An ionic charge-transfer dyad prepared cost-effectively from a tetrathiafulvalene carboxylate anion and a TMPyP cation

The assembly of a simple ionic supramolecular system would be a cost-effective way to construct donor–acceptor ensembles and the strong anion–cation interaction can enhance the charge-transfer between them.

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Nonconjugated Triptycene-Spaced Donor–Acceptor-Type Emitters Showing Thermally Activated Delayed Fluorescence via Both Intra- and Intermolecular Charge-Transfer Transitions

ACS Applied Materials & Interfaces ◽

10.1021/acsami.1c05646 ◽

2021 ◽

Author(s):

Gaole Dai ◽

Ming Zhang ◽

Kai Wang ◽

Xiaochun Fan ◽

Yizhong Shi ◽

...

Keyword(s):

Charge Transfer ◽

Delayed Fluorescence ◽

Thermally Activated Delayed Fluorescence ◽

Thermally Activated ◽

Intermolecular Charge Transfer ◽

Charge Transfer Transitions ◽

Donor Acceptor

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Ultrafast Charge Transfer and Relaxation at a Donor–Acceptor Interface

The Journal of Physical Chemistry B ◽

10.1021/acs.jpcb.1c03595 ◽

2021 ◽

Author(s):

Fernando Rodríguez Díaz ◽

Hong-Guang Duan ◽

R. J. Dwayne Miller ◽

Michael Thorwart

Keyword(s):

Charge Transfer ◽

Donor Acceptor ◽

Ultrafast Charge Transfer

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Ultrafast broadband laser spectroscopy reveals energy and charge transfer in novel donor-acceptor triads for photovoltaic applications

Journal of Physics Conference Series ◽

10.1088/1742-6596/276/1/012006 ◽

2011 ◽

Vol 276 ◽

pp. 012006 ◽

Cited By ~ 8

Author(s):

T Roland ◽

G Hernandez Ramirez ◽

J Léonard ◽

S Méry ◽

S Haacke

Keyword(s):

Charge Transfer ◽

Laser Spectroscopy ◽

Broadband Laser ◽

Photovoltaic Applications ◽

Donor Acceptor

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Design of rigid donor-acceptor systems with a low-lying charge-transfer state: an INDO model study of barrelene-based compounds

The Journal of Physical Chemistry ◽

10.1021/j100146a014 ◽

1993 ◽

Vol 97 (44) ◽

pp. 11420-11426 ◽

Cited By ~ 7

Author(s):

Thomas Fox ◽

Manfred Kotzian ◽

Notker Roesch

Keyword(s):

Charge Transfer ◽

Charge Transfer State ◽

Model Study ◽

Donor Acceptor ◽

Transfer State

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Theoretical study on the charge transfer mechanism at donor/acceptor interface: Why TTF/TCNQ is inadaptable to photovoltaics?

The Journal of Chemical Physics ◽

10.1063/1.4972005 ◽

2016 ◽

Vol 145 (24) ◽

pp. 244705 ◽

Cited By ~ 11

Author(s):

Shuang-Bao Li ◽

Yun Geng ◽

Yu-Ai Duan ◽

Guang-Yan Sun ◽

Min Zhang ◽

...

Keyword(s):

Charge Transfer ◽

Theoretical Study ◽

Transfer Mechanism ◽

Charge Transfer Mechanism ◽

Donor Acceptor

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The driving force for solute retention in electron donor-acceptor chromatography: Electrostatic versus charge-transfer interactions

Chromatographia ◽

10.1007/bf02466644 ◽

1998 ◽

Vol 48 (7-8) ◽

pp. 523-528 ◽

Cited By ~ 4

Author(s):

Q. -H. Wan ◽

L. Ramaley ◽

R. Guy

Keyword(s):

Charge Transfer ◽

Electron Donor ◽

Driving Force ◽

Solute Retention ◽

Donor Acceptor

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Charge Transfer in Complexes of the Donor–Acceptor Type

Russian Chemical Reviews ◽

10.1070/rc1976v045n12abeh002761 ◽

1976 ◽

Vol 45 (12) ◽

pp. 1077-1090 ◽

Cited By ~ 17

Author(s):

Oleg Kh Poleshchuk ◽

Yu K Maksyutin

Keyword(s):

Charge Transfer ◽

Donor Acceptor

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Incomplete charge transfer stability of organic donor-acceptor compounds

Physical Review B ◽

10.1103/physrevb.16.5153 ◽

1977 ◽

Vol 16 (12) ◽

pp. 5153-5162 ◽

Cited By ~ 16

Author(s):

B. D. Silverman

Keyword(s):

Charge Transfer ◽

Donor Acceptor

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Homeotropic alignment through charge-transfer-induced columnar mesophase formation in an unsymmetrically substituted triphenylene derivative

Pure and Applied Chemistry ◽

10.1351/pac-con-09-12-17 ◽

2010 ◽

Vol 82 (11) ◽

pp. 1993-2003 ◽

Cited By ~ 13

Author(s):

Juanjuan Li ◽

Zhiqun He ◽

Huan Zhao ◽

Hemant Gopee ◽

Xiangfei Kong ◽

...

Keyword(s):

Charge Transfer ◽

Charge Transfer Complex ◽

X Ray Diffraction ◽

Hexagonal Symmetry ◽

X Ray ◽

Mesophase Formation ◽

Homeotropic Orientation ◽

Donor Acceptor ◽

Homeotropic Alignment ◽

Spectroscopy Optical

An unsymmetrically substituted triphenylene, with two adjacent chloroethoxyethyl lateral flexible chains, was synthesized and characterized. Although this compound showed no mesomorphic behavior, it formed a donor–acceptor charge-transfer complex with 2,4,7-trinitrofluorenone (TNF). The resulting 1:1 complex has been investigated using UV–vis and IR spectroscopy, optical microscopy, thermal analysis, and X-ray diffraction. A columnar mesophase with hexagonal symmetry was found. More interestingly, this charge-transfer complex can be easily aligned on a glass surface in a homeotropic orientation, which is stable at room temperature (RT) and over a wide temperature range.

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