Amine modified mesoporous Al2O3@MCM-41: an efficient, synergetic and recyclable catalyst for the formylation of amines using carbon dioxide and DMAB under mild reaction conditions

2016 ◽  
Vol 6 (13) ◽  
pp. 4872-4881 ◽  
Author(s):  
Deepak B. Nale ◽  
Dharitri Rath ◽  
K. M. Parida ◽  
Aravind Gajengi ◽  
Bhalchandra M. Bhanage

A novel amine modified meso Al2O3@MCM-41 catalyst was investigated for the synthesis of formamides from 1°/2° aliphatic as well as aromatic amines with CO2, using DMAB.

RSC Advances ◽  
2020 ◽  
Vol 10 (67) ◽  
pp. 41229-41236
Author(s):  
Jitendra Kumar Yadav ◽  
Priyanka Yadav ◽  
Satish K. Awasthi ◽  
Alka Agarwal

Sulfonic acid functionalized over biguanidine fabricated silica-coated heterogeneous magnetic nanoparticles (NP@SO3H) have been synthesized, well characterized and explored for the first time, as an efficient and recyclable catalyst for N-formylation of primary amines under mild reaction conditions.


2014 ◽  
Vol 4 (6) ◽  
pp. 1608-1614 ◽  
Author(s):  
Deepak B. Nale ◽  
Surjyakanta Rana ◽  
Kulamani Parida ◽  
Bhalchandra M. Bhanage

Covalently linked amine functionalized MCM-41 was investigated as an efficient catalyst for the synthesis of various quinazoline-2,4(1H,3H)-dione derivatives from 2-aminobenzonitriles and carbon dioxide in water.


2011 ◽  
Vol 143 (1) ◽  
pp. 174-179 ◽  
Author(s):  
Marília R. Mello ◽  
Delphine Phanon ◽  
Gleiciani Q. Silveira ◽  
Philip L. Llewellyn ◽  
Célia M. Ronconi

2010 ◽  
Vol 88 (9) ◽  
pp. 964-968 ◽  
Author(s):  
Zhaoqiong Jiang ◽  
Zhiqing Wu ◽  
Lixia Wang ◽  
Di Wu ◽  
Xiangge Zhou

A simple, highly efficient, and environmentally friendly protocol for the synthesis of primary aromatic amines by catalytic coupling of aromatic boronic acids with aqueous ammonia has been developed by using commercial and inexpensive CuSO4·5H2O as catalyst without addition of other solvents under mild reaction conditions.


2011 ◽  
Vol 13 (3) ◽  
pp. 644 ◽  
Author(s):  
Hui Zhou ◽  
Yi-Ming Wang ◽  
Wen-Zhen Zhang ◽  
Jing-Ping Qu ◽  
Xiao-Bing Lu

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