An iron(ii) spin-crossover metallacycle from a back-to-back bis-[dipyrazolylpyridine]
Keyword(s):
Iron(ii) and zinc(ii) complexes of bis[2,6-di(pyrazol-1-yl)pyrid-4-yl]disulfide assemble into tetranuclear metallacycles according to ES-MS, DOSY NMR and conductivity data. The iron complex exhibits a thermal spin-state equilibrium in solution, which the iron centres appear to undergo independently of each other.
Keyword(s):
2014 ◽
Vol 20
(19)
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pp. 5613-5618
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2015 ◽
Vol 22
(1)
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pp. 331-339
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2016 ◽
Vol 18
(40)
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pp. 28307-28315
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Keyword(s):
1976 ◽
Vol 98
(17)
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pp. 5159-5168
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