Investigation on the growth, structural, HOMO–LUMO and optical studies of 1-ethyl-2-[2-(4-hydroxy-phenyl)-vinyl]-pyridinium iodide (HSPI) – a new stilbazolium derivative for third-order NLO applications

RSC Advances ◽  
2016 ◽  
Vol 6 (42) ◽  
pp. 35977-35990 ◽  
Author(s):  
K. Nivetha ◽  
S. Kalainathan ◽  
Manabu Yamada ◽  
Yoshihiko Kondo ◽  
Fumio Hamada

The organic third-order non-linear optical crystal HSPI, a new derivative of the stilbazolium family, was successfully synthesized and the optical quality single crystal was grown by a slow evaporation technique for the first time.

RSC Advances ◽  
2016 ◽  
Vol 6 (39) ◽  
pp. 33159-33169 ◽  
Author(s):  
S. Karthigha ◽  
S. Kalainathan ◽  
Fumio Hamada ◽  
Manabu Yamada ◽  
Yoshihiko Kondo

N-Ethyl quinolinium chromophore crystal 2-[2-(4-chloro-phenyl)-vinyl]-1-ethyl-quinolinium iodide (PCLQI) has been successfully grown by the slow evaporation technique.


2015 ◽  
Vol 2 (2) ◽  
pp. 102-104
Author(s):  
Sakthi.P ◽  
Rajasekaran.R

Sodium thiourea nitrate (STN) a semi organic optical crystal was grown by slow evaporation technique at room temperature. The cell parameter value and crystal structure was determined Single crystal Xray diffraction study. Presence functional group was identified FTIR study. The cut-off wavelength was determined UV-visible transmission spectrum study. The mechanical strength was analysis using Vicker’s microhardness test.


2021 ◽  
Vol 3 (1) ◽  
pp. 13-20
Author(s):  
Mohanraj V ◽  
Ilango S.S. ◽  
Ponnuswamy S

The single crystal of cis-2,6-bis(4-chlorophenyl)-3,3-dimethylpiperidin-4-one (4C3DMPO) has been grown using a slow evaporation technique. 4C3DMPO is a non-centrosymmetric crystal which crystallizes in the orthorhombic system with space group Pna21. Benzene is used as a solvent for the crystal growth based on solubility studies. The mechanical studies, using microhardness methods, have also been carried out. The compound is characterised using UV, FT-IR and NMR spectral studies. Furthermore, the thermal stability of the crystal is established by TG/DTA. The nonlinear optical studies (SHG) of the crystal have been determined using the Kurtz and Perry powder technique and the activity observed is 2.5 times greater than that of KDP.


2019 ◽  
Vol 1 (1) ◽  
pp. 42-45
Author(s):  
Tamiloli Devendhiran ◽  
Keerthika Kumarasamy ◽  
Mei–Ching Lin

Single crystals of 2-Aminothiazole 3,5-Dinitrobenzoic acid has been synthesized and good quality optical crystals were grown by slow evaporation technique at room temperature. The crystallinity nature of the grown crystal was confirmed from X-ray diffraction technique. An optical transmittance study was also carried out by UV – Vis spectra. FTIR spectra confirm the presence of functional groups in the grown crystal. The dielectric measurements were carried out in the range of 50Hz to 2MHz. The dielectric constant was seen to increase exponentially at lower frequencies. The microhardness studies were carried out using Vickers hardness indenter. Photoluminescence study shows that maximum emission occurs at 435nm.


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