absence and presence of water vapor, under the experimental conditions representative of exhaust gases from stationary sources. The influence of SO2 on catalytic performance was also investigated. Among the studied catalysts, the Fe-Zr sample showed the most promising results in NH3-SCR, being active and highly selective to N2. The addition of SO2 markedly improved NO and NH3 conversions during NH3-SCR in the presence of H2O. The improvement in acidic surface properties is believed to be the cause.


RSC Advances ◽  
2015 ◽  
Vol 5 (127) ◽  
pp. 104923-104931 ◽  
Author(s):  
Jixing Liu ◽  
Weiyu Song ◽  
Chi Xu ◽  
Jian Liu ◽  
Zhen Zhao ◽  
...  

A series of Cu/ZSM-5/SAPO-34 composite catalysts with varying ZSM-5 mass fraction were synthesized using a pre-seed method, and their catalytic performances were tested for selective catalytic reduction (SCR) of NO with NH3.


Rare Metals ◽  
2018 ◽  
Vol 38 (4) ◽  
pp. 292-298 ◽  
Author(s):  
Xun-Zhe Shao ◽  
Hong-You Wang ◽  
Meng-Long Yuan ◽  
Jie Yang ◽  
Wang-Cheng Zhan ◽  
...  

2020 ◽  
Vol 10 (10) ◽  
pp. 3450-3457
Author(s):  
Kang Zheng ◽  
Zhiyuan Zhou ◽  
Yongzhao Wang ◽  
Zhiling Xin ◽  
Zhiliang Zhao ◽  
...  

We report a facile method for dispersing Mn species onto two-dimensional Co3O4 nanosheets at the nanoscale for the selective catalytic reduction (SCR) of NOx with NH3.


RSC Advances ◽  
2017 ◽  
Vol 7 (39) ◽  
pp. 24177-24187 ◽  
Author(s):  
Haidi Xu ◽  
Mengmeng Sun ◽  
Shuang Liu ◽  
Yuanshan Li ◽  
Jianli Wang ◽  
...  

The calcined temperature of the carrier obviously affected SCR activity of catalysts, WO3/Ce0.68Zr0.32O2-500 showed the best low-temperature NH3-SCR activity due to its more Lewis acid sites and stronger redox property.


2018 ◽  
Vol 8 (12) ◽  
pp. 2430 ◽  
Author(s):  
Xinbo Zhu ◽  
Yaolin Wang ◽  
Yu Huang ◽  
Yuxiang Cai

In this work, a series of Ce-W-Ti catalysts were synthesized using a solution combustion method for the selective catalytic reduction (SCR) of NO with NH3 at low temperatures. The reaction performance of NH3-SCR of NO was significantly improved over the Ce-W-Ti catalysts compared to Ce0.4Ti and W0.4Ti catalysts, while Ce0.2W0.2Ti showed the best activity among all the samples. The Ce0.2W0.2Ti catalyst exhibited over 90% removal of NO and 100% N2 selectivity in the temperature range of 250–400 °C at a gas hourly space velocity (GHSV) of 120,000 mL·g−1·h−1. The Ce-W-Ti catalysts were characterized using N2 adsorption-desorption, X-ray diffraction, X-ray photoelectron spectrometry and temperature programmed desorption of NH3 to establish the structure-activity relationships of the Ce-W-Ti catalysts. The excellent catalytic performance of the Ce0.2W0.2Ti catalyst could be associated with the larger specific surface area, highly dispersed Ce and W species, increased amount of surface adsorbed oxygen (Oads) and enhanced total acidity on the catalyst surfaces.


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