Electrochemical probing of hydrogelation induced by the self-assembly of a donor–acceptor complex comprising pyranine and viologen

2017 ◽  
Vol 53 (15) ◽  
pp. 2371-2374 ◽  
Author(s):  
Sougata Datta ◽  
Nilanjan Dey ◽  
Santanu Bhattacharya
Keyword(s):  
Self Assembly ◽  
Methyl Viologen ◽  
Electrochemical Analysis ◽  
The Self ◽  
Acceptor Complex ◽  
Two Component ◽  
Donor Acceptor

We report the electrochemical analysis of a donor–acceptor type two-component hydrogelation by an electroactive co-assembly of pyranine and n-dodecyl methyl viologen.

Controlled self-assembly of porphyrin/fullerene donor-acceptor complex in a polymer thin film

2014 ◽  
Vol 52 (11) ◽  
pp. 743-746 ◽  
Author(s):  
Itaru Natori ◽  
Shizue Natori ◽  
Naoki Hanawa ◽  
Kenji Ogino
Keyword(s):  
Thin Film ◽  
Self Assembly ◽  
Polymer Thin Film ◽  
Acceptor Complex ◽  
Donor Acceptor

scholarly journals First in situ vesicular self-assembly of ‘binols’ generated by a two-component aerobic oxidation reaction

RSC Advances ◽  
2018 ◽  
Vol 8 (51) ◽  
pp. 29155-29163 ◽  
Author(s):  
Braja G. Bag ◽  
Subrata Ghorai ◽  
Saikat K. Panja ◽  
Shaishab K. Dinda ◽  
Koushik Paul
Keyword(s):  
Self Assembly ◽  
Oxidation Reaction ◽  
Aerobic Oxidation ◽  
Alkyl Chains ◽  
Two Component ◽  
Donor Acceptor ◽  
Self Assembled ◽  
Naphthol Derivatives

Binol derivatives, obtained by aerobic coupling of two 2-naphthol derivatives having H-bond donor–acceptor groups and appended alkyl chains, spontaneously self-assembled in situ yielding vesicular self-assemblies and gels.

scholarly journals {N 1-[2-(Butylselanyl)benzyl]-N 2,N 2-dimethylethane-1,2-diamine}dichloridomercury(II)

2018 ◽  
Vol 74 (8) ◽  
pp. 1151-1154
Author(s):  
Pushpendra Singh ◽  
Harkesh B. Singh ◽  
Ray J. Butcher
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Self Assembly ◽  
Title Compound ◽  
Supramolecular Assembly ◽  
Molecular Geometry ◽  
The Self ◽  
Intermolecular Hydrogen Bonding ◽  
Hydrogen Bonding Interactions ◽  
Donor Acceptor

In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound.

scholarly journals Design directed self-assembly of donor–acceptor polymers

2016 ◽  
Vol 52 (73) ◽  
pp. 10938-10947 ◽  
Author(s):  
Tomasz Marszalek ◽  
Mengmeng Li ◽  
Wojciech Pisula
Keyword(s):  
Molecular Weight ◽  
Self Assembly ◽  
The Self ◽  
Side Chain ◽  
Structural Factors ◽  
Chemical Design ◽  
Donor Acceptor

This review discusses the role of chemical design on the self-assembly of donor–acceptor polymers on surfaces. Three major structural factors are highlighted including molecular weight, side chain engineering and backbone curvature of the polymers.

Wechselwirkungen in Molekülkristallen, 181 [1, 2]. σ-Donator/Akzeptor-Komplexe {MAI4···X⊖ } (X⊖ = Br⊖ , I⊖ , SCN⊖ ) der Tetraiod-Akzeptormoleküle MAI4 (MA = Ethen, Thiophen, N-Methylpyrrol) in Tetraphenylphosphoniumhalogenid-Salzen Interaction in Molecular Crystals, 181 [1, 2]. σ-Donor/Acceptor Complexes {MAI4···X⊖ }(X⊖ = Br⊖, I⊖, SCN⊖ of Tetraiodo Acceptor Molecules MAI4 (MA = Ethene, Thiophene, N-Methylpyrrole) in Tetraphenylphosphonium Halide Salts

2002 ◽  
Vol 57 (8) ◽  
pp. 843-858 ◽  
Keyword(s):  
Low Temperature ◽  
Complex Molecule ◽  
Molecular Crystals ◽  
Ammonium Cation ◽  
The Self ◽  
Acceptor Complex ◽  
Donor Acceptor ◽  
Halide Salts ◽  
Self Aggregation ◽  
Acceptor Molecules

Four donor/acceptor complex phosphoniumhalide salts [(H6C5)4P⊕{X⊖···I4MA}] have been crystallized from chloroform solutions of the components (H6C5)4P⊕X⊖ (X⊖ =Br⊖, I⊖, SCN⊖) and the acceptor molecules MAI4 tetraiodoethene, -thiophene, as well as -N-methylpyrrole by using low-gradient techniques and their low-temperature structures determined. The discussion includes analogous salts with the more flexible tetra(n-butyl)ammonium cation and centers on Br$ coordination to tetraiodothiophene, dimer {X⊖···(IC)4NR}2 disordering in the two tetraiodopyrrole salt, the band structures as well as the donor/acceptor complexes formed with bidentate SCN⊖ anions. The regularities detected in the rather complex molecule packing features add essential aspects to the self-aggregation of polyiodo acceptor molecules and electron- rich donor anions in halide salts with rigid tetraphenylphosphonium and more flexible tetra(n-butyl)ammonium cations.

Single-molecule analysis of the self-assembly process facilitated by host–guest interactions

2015 ◽  
Vol 51 (7) ◽  
pp. 1202-1205 ◽  
Author(s):  
Fu-Na Meng ◽  
Xuyang Yao ◽  
Yi-Lun Ying ◽  
Junji Zhang ◽  
He Tian ◽  
...  
Keyword(s):  
Single Molecule ◽  
Self Assembly ◽  
Methyl Viologen ◽  
The Self ◽  
Assembly Process ◽  
Single Molecule Level ◽  
Single Molecule Analysis

The self-assembly process operated by para-sulfonatocalix[6]arenes and methyl viologen was analyzed at the single-molecule level through an α-hemolysin nanopore.

Electrochemical Analysis of Enzyme Based on the Self-Assembly of Lipid Bilayer on an Electrode Surface Mediated by Hydrazone Chemistry

2017 ◽  
Vol 89 (24) ◽  
pp. 13245-13251 ◽  
Author(s):  
Juan Zhang ◽  
Xiaonan Wang ◽  
Tingjun Chen ◽  
Chang Feng ◽  
Genxi Li
Keyword(s):  
Lipid Bilayer ◽  
Self Assembly ◽  
Electrode Surface ◽  
Electrochemical Analysis ◽  
The Self

Near-infrared fluorescent organic porous crystal that responds to solvent vapors

2020 ◽  
Vol 8 (36) ◽  
pp. 12437-12444
Author(s):  
Tsutomu Ishi-i ◽  
Honoka Tanaka ◽  
Himiko Koga ◽  
Yuuma Tanaka ◽  
Taisuke Matsumoto
Keyword(s):  
Self Assembly ◽  
Near Infrared ◽  
The Self ◽  
Solvent Vapor ◽  
Near Ir ◽  
Donor Acceptor ◽  
Porous Crystal ◽  
Solvent Vapors

Creation of a near-IR porous florescent crystal by noncovalent synthesis based on the self-assembly of donor–acceptor dye and its development into a solvent vapor-responsive fluorescence system were studied.

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