POSS-based meso-/macroporous covalent networks: supporting and stabilizing Pd for Suzuki–Miyaura reaction at room temperature

RSC Advances ◽  
2016 ◽  
Vol 6 (62) ◽  
pp. 57183-57189 ◽  
Author(s):  
Chenjun Zhang ◽  
Yan Leng ◽  
Pingping Jiang ◽  
Dan Lu
Keyword(s):  
Schiff Base ◽  
Room Temperature ◽  
Pd Catalyst ◽  
Terephthalic Aldehyde ◽  
Organic Networks

Porous covalent organic networks synthesized by Schiff base chemistry reaction of POSS and terephthalic aldehyde could serve as both supports and stabilizers for Pd catalyst, which exhibited excellent performances for Suzuki-Miyaura reactions.

Synthesis, structural characterization and catalytic activity of chlororuthenium(II) complexes with substituted Schiff base/phosphine ancillary ligands

2020 ◽  
Vol 75 (9-10) ◽  
pp. 851-857
Author(s):  
Chong Chen ◽  
Fule Wu ◽  
Jiao Ji ◽  
Ai-Quan Jia ◽  
Qian-Feng Zhang
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Structural Characterization ◽  
Room Temperature ◽  
Molecular Structures ◽  
Cationic Complex ◽  
Neutral Complex ◽  
Ancillary Ligands ◽  
X Ray ◽  
X Ray Crystallography

AbstractTreatment of [(η6-p-cymene)RuCl2]2 with one equivalent of chlorodiphenylphosphine in tetrahydrofuran at reflux afforded a neutral complex [(η6-p-cymene)RuCl2(κ1-P-PPh2OH)] (1). Similarly, the reaction of [Ru(bpy)2Cl2·2H2O] (bpy = 2,2′-bipyridine) and chlorodiphenylphosphine in methanol gave a cationic complex [Ru(bpy)2Cl(κ1-P-PPh2OCH3)](PF6) (2), while treatment of [RuCl2(PPh3)3] with [2-(C5H4N)CH=N(CH2)2N(CH3)2] (L1) in tetrahydrofuran at room temperature afforded a ruthenium(II) complex [Ru(PPh3)Cl2(κ3-N,N,N-L1)] (3). Interaction of the chloro-bridged complex [Ru(CO)2Cl2]n with one equivalent of [Ph2P(o-C6H4)CH=N(CH2)2N(CH3)2] (L2) led to the isolation of [Ru(CO)Cl2(κ3-P,N,N-L2)] (4). The molecular structures of the ruthenium(II) complexes 1–4 have been determined by single-crystal X-ray crystallography. The properties of the ruthenium(II) complex 4 as a hydrogenation catalyst for acetophenone were also tested.

A Schiff Base Modified Pd Catalyst for Selective Hydrogenation of 2-Butyne-1,4-diol to 2-Butene-1,4-diol

2020 ◽  
Vol 150 (8) ◽  
pp. 2150-2157
Author(s):  
Haomeng Li ◽  
Xinkui Wang ◽  
Xiao Chen ◽  
Chuang Li ◽  
Min Wang ◽  
...  
Keyword(s):  
Schiff Base ◽  
Selective Hydrogenation ◽  
Pd Catalyst

Palladium-Schiff-base-silica framework as a robust and recyclable catalyst for Suzuki–Miyaura cross-coupling in aqueous media

RSC Advances ◽  
2015 ◽  
Vol 5 (48) ◽  
pp. 38085-38092 ◽  
Author(s):  
Tahshina Begum ◽  
Manoj Mondal ◽  
Pradip K. Gogoi ◽  
Utpal Bora
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Room Temperature ◽  
Aqueous Media ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Recyclable Catalyst ◽  
Cross Coupling Reaction

A novel Pd@imine-SiO2 catalyst was prepared and found to exhibit excellent catalytic activity in a Suzuki-Miyaura cross-coupling reaction under aqueous media at room temperature.

scholarly journals Low Temperature Chemoselective Hydrogenation of Aldehydes over a Magnetic Pd Catalyst

2019 ◽  
Vol 9 (9) ◽  
pp. 1792
Author(s):  
Liu ◽  
Wang ◽  
Gao ◽  
Wang ◽  
Cheng ◽  
...  
Keyword(s):  
Low Temperature ◽  
Room Temperature ◽  
Heterogeneous Catalysts ◽  
Aromatic Aldehydes ◽  
Pd Catalyst ◽  
Primary Alcohols ◽  
Mild Conditions ◽  
Excellent Yield ◽  
Chemoselective Hydrogenation ◽  
Supported Palladium

Chemoselective hydrogenation of aldehydes with heterogeneous catalysts under mild conditions is of great importance but remains a major challenge. Herein, an efficient strategy was developed for low temperature chemoselective hydrogenation of aldehydes with broad substrate scope over a magnetic material supported palladium catalyst (γ-Fe2O3@HAP-Pd). Aldehydes bearing various reducible functional groups readily underwent hydrogenation to give the corresponding primary alcohols with moderate to excellent yield at room temperature in aqueous solutions. The Hammett equation revealed that the hydrogenation of aromatic aldehydes proceeded via an anionic intermediate. Additionally, when the temperature increased to 70 °C, toluene was obtained by the deoxygenation of benzaldehyde in excellent yield. Furthermore, the γ-Fe2O3@HAP-Pd could be recycled up to six times without loss of activity and metal leaching.

Tunable Emissive Lanthanidomesogen Derived from a Room-Temperature Liquid-Crystalline Schiff-Base Ligand

2013 ◽  
Vol 19 (39) ◽  
pp. 13151-13159 ◽  
Author(s):  
Harun A. R. Pramanik ◽  
Gobinda Das ◽  
Chira R. Bhattacharjee ◽  
Pradip C. Paul ◽  
Paritosh Mondal ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Liquid Crystalline ◽  
Room Temperature ◽  
Temperature Liquid
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