K2S2O8-mediated metal-free direct C–H functionalization of quinones using arylboronic acids

A metal-free and radical-free synthesis of heteroaromatic aldehydes was developed through aerobic oxidation of methyl groups in an I2/DMSO/O2 catalytic system.

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Metal-free regioselective hydrochlorination of unactivated alkenes via a combined acid catalytic system

Green Chemistry ◽

10.1039/c7gc03665e ◽

2018 ◽

Vol 20 (3) ◽

pp. 680-684 ◽

Cited By ~ 5

Author(s):

Shengzong Liang ◽

Gerald B. Hammond ◽

Bo Xu

Keyword(s):

Acetic Acid ◽

Catalytic System ◽

Metal Free ◽

System P ◽

Wide Range

A combined acid HCl/DMPU-acetic acid catalytic system was used in the hydrochlorination of a wide range of unactivated alkenes.

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Metal free decarboxylative aminoxylation of carboxylic acids using a biphasic solvent system

Organic & Biomolecular Chemistry ◽

10.1039/d0ob01773f ◽

2021 ◽

Vol 19 (1) ◽

pp. 273-278

Author(s):

Göran Schulz ◽

Andreas Kirschning

Keyword(s):

Carboxylic Acids ◽

Solvent System ◽

Radical Scavenger ◽

Synthetic Approach ◽

Metal Free ◽

System P

The oxidative radical decarboxylation of carboxylic acids with TEMPO as radical scavenger in a biphasic solvent system is reported which is successfully used in a new synthetic approach for the antidepressants indatraline.

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Transition metal free, green and facile halogenation of ketene dithioacetals using a KX–oxidant system

New Journal of Chemistry ◽

10.1039/d0nj03737k ◽

2021 ◽

Author(s):

Vishakha Rai ◽

Ganesh Shivayogappa Sorabad ◽

Mahagundappa Rachappa Maddani

Keyword(s):

Transition Metal ◽

Ambient Temperature ◽

Metal Free ◽

Ketene Dithioacetals ◽

System P ◽

Oxidative Halogenation ◽

Potassium Halide

A facile oxidative halogenation of α-oxo ketene dithioacetals is achieved by using a potassium halide and an oxidant combination under transition metal free conditions at ambient temperature.

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Atom-transfer radical addition of fluoroalkyl bromides to alkenes via a photoredox/copper catalytic system

Chemical Communications ◽

10.1039/d1cc01609a ◽

2021 ◽

Author(s):

Vladislav S. Kostromitin ◽

Artem A. Zemtsov ◽

Vladimir A. Kokorekin ◽

Vitalij V. Levin ◽

Alexander D. Dilman

Keyword(s):

Catalytic System ◽

Radical Addition ◽

Atom Transfer ◽

Alkyl Bromides ◽

System P ◽

Atom Transfer Radical Addition

A method for the addition of fluorinated alkyl bromides to alkenes is described.

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Synthesis of 2-aminothiazoles from methylcarbonyl compounds using a Fe3O4 nanoparticle-N-halo reagent catalytic system

RSC Advances ◽

10.1039/c6ra11175k ◽

2016 ◽

Vol 6 (69) ◽

pp. 64749-64755 ◽

Cited By ~ 13

Author(s):

Masoud Sadeghi ◽

Javad Safari ◽

Zohre Zarnegar

Keyword(s):

Catalytic System ◽

Fe3o4 Nanoparticle ◽

Catalytic Systems ◽

System P

An efficient protocol is developed for the synthesis of 2-aminothiazoles from unfunctionalized methylcarbonyl compounds using Fe3O4 nanoparticle-N-halo reagent catalytic systems.

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A novel enantioselective synthesis of 6H-dibenzopyran derivatives by combined palladium/norbornene and cinchona alkaloid catalysis

Organic & Biomolecular Chemistry ◽

10.1039/c4ob02551b ◽

2015 ◽

Vol 13 (8) ◽

pp. 2260-2263 ◽

Cited By ~ 25

Author(s):

Di Xu ◽

Li Dai ◽

Marta Catellani ◽

Elena Motti ◽

Nicola Della Ca’ ◽

...

Keyword(s):

Catalytic System ◽

Enantioselective Synthesis ◽

Cinchona Alkaloid ◽

System P ◽

First Time

Chiral dibenzopyran derivatives were obtained by cinchona alkaloid, as organocatalyst, in combination, for the first time, with palladium/norbornene catalytic system.

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