scholarly journals Efficient N-formylation of primary aromatic amines using novel solid acid magnetic nanocatalyst

RSC Advances ◽  
2020 ◽  
Vol 10 (67) ◽  
pp. 41229-41236
Author(s):  
Jitendra Kumar Yadav ◽  
Priyanka Yadav ◽  
Satish K. Awasthi ◽  
Alka Agarwal

Sulfonic acid functionalized over biguanidine fabricated silica-coated heterogeneous magnetic nanoparticles (NP@SO3H) have been synthesized, well characterized and explored for the first time, as an efficient and recyclable catalyst for N-formylation of primary amines under mild reaction conditions.

2010 ◽  
Vol 88 (9) ◽  
pp. 964-968 ◽  
Author(s):  
Zhaoqiong Jiang ◽  
Zhiqing Wu ◽  
Lixia Wang ◽  
Di Wu ◽  
Xiangge Zhou

A simple, highly efficient, and environmentally friendly protocol for the synthesis of primary aromatic amines by catalytic coupling of aromatic boronic acids with aqueous ammonia has been developed by using commercial and inexpensive CuSO4·5H2O as catalyst without addition of other solvents under mild reaction conditions.


2008 ◽  
Vol 59 (10) ◽  
Author(s):  
Carmen Limban ◽  
Alexandru-Vasile Missir ◽  
Ileana Cornelia Chirita ◽  
Corina Ilie ◽  
Miron Teodor Caproiu

Thioureides of 2-(4-methyl-phenoxymethyl)benzoic acid have been synthesised by reaction of 2-(4-methyl-phenoxymethyl)benzoyl isothiocyanate with primary aromatic amines. The mentionated isothiocyanate was obtained in the reaction of the 2-(4-methyl-phenoxymethyl)benzoic acid chloride with ammonium thiocyanate. The acid chloride was prepared by reacting the coresponding acid, the 2-(4-methyl-phenoxymethyl)benzoic acid, with thionyl chloride and the aforementioned acid from potassium para-cresolate with phtalide. The reaction conditions were established to ensure the best yields. These new thioureides have been characterized by means of elemental analysis, IR and NMR spectral studies.


2016 ◽  
Vol 6 (13) ◽  
pp. 4872-4881 ◽  
Author(s):  
Deepak B. Nale ◽  
Dharitri Rath ◽  
K. M. Parida ◽  
Aravind Gajengi ◽  
Bhalchandra M. Bhanage

A novel amine modified meso Al2O3@MCM-41 catalyst was investigated for the synthesis of formamides from 1°/2° aliphatic as well as aromatic amines with CO2, using DMAB.


1983 ◽  
Vol 48 (9) ◽  
pp. 2682-2692 ◽  
Author(s):  
Raul Mocelo ◽  
Jaroslav Kováč

Tertiary 5-nitrofurylamines were prepared by a nucleophilic substitution of 5-nitro-2-furfuryl bromide (I) with aliphatic secondary amines. According to reaction conditions N-(5-nitro-2-furfuryl)-X-phenylamines or their mixture with N,N-di(5-nitro-2-furfuryl)-X-phenylamines were obtained from the reaction of I with substituted primary aromatic amines. Compound I gave with 2-aminophenol a mixture of O- and N-mono- and disubstituted derivatives, and with ethyl salicylate ethyl 2-(5-nitro-2-furfuryloxy)benzoate.


RSC Advances ◽  
2015 ◽  
Vol 5 (20) ◽  
pp. 15274-15282 ◽  
Author(s):  
Forouz Rastegari ◽  
Iraj Mohammadpoor-Baltork ◽  
Ahmad R. Khosropour ◽  
Shahram Tangestaninejad ◽  
Valiollah Mirkhani ◽  
...  

An efficient procedure for the synthesis of isobenzofuran-1(3H)-one derivatives in the presence of [HSO3PMIM]OTf–SiO2@MNPs as a highly recyclable catalyst under solvent-free thermal conditions and MW irradiation is reported.


2021 ◽  
Vol 8 (4) ◽  
pp. 56
Author(s):  
Elias P. Papapanagiotou

Serious alert and border rejection notifications on food contact materials (FCM) retrieved from the RASFF database were analyzed for the first time regarding the period 2012–2019. The findings indicate that China was the main transgressor country for both types of notifications. Official controls were responsible for most FCM serious alerts (91.78%), and border rejection (90.82%) notifications. Another novelty proposed herein, is the criterion for “lag phases” (time from sampling to notification dates). Overall percentage distributions of lag phases, for all RASFF Member States, for the intervals of 0–50 days and 51– ≥ 101 days, were 25.09% and 67.87% for serious alert notifications and 65.21% and 29.34% for serious border rejection notifications. Differences in percent shares of lag phase intervals were observed between the top-four notifying countries, indicating a lack of harmonization in timely reporting of serious alert and border rejection notifications for FCM. Migration of primary aromatic amines and of metals were the most frequently notified hazards overall in the period of analysis. A decreasing trend is observed in the two more recent biannual averages of serious alert notifications for primary aromatic amines and metals, while decreasing for metals but increasing for primary aromatic amines in serious border rejection notifications.


1973 ◽  
Vol 26 (4) ◽  
pp. 827 ◽  
Author(s):  
AM Islam ◽  
AM Khalil ◽  
El-Gawad II Abd

1,2-Diaryl-4-arylmethylene-2-imidazolin-5-ones were prepared by the interaction of primary aromatic amines with 2-aryl-4-arylmethylene-2- oxazolin-5-ones in the presence of acetic acid and sodium acetate. The same imidazolones were also obtained by the cyclization of the arylamides of α-arylamido-β-arylacrylic acids under the same reaction conditions. A possible reaction mechanism was postulated.


1973 ◽  
Vol 26 (8) ◽  
pp. 1701 ◽  
Author(s):  
AM Islam ◽  
AM Khalil ◽  
MS El-Houseni

A facile route for the preparation of 1,2-diaryl-4-arylmethylene-2-imidazolin-5-ones was established by the direct interaction of primary aromatic amines with 2-(m-tolyl)-4-arylmethylene-2-oxazolin-5-ones in acetic acid containing catalytic amounts of sodium acetate. The same imidazolones were also obtained by cyclization of the aryl- carboxamides of α-arylcarboxamido-β-arylacrylic acids under the same reaction conditions. A possible reaction mechanism was discussed.


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