High storage capacity and separation selectivity for C2 hydrocarbons over methane in the metal–organic framework Cu–TDPAT

2014 ◽  
Vol 2 (38) ◽  
pp. 15823-15828 ◽  
Author(s):  
Kang Liu ◽  
Dingxuan Ma ◽  
Baiyan Li ◽  
Yi Li ◽  
Kexin Yao ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Enthalpy ◽  
High Storage Capacity ◽  
Metal Organic ◽  
High Adsorption Capacity ◽  
C2 Hydrocarbons ◽  
High Storage ◽  
Organic Framework

We report an rht-type metal–organic framework (MOF) which exhibits a high adsorption capacity for C2 hydrocarbons and excellent selectivity over CH4. This MOF displays the highest reported C2H2–CH4 selectivity of 127.1 as well as a record high value for C2H4 adsorption enthalpy (49.5 kJ mol−1).

A stable zinc-4-carboxypyrazole framework with high uptake and selectivity of light hydrocarbons

2015 ◽  
Vol 44 (6) ◽  
pp. 2893-2896 ◽  
Author(s):  
Hong-Ru Fu ◽  
Fei Wang ◽  
Jian Zhang
Keyword(s):  
Chemical Stability ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
High Uptake ◽  
Light Hydrocarbons ◽  
High Storage Capacity ◽  
Metal Organic ◽  
High Storage ◽  
Organic Framework

A metal–organic framework based on 4-carboxypyrazole ligands has been synthesized, and it shows unusual chemical stability and high storage capacity for C2 light hydrocarbons.

PPI-Dendrimer-Functionalized Magnetic Metal–Organic Framework (Fe3O4@MOF@PPI) with High Adsorption Capacity for Sustainable Wastewater Treatment

2020 ◽  
Vol 12 (22) ◽  
pp. 25294-25303 ◽  
Author(s):  
Hossein Shahriyari Far ◽  
Mahdi Hasanzadeh ◽  
Mohammad Shabani Nashtaei ◽  
Mahboubeh Rabbani ◽  
Aminoddin Haji ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Adsorption Capacity ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Magnetic Metal ◽  
Metal Organic ◽  
High Adsorption Capacity ◽  
Sustainable Wastewater Treatment ◽  
Organic Framework

A pillared-layer framework with high uptake and selective sorption of light hydrocarbons

2016 ◽  
Vol 45 (16) ◽  
pp. 7004-7007 ◽  
Author(s):  
Qing-Rong Ding ◽  
Fei Wang
Keyword(s):  
Room Temperature ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
High Uptake ◽  
Light Hydrocarbons ◽  
Adsorption Selectivity ◽  
Selective Sorption ◽  
High Storage Capacity ◽  
Metal Organic ◽  
High Storage

A pillared-layer metal–organic framework was successfully synthesized, which shows high storage capacity for C2 light hydrocarbons and good adsorption selectivity for C3/C1 and C2/C1 at room temperature.

Integrating multiple adsorption sites and tortuous diffusion paths into a metal–organic framework for C3H4/C3H6 separation

2019 ◽  
Vol 7 (44) ◽  
pp. 25254-25257 ◽  
Author(s):  
Xue-Qian Wu ◽  
Yabo Xie ◽  
Jing-Hao Liu ◽  
Tao He ◽  
Yong-Zheng Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Sites ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Diffusion Paths ◽  
High Adsorption Capacity ◽  
Multiple Adsorption ◽  
Excellent Selectivity ◽  
Organic Framework

By integrating open metal sites, Lewis basic sites, and tortuous diffusion paths, a new metal–organic framework has been designed and synthesized, which exhibits high adsorption capacity and excellent selectivity for separating a C3H4/C3H6 mixture.

scholarly journals High CO2 Adsorption Enthalpy Enabled by Uncoordinated N-Heteroatom Sites of a 3D Metal-Organic Framework

2019 ◽  
Vol 2019 ◽  
pp. 1-5 ◽  
Author(s):  
Yongting Zhao ◽  
Yiming Xie
Keyword(s):  
Room Temperature ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
X Ray Diffraction ◽  
High Adsorption ◽  
Adsorption Enthalpy ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

A 3D metal-organic framework (MOF), Mn2L2(H2O)2 · (DMF) {H2L = 5- (Pyridin-2-yl)-3, 3′-bi (1H-1,2,4-triazole)} (1) with uncoordinated N-heteroatom sites, has been obtained through hydrothermal method and structurally characterized by X-ray structural analysis, powder X-ray diffraction (PXRD), and thermal analysis (TGA). The framework of compound 1 exhibits fascinating adsorption properties and shows high adsorption enthalpy of CO2. The experimental results prove which uncoordinated nitrogen heteroatom sites can markedly increase the reciprocity between host frame and CO2 at room temperature.

High Adsorption Capacity and Selectivity of SO2 over CO2 in a Metal–Organic Framework

2020 ◽  
Vol 60 (1) ◽  
pp. 4-8
Author(s):  
Ya Ling Fan ◽  
Hui Ping Zhang ◽  
Meng Jia Yin ◽  
Rajamani Krishna ◽  
Xue Feng Feng ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Metal Organic Framework ◽  
High Adsorption ◽  
Metal Organic ◽  
High Adsorption Capacity ◽  
Organic Framework
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