Photocatalytic degradation of binary mixture of toxic dyes by HKUST-1 MOF and HKUST-1-SBA-15 in a rotating packed bed reactor under blue LED illumination: central composite design optimization

RSC Advances ◽  
2016 ◽  
Vol 6 (21) ◽  
pp. 17204-17214 ◽  
Author(s):  
S. Mosleh ◽  
M. R. Rahimi ◽  
M. Ghaedi ◽  
K. Dashtian ◽  
S. Hajati

A new composite of mesoporous materials, HKUST-1 metal organic framework and SBA-15, was synthesized and applied to the simultaneous visible-light-driven photodegradation of a binary dye mixture of safranin O and malachite green.

2017 ◽  
Vol 224 ◽  
pp. 292-297 ◽  
Author(s):  
Juntao Xu ◽  
Changsheng Liu ◽  
Meng Wang ◽  
Lei Shao ◽  
Li Deng ◽  
...  

2003 ◽  
Vol 58 (3-6) ◽  
pp. 569-575 ◽  
Author(s):  
Jian-Feng Chen ◽  
Lei Shao ◽  
Fen Guo ◽  
Xing-Ming Wang

2021 ◽  
Vol 11 (21) ◽  
pp. 10194
Author(s):  
Wenhui Hou ◽  
Wei Wang ◽  
Yang Xiang ◽  
Yingjiao Li ◽  
Guangwen Chu ◽  
...  

Polymerization of isobutylene (IB) for synthesizing highly reactive polyisobutylene (HRPIB) is characterized by a complicated fast intrinsic reaction rate; therefore, the features of its products exhibit a strong dependence on mixing efficiency. To provide uniform and efficient mixing, a rotating packed bed was employed as a reactor for polymerization of IB. The effects of operating parameters including polymerization temperature (T), rotating speed (N) and relative dosage of monomers and initiating systems ([M]0/[I]0) on number-average molecular weight (Mn) of HRPIB were studied. HRPIB with Mn of 2550 g·mol−1 and exo-olefin terminal content of 85 mol% were efficiently obtained at suitable conditions as T of 283 K, N of 1600 rpm and [M]0/[I]0 of 49. Moreover, the Mn can be regulated by changing T, N and [M]0/[I]0. Based on the presumptive-steady-state analysis method and the coalescence–redispersion model, a model for prediction of the Mn was developed and validated, and the calculated Mn values agreed well with experimental results, with a deviation of ±10%. The results demonstrate that RPB is a promising reactor for synthesizing HRPIB, and the given model for Mn can be applied for the design of RPB and process optimization.


2020 ◽  
Vol 8 (12) ◽  
pp. 6034-6040 ◽  
Author(s):  
Yanan Wang ◽  
Wenlong Zhen ◽  
Yiqing Zeng ◽  
Shipeng Wan ◽  
Haiwei Guo ◽  
...  

A series of Zr-porphyrin metal–organic framework (Zr-PMOF)/ultrathin g-C3N4 (UCN) heterostructure photocatalysts, as stable and efficient catalysts for the photoreduction of CO2, have been fabricated via a facile in situ hydrothermal self-assembly method.


2016 ◽  
Vol 128 (46) ◽  
pp. 14522-14526 ◽  
Author(s):  
Huabin Zhang ◽  
Jing Wei ◽  
Juncai Dong ◽  
Guigao Liu ◽  
Li Shi ◽  
...  

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