Synthesis of polyacrylonitrile by reversible-deactivation radical polymerization and its application as electrode materials for electrochemical double layer capacitors

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37780-37788 ◽  
Author(s):  
Yuanyuan Xu ◽  
Jinming Sun ◽  
Hou Chen ◽  
Liangjiu Bai
Keyword(s):  
Radical Polymerization ◽  
Electrode Materials ◽  
Controlled Radical Polymerization ◽  
Electrochemical Double Layer Capacitors ◽  
Reversible Deactivation ◽  
Electrochemical Double Layer ◽  
Reversible Deactivation Radical Polymerization ◽  
Double Layer Capacitors ◽  
Living Controlled Radical Polymerization ◽  
Polymerization Method

Polyacrylonitrile (PAN) was firstly synthesized using Fe(acac)2 as the mediator via “living”/controlled radical polymerization method.

scholarly journals The living dead – common misconceptions about reversible deactivation radical polymerization

2016 ◽  
Vol 3 (6) ◽  
pp. 471-477 ◽  
Author(s):  
Martina H. Stenzel ◽  
Christopher Barner-Kowollik
Keyword(s):  
Radical Polymerization ◽  
Soft Matter ◽  
Controlled Radical Polymerization ◽  
Reversible Deactivation ◽  
Living Dead ◽  
Reversible Deactivation Radical Polymerization ◽  
Living Controlled Radical Polymerization ◽  
Common Misconceptions

We illustrate common misconceptions and errors when interpreting polymerization data from ‘Living/controlled’ radical polymerization, preferably termed ‘reversible deactivation radical polymerization’ (RDRP). Avoiding the discussed errors leads to better defined materials for soft matter materials applications.

Mesoporous carbon capsules as electrode materials in electrochemical double layer capacitors

2011 ◽  
Vol 13 (7) ◽  
pp. 2652-2655 ◽  
Author(s):  
Shanthi Murali ◽  
Daniel R. Dreyer ◽  
Patricia Valle-Vigón ◽  
Meryl D. Stoller ◽  
Yanwu Zhu ◽  
...  
Keyword(s):  
Double Layer ◽  
Mesoporous Carbon ◽  
Electrode Materials ◽  
Electrochemical Double Layer Capacitors ◽  
Electrochemical Double Layer ◽  
Double Layer Capacitors

Photocontrolled iodine-mediated reversible-deactivation radical polymerization with a semifluorinated alternating copolymer as the macroinitiator

2020 ◽  
Vol 11 (47) ◽  
pp. 7497-7505
Author(s):  
Jiannan Cheng ◽  
Kai Tu ◽  
Enjie He ◽  
Jinying Wang ◽  
Lifen Zhang ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Room Temperature ◽  
Blue Led ◽  
Led Light ◽  
Alternating Copolymers ◽  
Alternating Copolymer ◽  
Reversible Deactivation ◽  
Novel Strategy ◽  
Reversible Deactivation Radical Polymerization

A novel strategy for preparing block copolymers with semifluorinated alternating copolymers as macroinitiators was established by photocontrolled iodine-mediated RDRP under irradiation with blue LED light at room temperature.

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