scholarly journals Synthesis, optoelectronic properties and photovoltaic performances of wide band-gap copolymers based on dibenzosilole and quinoxaline units, rivals to P3HT

2016 ◽  
Vol 7 (25) ◽  
pp. 4160-4175 ◽  
Author(s):  
F. Caffy ◽  
N. Delbosc ◽  
P. Chávez ◽  
P. Lévêque ◽  
J. Faure-Vincent ◽  
...  

Dibenzosilole and quinoxaline based copolymers were synthesized and tested in bulk-heterojunction solar cells showing power conversion efficiencies up to 5.14%.

2017 ◽  
Vol 5 (2) ◽  
pp. 712-719 ◽  
Author(s):  
Woosung Lee ◽  
Jae Woong Jung

A novel wide band gap polymer (PIDTT-TT) has been synthesized to use in efficient polymer solar cells with power conversion efficiencies up to 7.10%.


2017 ◽  
Vol 5 (38) ◽  
pp. 9920-9928 ◽  
Author(s):  
Duško Popović ◽  
Ibrahim Ata ◽  
Johannes Krantz ◽  
Sebastian Lucas ◽  
Mika Lindén ◽  
...  

A series of A–D–A type co-oligomers used as donors in organic solar cells are presented. Devices prepared exclusively from non-halogenated solvents via doctor-blading gave power conversion efficiencies of up to 7%.


Author(s):  
Lijun Su ◽  
Maria Méndez ◽  
Miaoli Zhu ◽  
Yaoming Xiao ◽  
Emilio J. Palomares

Our work analyses for the first time the kinetics of perovskite/organic photovoltaic (OPV) interface with different perovskite I/Br ratios (MAPbI3-xBrx, x=0, 1, 2, and 3) and PM6:Y6 as bulk heterojunction...


2016 ◽  
Vol 4 (17) ◽  
pp. 3715-3725 ◽  
Author(s):  
Christoph Wetzel ◽  
Amaresh Mishra ◽  
Elena Mena-Osteritz ◽  
Karsten Walzer ◽  
Martin Pfeiffer ◽  
...  

A new class of A–D–A molecular donor materials based on planar S,N-heterohexacenes is developed for vacuum-processed planar and bulk-heterojunction solar cells providing promising power conversion efficiencies up to 7.1%.


2021 ◽  
Vol 03 (02) ◽  
pp. 168-173
Author(s):  
Lukas Ahrens ◽  
Yvonne J. Hofstetter ◽  
Baris Celik ◽  
Julian F. Butscher ◽  
Frank Rominger ◽  
...  

Two covalently linked triisopropylsilyl-ethynylated phenazinothiadiazoles were prepared through condensation of a spirocyclic and a bicyclic tetraketone with a 5,6-diaminobenzothiadiazole. The spirobisindene- and the ethanoanthracene-based linkers render the electron acceptors amorphous in thin films. The optoelectronic properties of the non-conjugated dimers are indistinguishable from that of the crystalline monomer. Bulk heterojunction solar cells were prepared with power conversion efficiencies peaking at 1.6%. The choice of linker neither influenced optical and electrochemical properties nor device performance.


2019 ◽  
Vol 7 (6) ◽  
pp. 2754-2763 ◽  
Author(s):  
Jieming Zhen ◽  
Weiran Zhou ◽  
Muqing Chen ◽  
Bairu Li ◽  
Lingbo Jia ◽  
...  

A novel pyridine-functionalized fullerene derivative (C60-PyP) as an additive in regular bulk heterojunction perovskite (CH3NH3Pbl3) solar cells (PSCs) enables a power conversion efficiency of 19.82% with markedly suppressed hysteresis.


2007 ◽  
Vol 91 (9) ◽  
pp. 757-763 ◽  
Author(s):  
Sukhbinder Rait ◽  
Shipra Kashyap ◽  
P.K. Bhatnagar ◽  
P.C. Mathur ◽  
S.K. Sengupta ◽  
...  

2004 ◽  
Vol 822 ◽  
Author(s):  
Robert S. Echols ◽  
Chris E. France

AbstractWe investigate the behavior of a polymer blend (M3EH-PPV:CN-ether-PPV) bulk heterojunction solar cell using a numeric model that self-consistently solves Poisson's equation and the charge continuity equation while incorporating electric field dependent mobilities. We obtain good quantitative agreement with present experimental data for J-V curves and photocurrent action spectra. To reproduce experimental photocurrent action spectra, our model predicts 36% exciton dissociation efficiencies in the bulk of the polymer. We also study the limiting conditions of polymer solar cell development by simulating an ideal solar cell using an AM1.5 global spectrum and assuming all absorbed photons hitting a M3EH-PPV:CN-ether-PPV polymer blend (band gap ∼2.0 eV) based solar cell at normal incidence contribute to current. If such a solar cell has 100 nm length, open circuit voltage=0.6 V and 50% fill factor, then the maximum theoretical power conversion efficiency is ηp=5.6%. A similar analysis for a M3EH-PPV:PCBM bulk heterojunction cell yields, ηp=3.5%. These results further highlight the need to develop smaller band gap materials and help explain why the best polymer based solar cells have power conversion efficiencies that remain stuck at about 3%. Our model is used to investigate the important increase in power conversion efficiencies we can expect as lower band gap polymers become available.


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