Selective aerobic oxidation of biomass-derived HMF to 2,5-diformylfuran using a MOF-derived magnetic hollow Fe–Co nanocatalyst

2016 ◽  
Vol 18 (10) ◽  
pp. 3152-3157 ◽  
Author(s):  
Ruiqi Fang ◽  
Rafael Luque ◽  
Yingwei Li
Keyword(s):  
Catalytic System ◽  
Aerobic Oxidation ◽  
Cost Effective ◽  
Reaction Conditions ◽  
Highly Efficient ◽  
Selective Aerobic Oxidation

The present work reports a sustainable, cost-effective, and highly efficient catalytic system for directly transforming HMF to DFF that afforded >99% DFF yield under relatively mild reaction conditions.

A New Catalytic System for the Selective Aerobic Oxidation of Large Ring Cycloalkanes to Ketones

2003 ◽  
Vol 7 (3) ◽  
pp. 426-428 ◽  
Author(s):  
Xavier Baucherel ◽  
Isabel W. C. E. Arends ◽  
S. Ellwood ◽  
Roger A. Sheldon
Keyword(s):  
Catalytic System ◽  
Aerobic Oxidation ◽  
Large Ring ◽  
Selective Aerobic Oxidation

Practical organic solvent-free Cu(OAc)2/DMAP/TEMPO-catalyzed aldehyde and imine formation from alcohols under air atmosphere

RSC Advances ◽  
2014 ◽  
Vol 4 (90) ◽  
pp. 48777-48782 ◽  
Author(s):  
Mingyu Guan ◽  
Chao Wang ◽  
Jingyu Zhang ◽  
Yingsheng Zhao
Keyword(s):  
Organic Solvent ◽  
Aerobic Oxidation ◽  
Ambient Air ◽  
Catalyst System ◽  
Solvent Free ◽  
Allylic Alcohols ◽  
Highly Efficient ◽  
Air Atmosphere ◽  
Selective Aerobic Oxidation

A highly efficient and practical organic solvent-free Cu(OAc)2/DMAP/TEMPO catalyst system for the selective aerobic oxidation of benzylic and allylic alcohols to aldehydes and phenones under an ambient air atmosphere was reported.

Efficient and Selective Aerobic Oxidation of Alcohols into Aldehydes and Ketones Using Ruthenium/TEMPO as the Catalytic System

2001 ◽  
Vol 123 (28) ◽  
pp. 6826-6833 ◽  
Author(s):  
Arné Dijksman ◽  
Arturo Marino-González ◽  
Antoni Mairata i Payeras ◽  
Isabel W. C. E. Arends ◽  
Roger A. Sheldon
Keyword(s):  
Catalytic System ◽  
Aerobic Oxidation ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones ◽  
Selective Aerobic Oxidation

scholarly journals LiHSO4/SiO2as a New, Efficient and Reusable Catalytic System for the Chemoselective Conversion of Aldehydes to Acylals under Solvent-Free Conditions

2009 ◽  
Vol 6 (s1) ◽  
pp. S390-S396 ◽  
Author(s):  
Abdolkarim Zare ◽  
Alireza Hasaninejad ◽  
Esmael Rostami ◽  
Ahmad Reza Moosavi-Zare ◽  
Maria Merajoddin ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Acetic Anhydride ◽  
Catalytic System ◽  
Catalytic Amount ◽  
Significant Loss ◽  
Solvent Free ◽  
Reaction Conditions ◽  
Highly Efficient ◽  
Solvent Free Conditions

A highly efficient, green and expeditious solvent-free method is described for the chemoselective conversion of aldehydes to the corresponding acylals in excellent yields, using acetic anhydride in the presence of catalytic amount (20 mol%) of silica-supported LiHSO4. Ketones does not react under these reaction conditions. LiHSO4/SiO2can be recovered and reused without any significant loss of its catalytic activity.

ChemInform Abstract: A 4-MeO-TEMPO, PEG-NO2 and HCl Catalytic System for Highly Efficient Aerobic Oxidation of Alcohols.

ChemInform ◽  
2011 ◽  
Vol 42 (14) ◽  
pp. no-no
Author(s):  
Jianwei Tao ◽  
Qiongqiong Lu ◽  
Changhu Chu ◽  
Renhua Liu ◽  
Xinmiao Liang
Keyword(s):  
Catalytic System ◽  
Aerobic Oxidation ◽  
Highly Efficient ◽  
Oxidation Of Alcohols

Supported task-specific ionic liquid catalyst for highly efficient and recyclable aerobic oxidation of benzyl alcohols

2011 ◽  
Vol 89 (1) ◽  
pp. 68-71 ◽  
Author(s):  
Lin Liu ◽  
Juanjuan Ma ◽  
Zhen Sun ◽  
Jianping Zhang ◽  
Jingjing Huang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Aerobic Oxidation ◽  
Copper Salt ◽  
High Conversion ◽  
Allylic Alcohols ◽  
Benzyl Alcohols ◽  
Highly Efficient ◽  
Silica Supports ◽  
Task Specific Ionic Liquid

A novel catalytic system was prepared by impregnating ionic liquid immobilized 2,2,6,6-tetramethylpiperidyl-1-oxyl (TEMPO) and copper salt onto various silica supports. This catalytic system was capable of rapidly converting different benzylic and allylic alcohols into the corresponding aldehydes under O2 atmosphere with high conversion. Recycling results showed that the catalyst could be easily recovered and reused.

ChemInform Abstract: Efficient and Selective Aerobic Oxidation of Alcohols into Aldehydes and Ketones Using Ruthenium/TEMPO as the Catalytic System.

ChemInform ◽  
2010 ◽  
Vol 32 (44) ◽  
pp. no-no
Author(s):  
Arne Dijksman ◽  
Artuoro Marino-Gonzalez ◽  
Antoni Mairata i Payeras ◽  
Isabel W. C. E. Arends ◽  
Roger A. Sheldon
Keyword(s):  
Catalytic System ◽  
Aerobic Oxidation ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones ◽  
Selective Aerobic Oxidation
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