Size-dependent electronic structure controls activity for ethanol electro-oxidation at Ptn/indium tin oxide (n = 1 to 14)

2015 ◽  
Vol 17 (27) ◽  
pp. 17601-17610 ◽  
Author(s):  
Alexander von Weber ◽  
Eric T. Baxter ◽  
Sebastian Proch ◽  
Matthew D. Kane ◽  
Michael Rosenfelder ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Binding Energy ◽  
High Activity ◽  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Cluster Size ◽  
Core Level ◽  
Size Dependent ◽  
Electro Oxidation ◽  
Core Level Binding Energy

Activity of small Ptn clusters on ITO is strongly dependent on cluster size, and anti-correlated with the Pt 4d core level binding energy, demonstrating that electron-rich Pt clusters are required for high activity.

scholarly journals Surface core-level binding energy shifts for MgO(100)

2014 ◽  
Vol 16 (40) ◽  
pp. 21953-21956 ◽  
Author(s):  
Connie J. Nelin ◽  
Felix Uhl ◽  
Volker Staemmler ◽  
Paul S. Bagus ◽  
Yuichi Fujimori ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Binding Energy ◽  
Core Level ◽  
Experimental Results ◽  
Surface Electronic Structure ◽  
Core Level Binding Energy

Theoretical and experimental results for the surface core-level binding energy, BE, shifts, SCLS, for MgO(100) are presented and the anomalous O(1s) SCLS is interpreted in terms of the surface electronic structure.

Origin of the Ba core-level binding-energy difference between tetragonal and orthorhombicYBa2Cu3O7−δ

1991 ◽  
Vol 43 (4) ◽  
pp. 3695-3698 ◽  
Author(s):  
F. Parmigiani ◽  
G. Pacchioni ◽  
C. R. Brundle ◽  
D. E. Fowler ◽  
P. S. Bagus
Keyword(s):  
Binding Energy ◽  
Energy Difference ◽  
Core Level ◽  
Binding Energy Difference ◽  
Core Level Binding Energy

Core level binding energy shifts for reconstructed GaAs(001) surfaces

Physica B+C ◽  
1983 ◽  
Vol 117-118 ◽  
pp. 822-824 ◽  
Author(s):  
J.F. van der Veen ◽  
L. Smit ◽  
P.K. Larsen ◽  
J.H. Neave
Keyword(s):  
Binding Energy ◽  
Core Level ◽  
Core Level Binding Energy

scholarly journals Effect of electron correlation in the decomposition of core level binding energy shifts into initial and final state contributions

2019 ◽  
Vol 21 (18) ◽  
pp. 9399-9406 ◽  
Author(s):  
Marc Figueras ◽  
Carmen Sousa ◽  
Francesc Illas
Keyword(s):  
Binding Energy ◽  
Electron Correlation ◽  
Photoelectron Spectroscopy ◽  
Core Level ◽  
Final State ◽  
X Ray ◽  
Core Level Binding Energy

The influence of electron correlation into the decomposition of core level binding energy shifts, measured by X-ray photoelectron spectroscopy (XPS), into initial and final effects is analysed for a series of molecules where these effects are noticeable.

Core level binding energy shifts of K and Cs adlayers on Ru(001)

1989 ◽  
Vol 210 (3) ◽  
pp. L185-L192 ◽  
Author(s):  
T.K. Sham ◽  
G.-Q. Xu ◽  
J. Hrbek ◽  
M.-L. Shek
Keyword(s):  
Binding Energy ◽  
Core Level ◽  
Core Level Binding Energy

Surface core-level binding energy shifts in alloys

1981 ◽  
Vol 39 (9) ◽  
pp. 987-989 ◽  
Author(s):  
V. Kumar ◽  
D. Tománek ◽  
K.H. Bennemann
Keyword(s):  
Binding Energy ◽  
Core Level ◽  
Core Level Binding Energy
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