A pillared-layer framework with high uptake and selective sorption of light hydrocarbons

2016 ◽  
Vol 45 (16) ◽  
pp. 7004-7007 ◽  
Author(s):  
Qing-Rong Ding ◽  
Fei Wang
Keyword(s):  
Room Temperature ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
High Uptake ◽  
Light Hydrocarbons ◽  
Adsorption Selectivity ◽  
Selective Sorption ◽  
High Storage Capacity ◽  
Metal Organic ◽  
High Storage

A pillared-layer metal–organic framework was successfully synthesized, which shows high storage capacity for C2 light hydrocarbons and good adsorption selectivity for C3/C1 and C2/C1 at room temperature.

A stable zinc-4-carboxypyrazole framework with high uptake and selectivity of light hydrocarbons

2015 ◽  
Vol 44 (6) ◽  
pp. 2893-2896 ◽  
Author(s):  
Hong-Ru Fu ◽  
Fei Wang ◽  
Jian Zhang
Keyword(s):  
Chemical Stability ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
High Uptake ◽  
Light Hydrocarbons ◽  
High Storage Capacity ◽  
Metal Organic ◽  
High Storage ◽  
Organic Framework

A metal–organic framework based on 4-carboxypyrazole ligands has been synthesized, and it shows unusual chemical stability and high storage capacity for C2 light hydrocarbons.

High storage capacity and separation selectivity for C2 hydrocarbons over methane in the metal–organic framework Cu–TDPAT

2014 ◽  
Vol 2 (38) ◽  
pp. 15823-15828 ◽  
Author(s):  
Kang Liu ◽  
Dingxuan Ma ◽  
Baiyan Li ◽  
Yi Li ◽  
Kexin Yao ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Enthalpy ◽  
High Storage Capacity ◽  
Metal Organic ◽  
High Adsorption Capacity ◽  
C2 Hydrocarbons ◽  
High Storage ◽  
Organic Framework

We report an rht-type metal–organic framework (MOF) which exhibits a high adsorption capacity for C2 hydrocarbons and excellent selectivity over CH4. This MOF displays the highest reported C2H2–CH4 selectivity of 127.1 as well as a record high value for C2H4 adsorption enthalpy (49.5 kJ mol−1).

A metal–organic framework functionalized with piperazine exhibiting enhanced CH4 storage

2017 ◽  
Vol 5 (1) ◽  
pp. 349-354 ◽  
Author(s):  
Mingxing Zhang ◽  
Cong Chen ◽  
Qian Wang ◽  
Wensheng Fu ◽  
Kunlin Huang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic ◽  
Organic Framework ◽  
Ch4 Storage

NJU-Bai 19, the first cycloaliphatic ring (piperazine) functionalized MOF-505 analogue, exhibits a notably high methane storage capacity of 246 cm3 (STP) cm−3 (at room temperature and 65 bar) and a working capacity of 185 cm3 (STP) cm−3.

A nitro-decorated NbO-type metal–organic framework with a highly selective CO2 uptake and CH4 storage capacity

CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6287-6290 ◽  
Author(s):  
Mingxing Zhang ◽  
Qian Wang ◽  
Zhiyong Lu ◽  
Huiyan Liu ◽  
Wenlong Liu ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Co2 Uptake ◽  
Adsorption Selectivity ◽  
Total Uptake ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework ◽  
Ch4 Storage

A nitro-decorated and highly porous metal–organic framework with NbO topology was reported, exhibiting good adsorption selectivity of CO2/CH4 (8) and CO2/N2 (24) at 273 K and 1 bar, high methane total uptake of 184 cm3 cm−3 at 290 K and 35 bar.

A microporous yttrium metal–organic framework of an unusual nia topology for high adsorption selectivity of C2H2and CO2over CH4at room temperature

2017 ◽  
Vol 1 (10) ◽  
pp. 1982-1988 ◽  
Author(s):  
Kang Liu ◽  
Xu Li ◽  
Dingxuan Ma ◽  
Yi Han ◽  
Baiyan Li ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Selectivity ◽  
Basic Sites ◽  
Metal Organic ◽  
Organic Framework

A new microporous yttrium MOF Y-H3TDPAT with Lewis basic sites on the pore surfaces was hydrothermally synthesized and structurally characterized as an unusualniatopology.

A novel metal-organic framework for high storage and separation of acetylene at room temperature

2016 ◽  
Vol 241 ◽  
pp. 152-156 ◽  
Author(s):  
Xing Duan ◽  
Huizhen Wang ◽  
Zhenguo Ji ◽  
Yuanjing Cui ◽  
Yu Yang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
High Storage ◽  
Organic Framework

A new NbO type metal–organic framework for high acetylene and methane storage

RSC Advances ◽  
2015 ◽  
Vol 5 (103) ◽  
pp. 84446-84450 ◽  
Author(s):  
Xing Duan ◽  
Huizhen Wang ◽  
Yuanjing Cui ◽  
Yu Yang ◽  
Zhiyu Wang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Methane Storage ◽  
Metal Organic ◽  
Organic Framework

A novel NbO-type metal–organic framework (ZJU-9) has been designed and synthesized, exhibiting high acetylene and methane storage capacity at room temperature.

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