scholarly journals Substituent effects on fluoride binding by lanthanide complexes of DOTA-tetraamides

2016 ◽  
Vol 45 (7) ◽  
pp. 3070-3077 ◽  
Author(s):  
Octavia A. Blackburn ◽  
Jack D. Routledge ◽  
Laura B. Jennings ◽  
Nicholas H. Rees ◽  
Alan M. Kenwright ◽  
...  

Fluoride binding by lanthanide complexes of a range of DOTA tetraamides changes the magnetic anisotropy at the metal centre from an easy axis to an easy plane.

2018 ◽  
Vol 28 (32) ◽  
pp. 1801846 ◽  
Author(s):  
Mauro Perfetti ◽  
Mikkel A. Sørensen ◽  
Ursula B. Hansen ◽  
Heiko Bamberger ◽  
Samuel Lenz ◽  
...  

2020 ◽  
Vol 818 ◽  
pp. 152902
Author(s):  
E.G. Gerasimov ◽  
P.B. Terentev ◽  
A.F. Gubkin ◽  
H.E. Fischer ◽  
D.I. Gorbunov ◽  
...  

2014 ◽  
Vol 50 (14) ◽  
pp. 1648-1651 ◽  
Author(s):  
Eva Lucaccini ◽  
Lorenzo Sorace ◽  
Mauro Perfetti ◽  
Jean-Pierre Costes ◽  
Roberta Sessoli

The slow relaxation of the magnetization of lanthanide SMMs cannot be directly associated with the nature of magnetic anisotropy.


2010 ◽  
Vol 168-169 ◽  
pp. 138-141
Author(s):  
A.N. Pirogov ◽  
S.G. Bogdanov ◽  
Young Hyun Choi ◽  
E.V. Rozenfeld ◽  
Yong Choi ◽  
...  

The Tm2Fe17 compound has been studied by means of powder neutron diffraction. The compound undergoes a spin-reorientation transition (SRT) of the “easy axis – easy plane” type with increasing temperature from 75 K to 100 K. The SRT is accompanied by a distinct anomaly in the temperature dependencies of the Tm- and Fe-ion magnetizations, significative of large magnetization anisotropy. Using three sublattices model, the parameter of the Tm-Fe interaction and constants of magnetic anisotropy are determined.


1999 ◽  
Vol 562 ◽  
Author(s):  
K. Attenborough ◽  
M. Cerisier ◽  
H. Boeve ◽  
J. De Boeck ◽  
G. Borghs ◽  
...  

ABSTRACTWe have studied the magnetic and structural properties of thin electrodeposited Co and Cu layers grown directly onto (100) n-GaAs and have investigated the influence of a buffer layer. A dominant fourfold anisotropy with a uniaxial contribution is observed in 10 nm Co electrodeposited films on GaAs. An easy axis is observed in the [001] GaAs direction with two hard axes of differing coercivities parallel to the [011] and [011] directions. For thicker films the easy axes in the [001] direction becomes less pronounced and the fourfold anisotropy becomes less dominant. Co films of similar thicknesses deposited onto an electrodeposited Cu buffer layer were nearly isotropic. From X-ray diffraction 21 nm Co layers on GaAs were found to be hcp with the c-axis tending to be in the plane of the film. The anisotropy is ascribed to the Co/GaAs interface and is held responsible for the unique spin-valve properties seen recently in electrodeposited Co/Cu films.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Oana Ciubotariu ◽  
Anna Semisalova ◽  
Kilian Lenz ◽  
Manfred Albrecht

AbstractIn the attempt of implementing iron garnets with perpendicular magnetic anisotropy (PMA) in spintronics, the attention turned towards strain-grown iron garnets. One candidate is Tm3Fe5O12 (TmIG) which possesses an out-of-plane magnetic easy axis when grown under tensile strain. In this study, the effect of film thickness on the structural and magnetic properties of TmIG films including magnetic anisotropy, saturation magnetization, and Gilbert damping is investigated. TmIG films with thicknesses between 20 and 300 nm are epitaxially grown by pulsed laser deposition on substituted-Gd3Ga5O12(111) substrates. Structural characterization shows that films thinner than 200 nm show in-plane tensile strain, thus exhibiting PMA due to strain-induced magnetoelastic anisotropy. However, with increasing film thickness a relaxation of the unit cell is observed resulting in the rotation of the magnetic easy axis towards the sample plane due to the dominant shape anisotropy. Furthermore, the Gilbert damping parameter is found to be in the range of 0.02 ± 0.005.


2019 ◽  
Vol 89 (10) ◽  
pp. 1567
Author(s):  
А.В. Тимофеев ◽  
В.Г. Костишин ◽  
Д.Б. Макеев ◽  
Д.Н. Читанов

Magnetic force microscopy and magnetometry were used to study the magnetic characteristics of pressed nanosized powders BaFe12O19. The powders were obtained by chemical coprecipitation. Magnetic anisotropy of the “easy-plane” type, formed after the pressing operation, was found. The nature of the appearance of anisotropy is discussed.


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