The influence of halides in polyoxotitanate cages; dipole moment, splitting and expansion of d-orbitals and electron–electron repulsion

The influence of halides on the electronic structures of polyoxotitanate cages is explored in this experimental and theoretical study. Dipole moment, crystal-field splitting, Nephelauxetic influence of the halide and electron–electron repulsion all play a role.

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Electronic structures of organometallic complexes of f elements LXXIII: Parametric analysis of the crystal field splitting pattern of tris(η5-pentamethylcyclopentadienyl)cerium(III)

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2010.02.018 ◽

2010 ◽

Vol 695 (9) ◽

pp. 1293-1299 ◽

Cited By ~ 10

Author(s):

Hanns-Dieter Amberger ◽

Hauke Reddmann ◽

Thomas J. Mueller ◽

William J. Evans

Keyword(s):

Crystal Field ◽

Electronic Structures ◽

Parametric Analysis ◽

Organometallic Complexes ◽

Crystal Field Splitting ◽

Field Splitting

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Electronic structures of organometallic complexes of f elements LXXIX: Truncated crystal field splitting patterns of monomeric pseudo trigonal planar Yb(η5-C5H4R)3 (R = Me, Et, tBu, SiMe3) complexes and polymeric [(η5-C5H5)2Yb(μ-η5:η1-C5H5)] as well as selected mono adducts

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2012.06.008 ◽

2012 ◽

Vol 716 ◽

pp. 138-145 ◽

Cited By ~ 4

Author(s):

Hanns-Dieter Amberger ◽

Hauke Reddmann ◽

Guokui Liu

Keyword(s):

Crystal Field ◽

Electronic Structures ◽

Organometallic Complexes ◽

Crystal Field Splitting ◽

Field Splitting

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Electronic structures of organometallic complexes of f elements. XLIV. Parametrization of the crystal field splitting pattern of [(MeCp)3PrCl]−

Journal of Alloys and Compounds ◽

10.1016/s0925-8388(98)00332-6 ◽

1998 ◽

Vol 275-277 ◽

pp. 323-326 ◽

Cited By ~ 7

Author(s):

B. Unrecht ◽

H. Reddmann ◽

H.-D. Amberger

Keyword(s):

Crystal Field ◽

Electronic Structures ◽

Organometallic Complexes ◽

Crystal Field Splitting ◽

Field Splitting

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Electronic structures and crystal field splitting of antiperovskite XNMn 3 (X = 3 d and 4 d elements)

Computational Materials Science ◽

10.1016/j.commatsci.2017.02.026 ◽

2017 ◽

Vol 132 ◽

pp. 132-136 ◽

Cited By ~ 1

Author(s):

Shaohua Chen ◽

Peng Tong ◽

Jie Wu ◽

Wei-Hua Wang ◽

Weichao Wang

Keyword(s):

Crystal Field ◽

Electronic Structures ◽

Crystal Field Splitting ◽

Field Splitting

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Electronic Structures of Organometallic Complexes of f Elements. 62 Parametric Analysis of the Crystal Field Splitting Pattern of Pseudo Trigonal Planar Nd(η5-C5Me4H)3

Zeitschrift für anorganische und allgemeine Chemie ◽

10.1002/zaac.200600146 ◽

2006 ◽

Vol 632 (12-13) ◽

pp. 1953-1955 ◽

Cited By ~ 7

Author(s):

Hauke Reddmann ◽

Mirosław Karbowiak ◽

Hanns-Dieter Amberger ◽

Janusz Drożdżyński

Keyword(s):

Crystal Field ◽

Electronic Structures ◽

Parametric Analysis ◽

Organometallic Complexes ◽

Crystal Field Splitting ◽

Field Splitting

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Crystal-Field Splitting of Orthohydrogen in Solid Parahydrogen

Physical Review Letters ◽

10.1103/physrevlett.19.1417 ◽

1967 ◽

Vol 19 (25) ◽

pp. 1417-1420 ◽

Cited By ~ 38

Author(s):

Walter N. Hardy ◽

James R. Gaines

Keyword(s):

Crystal Field ◽

Crystal Field Splitting ◽

Field Splitting

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The influence of nd0 transition metal cations on the Eu3+ asymmetry ratio R=I(5D0−7F2)I(5D0−7F1) and crystal field splitting of 7F1 manifold in pyrochlore and zircon compounds

Optical Materials ◽

10.1016/j.optmat.2021.110931 ◽

2021 ◽

Vol 114 ◽

pp. 110931

Author(s):

A.M. Srivastava ◽

M.G. Brik ◽

W.W. Beers ◽

W. Cohen

Keyword(s):

Transition Metal ◽

Crystal Field ◽

Metal Cations ◽

Crystal Field Splitting ◽

Asymmetry Ratio ◽

Transition Metal Cations ◽

Field Splitting

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Crystal-field splitting of the Cr4+ terms in LiAlO2 oxide crystal

Journal of Luminescence ◽

10.1016/j.jlumin.2003.10.002 ◽

2004 ◽

Vol 106 (3-4) ◽

pp. 205-210 ◽

Cited By ~ 15

Author(s):

Souha Kammoun

Keyword(s):

Crystal Field ◽

Crystal Field Splitting ◽

Field Splitting ◽

Oxide Crystal

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An explanation of the 1D2 anomalous crystal field splitting in PrCl3

The Journal of Chemical Physics ◽

10.1063/1.456431 ◽

1989 ◽

Vol 90 (10) ◽

pp. 5280-5283 ◽

Cited By ~ 52

Author(s):

D. Garcia ◽

M. Faucher

Keyword(s):

Crystal Field ◽

Crystal Field Splitting ◽

Field Splitting

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Magnetic Anisotropy in Single Crystals of Zn–Mn and Zn–Cr

Canadian Journal of Physics ◽

10.1139/p74-233 ◽

1974 ◽

Vol 52 (18) ◽

pp. 1759-1764 ◽

Cited By ~ 13

Author(s):

F. T. Hedgcock ◽

S. Lenis ◽

P. L. Li ◽

J. O. Ström-Olsen ◽

E. F. Wassermann

Keyword(s):

Low Temperature ◽

Magnetic Fields ◽

Magnetic Anisotropy ◽

Single Crystals ◽

Crystal Field ◽

Interaction Effects ◽

Crystal Field Splitting ◽

High Magnetic Fields ◽

Field Splitting ◽

Chromium Ion

We have extended the low temperature magnetic anisotropy measurements on single crystals of zinc containing up to 600 p.p.m. manganese from magnetic fields of 9 to 56 kG. The crystal field splitting parameters determined at low magnetic fields also characterizes the magnetic anisotropy at high magnetic fields. Manganese–manganese interaction effects are observed in the magnetic anisotropy at manganese concentrations greater than 300 p.p.m. Low temperature magnetic anisotropy measurements on single crystals of zinc containing up to 164 p.p.m. chromium are reported and indicate a crystal field splitting of 0.16 K for the chromium ion.

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