scholarly journals First in situ vesicular self-assembly of ‘binols’ generated by a two-component aerobic oxidation reaction

RSC Advances ◽  
2018 ◽  
Vol 8 (51) ◽  
pp. 29155-29163 ◽  
Author(s):  
Braja G. Bag ◽  
Subrata Ghorai ◽  
Saikat K. Panja ◽  
Shaishab K. Dinda ◽  
Koushik Paul

Binol derivatives, obtained by aerobic coupling of two 2-naphthol derivatives having H-bond donor–acceptor groups and appended alkyl chains, spontaneously self-assembled in situ yielding vesicular self-assemblies and gels.

2017 ◽  
Vol 1 (3) ◽  
Author(s):  
Braja G. Bag ◽  
Subrata Ghorai ◽  
Saikat K. Panja ◽  
Shaishab K. Dinda ◽  
Koushik Paul

6-hydroxy-N-(6-methylpyridin-2-yl)naphthalene-2- carboxamide and its alkoxy analogues bearing long alkyl chains have been synthesized using 6-hydroxy-2-naphthoic acid and 2-amino-6-picoline. The facile synthetic scheme reported here using conventional laboratory reagents opens up a new strategy for the generation of libraries of such compounds in high yields. The H-bond donor acceptor groups along with the reactive 2-naphthol moiety present in the target compounds make them useful for their use in self-assembly and self-replication studies.


2020 ◽  
Vol 8 (3) ◽  
pp. 930-934
Author(s):  
Mengyu Xu ◽  
Kangyi Kong ◽  
Haoran Ding ◽  
Yanmeng Chu ◽  
Shicong Zhang ◽  
...  

Self-assembled nanobelt photocatalysts with quinacridone containing different alkyl chains as donor and pyridine dicarboxylic acid as acceptor were firstly developed for H2 evolution. SQAP-C4 without cocatalyst of Pt exhibited HER of 656 μmol h−1 g−1.


2020 ◽  
Vol 8 (42) ◽  
pp. 21968-21972
Author(s):  
Debabrata Samanta ◽  
Manish Kumar ◽  
Sugandha Singh ◽  
Parul Verma ◽  
Kamal K. Kar ◽  
...  

A donor–acceptor coordination polymer (TPA-Zn) was synthesized by Zn(ii)-assisted self-assembly of an in situ generated triphenylamine (TPA) cored tristerpyridine ligand.


2014 ◽  
Vol 47 (5) ◽  
pp. 1757-1767 ◽  
Author(s):  
Yueqin Shi ◽  
Licheng Tan ◽  
Lie Chen ◽  
Yiwang Chen

Author(s):  
Iltai (Isaac) Kim ◽  
Kenneth David Kihm

Innovative optical techniques based on nano-biophotonics such as surface plasmon resonance (SPR) imaging and R-G-B natural fringe mapping techniques are developed to characterize the transport and optical properties of nanofluids in situ, real-time, and full field manner. Recent results regarding the characterization of nanofluids are summarized and future research directions are presented. 47 nm Al2O3 nanoparticles are dispersed in water with various concentrations. Al2O3 nanofluids droplets are placed on substrates and evaporated in room temperature. In-situ visualization of evaporation-induced self-assembly is conducted to detect concentration, effective refractive index, and different self-assembled pattern including cavity with various nanofluids concentrations and surface hydrophobbicities with SPR and fringe mapping. During the evaporation, time-dependent and near-field nanoparticle concentrations are determined by correlating the SPR reflectance intensities with the effective refractive index (ERI) of the nanofluids. With increasing the concentrations of nanofluids, the existence of hidden complex cavities inside a self-assembled nanocrystalline structure or final dryout pattern is discovered in real-time. R-G-B natural fringe mapping allowed the reconstruction of the 3D cavity formation and crystallization processes quantitatively. The formation of the complex inner structure was found to be attributable to multiple cavity inceptions and their competing growth during the aquatic evaporation. Furthermore, the effect of surface hydrophobicity is examined in the formation of hidden complex cavities, taking place on three different substrates bearing different levels of hydrophobicity; namely, cover glass (CG), gold thin film (Au), and polystyrene dish (PS). These surface plamson resonance imaging and natural fringe mapping techniques are expected to provide a breakthrough in micro-nanoscale thermal fluids phenomena and nano-biochemical sensing when coupled with localized surface Plasmon and metamaterials techniques.


2019 ◽  
Vol 10 (6) ◽  
pp. 1651-1658 ◽  
Author(s):  
Shuzhen Yue ◽  
Xinyue Song ◽  
Weiling Song ◽  
Sai Bi

Branched catalytic hairpin assembly is proposed for dynamic self-assembly of DNA dendrimers for signal amplification and in situ imaging of microRNAs in live cells with high sensitivity and selectivity.


2020 ◽  
Vol 8 (7) ◽  
pp. 2031-2039 ◽  
Author(s):  
Zhiwei Shen ◽  
Zhen Guo ◽  
Limin Zhou ◽  
Yujiao Wang ◽  
Jinjin Zhang ◽  
...  

FF8 self-assembled into nanofibers on the negatively charged lipid membrane and induced rupture of the membrane.


2021 ◽  
Author(s):  
Panittha Damsongsang ◽  
Voravee Hoven ◽  
Shinichi Yusa
Keyword(s):  

The combination of polymerization-induced self-assembly (PISA) and post-polymerization modification is a versatile route by which to prepare core-functionalized nanoaggregates. PISA is a useful approach for preparing in situ self-assembled nano-objects...


2017 ◽  
Vol 53 (15) ◽  
pp. 2371-2374 ◽  
Author(s):  
Sougata Datta ◽  
Nilanjan Dey ◽  
Santanu Bhattacharya

We report the electrochemical analysis of a donor–acceptor type two-component hydrogelation by an electroactive co-assembly of pyranine and n-dodecyl methyl viologen.


RSC Advances ◽  
2015 ◽  
Vol 5 (88) ◽  
pp. 72416-72422 ◽  
Author(s):  
Challa V. Kumar ◽  
Marc J. Novak ◽  
Kyle R. Benson ◽  
Clive Baveghems ◽  
Vindya K. Thilakarathne ◽  
...  

Artificial antenna complexes built via self-assembly are reported, indicating efficient cascade energy transfer, unprecedented thermal stability, and ease of formation.


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