A symmetry breaking phase transition-triggered high-temperature solid-state quadratic nonlinear optical switch coupled with a switchable dielectric constant in an organic–inorganic hybrid compound

2016 ◽  
Vol 52 (74) ◽  
pp. 11135-11138 ◽  
Author(s):  
Guang-Quan Mei ◽  
Han-Yue Zhang ◽  
Wei-Qiang Liao
Keyword(s):  
Phase Transition ◽  
Dielectric Constant ◽  
High Temperature ◽  
Solid State ◽  
Symmetry Breaking ◽  
Nonlinear Optical ◽  
Optical Switch ◽  
Hybrid Compound ◽  
Inorganic Hybrid

The compound exhibits switchable SHG effect and tunable dielectric behaviors, associated with its symmetry breaking phase transition.

High temperature structural phase transition and dielectric relaxation in an organic–inorganic hybrid compound: (4-methylpiperidinium)CdCl3

CrystEngComm ◽  
2017 ◽  
Vol 19 (14) ◽  
pp. 1896-1901 ◽  
Author(s):  
Yang Lu ◽  
Zhongxia Wang ◽  
Hai-Peng Chen ◽  
Jia-Zhen Ge
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Dielectric Relaxation ◽  
Structural Phase Transition ◽  
Structural Phase ◽  
Hybrid Compound ◽  
Inorganic Hybrid

The wavevector substar group in reciprocal space and its representation

2017 ◽  
Vol 73 (5) ◽  
pp. 403-413
Author(s):  
Il Hwan Kim ◽  
Jong Ok Pak ◽  
Il Hun Kim ◽  
Song Won Kim ◽  
Lin Li
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Solid State ◽  
Symmetry Breaking ◽  
High Temperature Superconductor ◽  
Landau Theory ◽  
Translational Symmetry ◽  
Mathematical Tool ◽  
Symmetry Breaking Phenomena ◽  
Powerful Mathematical Tool

A new concept of the wavevector substar group is established which, in the study of translational symmetry breaking of a crystal, only considers the particular arms of the wavevector star taking part in the phase transition; this is in contrast with the traditional Landau theory which considers all of the arms of the wavevector star. It is shown that this new concept can be used effectively to investigate the interesting physical properties of crystals associated with translational symmetry breaking. It is shown that studies on complicated phase transitions related to reducible representations, such as those in perovskite KMnF3multiferroics and the high-temperature superconductor La2/3Mg1/2W1/2O3(La4Mg3W3O18), are much simplified by the new concept. The theory of the wavevector substar group and its representation is a powerful mathematical tool for the study of various symmetry-breaking phenomena in solid-state crystals.

Temperature-Triggered Reversible Dielectric and Nonlinear Optical Switch Based on the One-Dimensional Organic–Inorganic Hybrid Phase Transition Compound [C6H11NH3]2CdCl4

2014 ◽  
Vol 53 (20) ◽  
pp. 11146-11151 ◽  
Author(s):  
Wei-Qiang Liao ◽  
Heng-Yun Ye ◽  
Da-Wei Fu ◽  
Peng-Fei Li ◽  
Li-Zhuang Chen ◽  
...  
Keyword(s):  
Phase Transition ◽  
Nonlinear Optical ◽  
Optical Switch ◽  
Inorganic Hybrid ◽  
One Dimensional ◽  
The One

scholarly journals A high-temperature organic–inorganic ferroelectric with outstanding switchable dielectric characteristics

RSC Advances ◽  
2017 ◽  
Vol 7 (76) ◽  
pp. 47933-47937 ◽  
Author(s):  
Cong Xu ◽  
Wenjun Zhang ◽  
Linsong Gao ◽  
Xuecheng Gan ◽  
Xiaofan Sun ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase ◽  
Hybrid Compound ◽  
Dielectric Characteristics ◽  
Inorganic Hybrid ◽  
Compound C

A new molecular ferroelectric is discovered in an organic–inorganic hybrid compound, (C6H5NH3)2CdCl4, which undergoes a reversible order–disorder ferroelectric phase transition at 369 K.

[C 5 H 12 N]SnCl 3 : A Tin Halide Organic–Inorganic Hybrid as an Above‐Room‐Temperature Solid‐State Nonlinear Optical Switch

2019 ◽  
Vol 25 (10) ◽  
pp. 2610-2615 ◽  
Author(s):  
Xitao Liu ◽  
Chengmin Ji ◽  
Zhenyue Wu ◽  
Lina Li ◽  
Shiguo Han ◽  
...  
Keyword(s):  
Solid State ◽  
Nonlinear Optical ◽  
Room Temperature ◽  
Optical Switch ◽  
Inorganic Hybrid

Above room-temperature dielectric switching and semiconducting properties of a layered organic–inorganic hybrid compound: (C6H12N)2Pb(NO3)4

2020 ◽  
Vol 49 (46) ◽  
pp. 16860-16865
Author(s):  
Jia-Ying Jiang ◽  
Qi Xu ◽  
Jia-Jun Ma ◽  
Zhi-Xin Gong ◽  
Chao Shi ◽  
...  
Keyword(s):  
Phase Transition ◽  
Dielectric Constant ◽  
Structural Phase Transition ◽  
Room Temperature ◽  
Structural Phase ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
Semiconducting Properties

(C6H12N)2Pb(NO3)4, a layered hybrid semiconductor with switchable dielectric constant, undergoes a structural phase transition around 352 K.

An organic–inorganic hybrid co-crystal complex as a high-performance solid-state nonlinear optical switch

2016 ◽  
Vol 4 (2) ◽  
pp. 266-271 ◽  
Author(s):  
Tianliang Chen ◽  
Zhihua Sun ◽  
Sangen Zhao ◽  
Chengmin Ji ◽  
Junhua Luo
Keyword(s):  
Solid State ◽  
High Performance ◽  
Nonlinear Optical ◽  
Optical Switch ◽  
Optical Performance ◽  
Inorganic Hybrid ◽  
Crystal Complex ◽  
High Repeatability

An organic–inorganic hybrid co-crystal complex exhibits an attractive switching nonlinear optical performance with a superior contrast and high repeatability.

A single layered organic-inorganic hybrid compound [(FBMA)2PbBr4] with reversible phase transition and intense fluorescent property

2019 ◽  
Vol 270 ◽  
pp. 226-230 ◽  
Author(s):  
Yanhuan Hao ◽  
Shuyao Wen ◽  
Jiaojiao Yao ◽  
Zhenhong Wei ◽  
Xiuxiu Zhang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Fluorescent Property ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
Reversible Phase Transition ◽  
Reversible Phase
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