A bracket approach to improve the stability and gas sorption performance of a metal–organic framework via in situ incorporating the size-matching molecular building blocks

2016 ◽  
Vol 52 (54) ◽  
pp. 8413-8416 ◽  
Author(s):  
Di-Ming Chen ◽  
Jia-Yue Tian ◽  
Chun-Sen Liu ◽  
Miao Du
Keyword(s):  
Metal Organic Framework ◽  
Building Blocks ◽  
Gas Sorption ◽  
Molecular Building Blocks ◽  
Metal Organic ◽  
Coordination Framework ◽  
The Stability ◽  
Organic Framework

The robustness and gas sorption performance of a coordination framework can be greatly improved by incorporating size-matching molecular building blocks.

scholarly journals In Situ Spectroscopy of Calcium Fluoride Anchored Metal–Organic Framework Thin Films during Gas Sorption

2020 ◽  
Vol 132 (44) ◽  
pp. 19713-19720 ◽  
Author(s):  
Laurens D. B. Mandemaker ◽  
Miguel Rivera‐Torrente ◽  
Robert Geitner ◽  
Carolien M. Vis ◽  
Bert M. Weckhuysen
Keyword(s):  
Thin Films ◽  
Calcium Fluoride ◽  
Metal Organic Framework ◽  
In Situ Spectroscopy ◽  
Gas Sorption ◽  
Metal Organic ◽  
Organic Framework

scholarly journals In Situ Spectroscopy of Calcium Fluoride Anchored Metal–Organic Framework Thin Films during Gas Sorption

2020 ◽  
Vol 59 (44) ◽  
pp. 19545-19552 ◽  
Author(s):  
Laurens D. B. Mandemaker ◽  
Miguel Rivera‐Torrente ◽  
Robert Geitner ◽  
Carolien M. Vis ◽  
Bert M. Weckhuysen
Keyword(s):  
Thin Films ◽  
Calcium Fluoride ◽  
Metal Organic Framework ◽  
In Situ Spectroscopy ◽  
Gas Sorption ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

Sign in / Sign up

Export Citation Format

Share Document