Getting faster: low temperature copper-mediated SARA ATRP of methacrylates, acrylates, styrene and vinyl chloride in polar media using sulfolane/water mixtures

RSC Advances ◽  
2016 ◽  
Vol 6 (12) ◽  
pp. 9598-9603 ◽  
Author(s):  
Joana P. Mendes ◽  
Patrícia V. Mendonça ◽  
Pedro Maximiano ◽  
Carlos M. R. Abreu ◽  
Tamaz Guliashvili ◽  
...  

Supplemental activator and reducing agent atom transfer radical polymerization (SARA ATRP) of acrylates, methacrylates, styrene and vinyl chloride was successfully performed in sulfolane/water mixtures using ppm amounts of soluble copper.

2014 ◽  
Vol 5 (12) ◽  
pp. 3919-3928 ◽  
Author(s):  
Joana R. Góis ◽  
Nuno Rocha ◽  
Anatoliy V. Popov ◽  
Tamaz Guliashvili ◽  
Krzysztof Matyjaszewski ◽  
...  

2-(Diisopropylamino)ethyl methacrylate was polymerized by Atom Transfer Radical Polymerization using sodium dithionite as a reducing agent and supplemental activator with a Cu(ii)Br2/Me6TREN catalytic system.


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