A stable zinc-4-carboxypyrazole framework with high uptake and selectivity of light hydrocarbons

A metal–organic framework based on 4-carboxypyrazole ligands has been synthesized, and it shows unusual chemical stability and high storage capacity for C2 light hydrocarbons.

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A pillared-layer framework with high uptake and selective sorption of light hydrocarbons

Dalton Transactions ◽

10.1039/c6dt00238b ◽

2016 ◽

Vol 45 (16) ◽

pp. 7004-7007 ◽

Cited By ~ 13

Author(s):

Qing-Rong Ding ◽

Fei Wang

Keyword(s):

Room Temperature ◽

Storage Capacity ◽

Metal Organic Framework ◽

High Uptake ◽

Light Hydrocarbons ◽

Adsorption Selectivity ◽

Selective Sorption ◽

High Storage Capacity ◽

Metal Organic ◽

High Storage

A pillared-layer metal–organic framework was successfully synthesized, which shows high storage capacity for C2 light hydrocarbons and good adsorption selectivity for C3/C1 and C2/C1 at room temperature.

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High storage capacity and separation selectivity for C2 hydrocarbons over methane in the metal–organic framework Cu–TDPAT

Journal of Materials Chemistry A ◽

10.1039/c4ta03656e ◽

2014 ◽

Vol 2 (38) ◽

pp. 15823-15828 ◽

Cited By ~ 74

Author(s):

Kang Liu ◽

Dingxuan Ma ◽

Baiyan Li ◽

Yi Li ◽

Kexin Yao ◽

...

Keyword(s):

Storage Capacity ◽

Metal Organic Framework ◽

High Adsorption ◽

Adsorption Enthalpy ◽

High Storage Capacity ◽

Metal Organic ◽

High Adsorption Capacity ◽

C2 Hydrocarbons ◽

High Storage ◽

Organic Framework

We report an rht-type metal–organic framework (MOF) which exhibits a high adsorption capacity for C2 hydrocarbons and excellent selectivity over CH4. This MOF displays the highest reported C2H2–CH4 selectivity of 127.1 as well as a record high value for C2H4 adsorption enthalpy (49.5 kJ mol−1).

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In-Situ Ligand Formation-Driven Preparation of a Heterometallic Metal–Organic Framework for Highly Selective Separation of Light Hydrocarbons and Efficient Mercury Adsorption

ACS Applied Materials & Interfaces ◽

10.1021/acsami.6b08397 ◽

2016 ◽

Vol 8 (35) ◽

pp. 23331-23337 ◽

Cited By ~ 45

Author(s):

Yi Han ◽

Hao Zheng ◽

Kang Liu ◽

Hongli Wang ◽

Hongliang Huang ◽

...

Keyword(s):

Metal Organic Framework ◽

Selective Separation ◽

Light Hydrocarbons ◽

Mercury Adsorption ◽

Metal Organic ◽

Organic Framework

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A heterometallic metal–organic framework based on multi-nuclear clusters exhibiting high stability and selective gas adsorption

Dalton Transactions ◽

10.1039/c8dt03826k ◽

2019 ◽

Vol 48 (1) ◽

pp. 278-284 ◽

Cited By ~ 12

Author(s):

Dongmei Wang ◽

Zihua Liu ◽

Lili Xu ◽

Chunxia Li ◽

Dian Zhao ◽

...

Keyword(s):

Chemical Stability ◽

High Performance ◽

High Stability ◽

Gas Adsorption ◽

Metal Organic Framework ◽

Gas Storage ◽

Nuclear Clusters ◽

Metal Organic ◽

Thermal And Chemical Stability ◽

Organic Framework

Porous In/Tb-CBDA has been successfully synthesized in the light of the heterometallic cooperative crystallization (HCC) approach. In/Tb-CBDA with high thermal and chemical stability exhibited high performance for gas storage and separation.

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A metal–organic framework functionalized with piperazine exhibiting enhanced CH4 storage

Journal of Materials Chemistry A ◽

10.1039/c6ta06037d ◽

2017 ◽

Vol 5 (1) ◽

pp. 349-354 ◽

Cited By ~ 25

Author(s):

Mingxing Zhang ◽

Cong Chen ◽

Qian Wang ◽

Wensheng Fu ◽

Kunlin Huang ◽

...

Keyword(s):

Room Temperature ◽

Storage Capacity ◽

Metal Organic Framework ◽

Methane Storage ◽

Working Capacity ◽

Metal Organic ◽

Organic Framework ◽

Ch4 Storage

NJU-Bai 19, the first cycloaliphatic ring (piperazine) functionalized MOF-505 analogue, exhibits a notably high methane storage capacity of 246 cm3 (STP) cm−3 (at room temperature and 65 bar) and a working capacity of 185 cm3 (STP) cm−3.

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