Spectroscopy of the Mirror Instability Growth Rate in Hollow Electrodes Discharge (HED) Plasma

In this work, an experimental study was conducted about the effect of gas pressure on the growth rate of the mirror instability produced in hollow electrodes discharge (HED) plasma in two regions: inter-electrodes gap and internal cathode cavity, by optical emission spectroscopy. Optical emission spectroscopy measurements, at different gas pressures in two regions under study, show that the electron number density (ne) increase with increasing gas pressure from 0.04 to 0.2 Torr. While the electron temperature (Te) decrease with increased gas pressure. In addition, the growth rate increase with increasing electron temperature anisotropy in both regions.

Raman spectroscopy and optical microscopy of medical infusion solutions for parenteral nutrition

Usage of Raman spectroscopy, optical microscopy, and retaining track membranes to find 20% SMOFlipid microparticles with a diameter of 5 to 10 μm and to prevent complications that arise during parenteral nutrition.

Enhancing the photoluminescence response from thick Ge-on-Si layers using the photonic crystals

More than an order of magnitude enhancement of the room-temperature photoluminescence (PL) signal from rather thick Ge layers grown on Si(001) was obtained by utilization of the two-dimensional photonic crystals (PhC). A set of PhCs with different periods and filling factors was fabricated and studied using a micro-PL spectroscopy. Optical features of the fabricated PhCs were also theoretically modeled using a rigorously coupled wave analysis which allowed to bring the observed peaks in the PL response into correlation with the different modes of PhC. In particular, we were able to associate the well-resolved peaks in the PL spectra with the optically active modes of the PhCs. The obtained results proved the possibility of using a homogeneously distributed active medium in PhCs without the formation of specially designed cavities in order to redistribute the internal emitted light into the required modes and efficiently extract it to the far field. The relative simplicity and higher tolerance to fabrication imperfections, as well as the large working area of such kind of PhCs as compared to PhCs with microcavities can be advantageous for creating a PhC-based Si-compatible light source for the telecom band.

Advancement in Salmonella Detection Methods: From Conventional to Electrochemical-Based Sensing Detection

Large-scale food-borne outbreaks caused by Salmonella are rarely seen nowadays, thanks to the advanced nature of the medical system. However, small, localised outbreaks in certain regions still exist and could possess a huge threat to the public health if eradication measure is not initiated. This review discusses the progress of Salmonella detection approaches covering their basic principles, characteristics, applications, and performances. Conventional Salmonella detection is usually performed using a culture-based method, which is time-consuming, labour intensive, and unsuitable for on-site testing and high-throughput analysis. To date, there are many detection methods with a unique detection system available for Salmonella detection utilising immunological-based techniques, molecular-based techniques, mass spectrometry, spectroscopy, optical phenotyping, and biosensor methods. The electrochemical biosensor has growing interest in Salmonella detection mainly due to its excellent sensitivity, rapidity, and portability. The use of a highly specific bioreceptor, such as aptamers, and the application of nanomaterials are contributing factors to these excellent characteristics. Furthermore, insight on the types of biorecognition elements, the principles of electrochemical transduction elements, and the miniaturisation potential of electrochemical biosensors are discussed.

Preparation and properties of a novel polystyrene solid-phase fluorescence pH sensor based on a naphthalimide derivative

A novel naphthalimide-based solid-phase fluorescence pH sensor (PS-Acyl-II) is prepared by immobilization of a small molecule probe (II) on polystyrene microspheres through an ester bond and is characterized by Fourier-transform infrared spectroscopy, optical microscope, scanning electron microscope, and conductiometric titrations. The sensor can determine the pH of a solution within the pH 4.0–7.0, free from interference of common metal ions, and can be reused several times. The geometries of II, PS-Acyl-II, and its product with H+ are optimized at the B3LYP/6-31G** level by density functional theory. The charge distribution, orbital interactions, and bonding characteristics are analyzed and compared in detail to discuss the recognition mechanism and structure–fluorescence property relationships.

Synthesis of Ethylenediaminetetraacetic Acid-Functionalized Chitosan Cryogels as Potential Sorbents of Heavy Metal Ions

An original functionalization strategy is proposed here to design chitosan (CS)-based cryogels with ethylenediaminetetraacetic acid (EDTA) moieties. Cryogels with aligned micro-sized tubular structures were further engineered through an unidirectional freezing approach. Attachment of EDTA groups onto CS chains was proved by 1H-RMN and FT-IR spectroscopy. The formation of EDTA-functionalized 3D porous CS-based cryogels was demonstrated by several methods of characterization (FTIR spectroscopy, optical microscopy, SEM, porosity measurements, swelling behavior, copper (II) retention capacity). The sorption tests pointed out the high potential of EDTA-functionalized CS-based cryogels for heavy metal ions retention.

Graphene Oxide-Doped MgO Nanostructures for Highly Efficient Dye Degradation and Bactericidal Action

Various concentrations (0.01, 0.03 and 0.05 wt ratios) of graphene oxide (GO) nanosheets were doped into magnesium oxide (MgO) nanostructures using chemical precipitation technique. The objective was to study the effect of GO dopant concentrations on the catalytic and antibacterial behavior of fixed amount of MgO. XRD technique revealed cubic phase of MgO, while its crystalline nature was confirmed through SAED profiles. Functional groups presence and Mg-O (443 cm−1) in fingerprint region was evident with FTIR spectroscopy. Optical properties were recorded via UV–visible spectroscopy with redshift pointing to a decrease in band gap energy from 5.0 to 4.8 eV upon doping. Electron–hole recombination behavior was examined through photoluminescence (PL) spectroscopy. Raman spectra exhibited D band (1338 cm−1) and G band (1598 cm−1) evident to GO doping. Formation of nanostructure with cubic and hexagon morphology was confirmed with TEM, whereas interlayer average d-spacing of 0.23 nm was assessed using HR-TEM. Dopants existence and evaluation of elemental constitution Mg, O were corroborated using EDS technique. Catalytic activity against methyl blue ciprofloxacin (MBCF) was significantly reduced (45%) for higher GO dopant concentration (0.05), whereas bactericidal activity of MgO against E. coli was improved significantly (4.85 mm inhibition zone) upon doping with higher concentration (0.05) of GO, owing to the formation of nanorods.