Conjugated microporous copolymer networks with enhanced gas adsorption

2015 ◽  
Vol 6 (17) ◽  
pp. 3217-3223 ◽  
Author(s):  
Miao Yu ◽  
Xiaoyan Wang ◽  
Xiao Yang ◽  
Yang Zhao ◽  
Jia-Xing Jiang
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Gas Adsorption ◽  
High Specific Surface Area

Conjugated microporous copolymer networks show a high specific surface area of up to 2241 m2 g−1 and a high CO2 uptake of 4.57 mmol g−1 (1.13 bar/273 K) with a H2 uptake of 2.24 wt% (1.13 bar/77.3 K).

The Effect of Hydrothermal Treatment on Samaria and Gadolinia Doped Ceria Powders Synthesized by Coprecipitation

2010 ◽  
Vol 660-661 ◽  
pp. 959-964
Author(s):  
Alexander Rodrigo Arakaki ◽  
Walter Kenji Yoshito ◽  
Valter Ussui ◽  
Dolores Ribeiro Ricci Lazar
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Hydrothermal Treatment ◽  
Specific Surface Area ◽  
Gas Adsorption ◽  
Fluorite Structure ◽  
High Specific Surface Area ◽  
Powder Synthesis ◽  
Laser Scattering ◽  
The One

One of the main applications of ceria-based (CeO2) ceramics is the manufacturing of Intermediate Temperature Solid Oxide Fuel Cells electrolytes. In order to improve ionic conductivity and densification of these materials various powder synthesis routes have been studied. In this work powders with composition Ce0.8(SmGd)0.2O1.9 have been synthesized by coprecipitation and hydrothermal treatment. A concentrate of rare earths containing 90wt% of CeO2 and other containing 51% of Sm2O3 and 30% of Gd2O3, both prepared from monazite processing, were used as precursor materials. The powders were characterized by X-ray diffraction, scanning and transmission electron microscopy, agglomerate size distribution by laser scattering and specific surface area by gas adsorption. Ceramic sinterability was evaluated by dilatometry and density measurements by Archimedes method. High specific surface area powders (~100m2/g) and cubic fluorite structure were obtained after hydrothermal treatment around 200°C. Ceramic densification was improved when compared to the one prepared from powders calcined at 800°C.

scholarly journals Nanoporous Quasi-High-Entropy Alloy Microspheres

Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 345 ◽  
Author(s):  
Lianzan Yang ◽  
Yongyan Li ◽  
Zhifeng Wang ◽  
Weimin Zhao ◽  
Chunling Qin
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Specific Surface Area ◽  
High Entropy Alloy ◽  
Face Centered Cubic ◽  
High Entropy ◽  
Hierarchical Porous

High-entropy alloys (HEAs) present excellent mechanical properties. However, the exploitation of chemical properties of HEAs is far less than that of mechanical properties, which is mainly limited by the low specific surface area of HEAs synthesized by traditional methods. Thus, it is vital to develop new routes to fabricate HEAs with novel three-dimensional structures and a high specific surface area. Herein, we develop a facile approach to fabricate nanoporous noble metal quasi-HEA microspheres by melt-spinning and dealloying. The as-obtained nanoporous Cu30Au23Pt22Pd25 quasi-HEA microspheres present a hierarchical porous structure with a high specific surface area of 69.5 m2/g and a multiphase approximatively componential solid solution characteristic with a broad single-group face-centered cubic XRD pattern, which is different from the traditional single-phase or two-phase solid solution HEAs. To differentiate, these are named quasi-HEAs. The synthetic strategy proposed in this paper opens the door for the synthesis of porous quasi-HEAs related materials, and is expected to promote further applications of quasi-HEAs in various chemical fields.

KCl-assisted activation: Moringa oleifera branch-derived porous carbon for high performance supercapacitor

2021 ◽  
Vol 45 (12) ◽  
pp. 5712-5719
Author(s):  
Yongxiang Zhang ◽  
Peifeng Yu ◽  
Mingtao Zheng ◽  
Yong Xiao ◽  
Hang Hu ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Porous Carbon ◽  
High Performance ◽  
Moringa Oleifera ◽  
High Specific Surface Area ◽  
Porous Carbons

Porous carbons with a high specific surface area (2314–3470 m2 g−1) are prepared via a novel KCl-assisted activation strategy for high-performance supercapacitor.

Carbon material with high specific surface area and high pseudocapacitance: Possible application in supercapacitors

2021 ◽  
Vol 319 ◽  
pp. 111063
Author(s):  
Yury M. Volfkovich ◽  
Valentin E. Sosenkin ◽  
Alexei Y. Rychagov ◽  
Alexandr V. Melezhik ◽  
Alexei G. Tkachev ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Carbon Material ◽  
High Specific Surface Area

Efficient conversion of CO2 to methane using thin-layer SiOx matrix anchored nickel catalysts

2019 ◽  
Vol 43 (33) ◽  
pp. 13217-13224 ◽  
Author(s):  
Xieyi Huang ◽  
Peng Wang ◽  
Zhichao Zhang ◽  
Shaoning Zhang ◽  
Xianlong Du ◽  
...  
Keyword(s):  
Thin Layer ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Geometric Structure ◽  
Nickel Catalysts ◽  
High Specific Surface Area ◽  
Efficient Conversion

Thin-layer SiOx matrix anchored nickel catalysts with high specific surface area and a unique electronic/geometric structure were fabricated for efficient CO2 methanation.

High specific surface area LaFeCo perovskites—Synthesis by nanocasting and catalytic behavior in the reduction of NO with CO

2009 ◽  
Vol 90 (3-4) ◽  
pp. 441-450 ◽  
Author(s):  
R.K.C. de Lima ◽  
M.S. Batista ◽  
M. Wallau ◽  
E.A. Sanches ◽  
Y.P. Mascarenhas ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Specific Surface Area ◽  
Catalytic Behavior ◽  
Reduction Of No
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