scholarly journals Reinforcing biofiller “Lignin” for high performance green natural rubber nanocomposites

RSC Advances ◽  
2017 ◽  
Vol 7 (9) ◽  
pp. 5222-5231 ◽  
Author(s):  
Yuko Ikeda ◽  
Treethip Phakkeeree ◽  
Preeyanuch Junkong ◽  
Hiroyuki Yokohama ◽  
Pranee Phinyocheep ◽  
...  

High performance eco-friendly natural rubber biocomposites with various contents up to 40 parts per one hundred rubber by weight of lignin were successfully prepared from sodium lignosulfonate and natural rubber latex using the soft process.

2004 ◽  
Vol 70 (12) ◽  
pp. 7388-7395 ◽  
Author(s):  
Reinhard Braaz ◽  
Peter Fischer ◽  
Dieter Jendrossek

ABSTRACT An extracellular protein with strong absorption at 406 nm was purified from cell-free culture fluid of latex-grown Xanthomonas sp. strain 35Y. This protein was identical to the gene product of a recently characterized gene cloned from Xanthomonas sp., as revealed by determination of m/z values and sequencing of selected isolated peptides obtained after trypsin fingerprint analysis. The purified protein degraded both natural rubber latex and chemosynthetic poly(cis-1,4-isoprene) in vitro by oxidative cleavage of the double bonds of poly(cis-1,4-isoprene). 12-Oxo-4,8-dimethyltrideca-4,8-diene-1-al (m/z 236) was identified and unequivocally characterized as the major cleavage product, and there was a homologous series of minor metabolites that differed from the major degradation product only in the number of repetitive isoprene units between terminal functions, CHO-CH2— and —CH2-COCH3. An in vitro enzyme assay for oxidative rubber degradation was developed based on high-performance liquid chromatography analysis and spectroscopic detection of product carbonyl functions after derivatization with dinitrophenylhydrazone. Enzymatic cleavage of rubber by the purified protein was strictly dependent on the presence of oxygen; it did not require addition of any soluble cofactors or metal ions and was optimal around pH 7.0 at 40°C. Carbon monoxide and cyanide inhibited the reaction; addition of catalase had no effect, and peroxidase activity could not be detected. The purified protein was specific for natural rubber latex and chemosynthetic poly(cis-1,4-isoprene). Analysis of the amino acid sequence deduced from the cloned gene (roxA [rubber oxygenase]) revealed the presence of two heme-binding motifs (CXXCH) for covalent attachment of heme to the protein. Spectroscopic analysis confirmed the presence of heme, and approximately 2 mol of heme per mol of RoxA was found.


Nanoscale ◽  
2017 ◽  
Vol 9 (27) ◽  
pp. 9510-9519 ◽  
Author(s):  
Alireza Hosseinmardi ◽  
Pratheep K. Annamalai ◽  
Lianzhou Wang ◽  
Darren Martin ◽  
Nasim Amiralian

Remnant lignin and hemicellulose in the cellulose nanofibre (CNF) and a deep-eutectic-solvent pretreatment on CNF can enhace the tensile strength and toughness or natural rubber nanocomposites.


2008 ◽  
Vol 81 (4) ◽  
pp. 709-722 ◽  
Author(s):  
Katrina Cornish ◽  
Jali Williams ◽  
Julie L. Hall ◽  
Raymond G. McCoy

Abstract Natural rubber is an irreplaceable raw material vital to industry, transportation, medicine and defense, largely produced from clonal plantations of Hevea brasiliensis in Southeast Asia. Additional rubber-producing crops are greatly desired to increase biodiversity, protect supplies, and provide a safe alternative for people suffering from Type I latex protein allergy. Basic and applied research approaches were used to make the production of latex (Yulex® latex) from Parthenium argentatum (guayule) a commercial reality. In contrast to Hevea brasiliensis, from which rubber latex is tapped by hand from laticifers, guayule latex rubber is contained within individual bark parenchyma cells. Processing involves disrupting these cells to release the rubber particles, and then purifying the latex. As in the Hevea industry, latex concentration can be achieved by centrifugation and/or by creaming agents. An artificially produced guayule natural rubber latex is then produced, under the material name of “Yulex® latex”. The Yulex Pilot Plant has been constructed, optimized and automated, and extracts then purifies latex from guayule shrub without detectable losses. The natural rubber polymers in guayule latex are high molecular weight and products made from this material have the desired high performance properties. Because guayule latex contains very little protein, all of which is hydrophobic and bound to the rubber phase, and because none of the protein cross-reacts with Type I latex allergy to Hevea latex products, its use is initially aimed towards the high-value medical products marketplace. Clinical and performance trials continue to ensure that guayule processing provides a safe, high performance, non-allergenic natural rubber latex that is safe for human use.


2014 ◽  
Vol 879 ◽  
pp. 224-229
Author(s):  
Wan Mohd Faruq Wan Mohd Ridzwan ◽  
Dzaraini Kamarun ◽  
Azemi Samsuri ◽  
Ahmad Faiza Mohd ◽  
Che Mohd Som Said

Natural rubber (NR) latex is widely used in the manufacture of thin film barrier products such as gloves and condom. However, due to its low Tg, film casted from NR latex is soft and tacky, and needed to be strengthened to produced high performance products. Films of prevulcanized natural rubber latex (PVNR) blended with nanosized copolymer of n-butyl acrylate/butyl methacrylate (BA/BMA) were prepared at three different ratios of acrylate copolymer: PVNR. The tensile strength and elongation at break of films prepared decreased with increasing ratios of acrylate copolymer:PVNR. FESEM images showed the occurrence of agglomeration of the acrylate copolymers with PVNR molecules. The degree of agglomeration of the blended molecules increased with percentages of copolymer added. The decrease in the tensile strength and elongation at break may due to the agglomeration of the blended molecules suggesting poor dispersion and/or destabilization of PVNR molecules.


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