Insight into thin-film stacking modes of π-expanded quinoidal molecules on charge transport property via side-chain engineering

2017 ◽  
Vol 5 (8) ◽  
pp. 1935-1943 ◽  
Author(s):  
Cheng Zhang ◽  
Dafei Yuan ◽  
Hao Wu ◽  
Eliot Gann ◽  
Lars Thomsen ◽  
...  
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Charge Transport ◽  
Transport Properties ◽  
Transport Property ◽  
Organic Electronics ◽  
Side Chain ◽  
Conjugated Molecules ◽  
Molecular Ordering ◽  
Insight Into

Control of molecular ordering and packing of π-conjugated molecules in the solid state is crucial for enhancing the charge transport properties in organic electronics.

Creation of Face-to-face π-π Stacking of Fused Acene Backbones by Aryl-perfluoroaryl Interactions and Induction of Charge Transport Properties

2011 ◽  
Vol 1360 ◽  
Author(s):  
Toshihiro Okamoto ◽  
Katsumasa Nakahara ◽  
Akinori Saeki ◽  
Shu Seki ◽  
Joon H. Oh ◽  
...  
Keyword(s):  
Solid State ◽  
Charge Transport ◽  
Transport Properties ◽  
Organic Electronics ◽  
High Performance ◽  
Molecular Design ◽  
Structural Defects ◽  
Face To Face ◽  
Π Stacking ◽  
Organic Semiconducting Materials

ABSTRACTThe charge transport properties critically depend on the degree of ordering of the chains in the solid state as well as on the density of chemical or structural defects. In general, goodelectronic performance requires strong electronic coupling between adjace nt molecules in the solid-state that yield strong intermolecular π-overlap. Herein, we newly designed and synthesized organic semiconducting materials having both aryl (Ar) and perfluoroaryl (FAr) as substituents for organic electronics along with molecular packing control. Regarding this molecular design, we hypothesized and expected that the Ar and FAr substituents would induce well-defined π-π stacking structure of charge transport units for high performance organic electronics devices.

Correlating Charge Transport Properties of Conjugated Polymers in Solution Aggregates and Thin‐Film Aggregates

2021 ◽  
Author(s):  
Jian Pei ◽  
Zi-Yuan Wang ◽  
Lucia Di Virgilio ◽  
Ze-Fan Yao ◽  
Zi-Di Yu ◽  
...  
Keyword(s):  
Thin Film ◽  
Conjugated Polymers ◽  
Charge Transport ◽  
Transport Properties

scholarly journals Photophysical and charge transport properties of pyrazolines

RSC Advances ◽  
2016 ◽  
Vol 6 (1) ◽  
pp. 786-795 ◽  
Author(s):  
Joseph Ajantha ◽  
Elumalai Varathan ◽  
Vishal Bharti ◽  
Venkatesan Subramanian ◽  
Shanmugam Easwaramoorthi ◽  
...  
Keyword(s):  
Solid State ◽  
Charge Transport ◽  
Transport Properties ◽  
High Yields

Pyrazoline, an intense green emitting molecule both in solution and solid state, with extended π-conjugation has been synthesized via simple two-step reactions in high yields.

scholarly journals Corrigendum: Solid-State NMR Measurements of Asymmetric Dipolar Couplings Provide Insight into Protein Side-Chain Motion

2012 ◽  
Vol 51 (40) ◽  
pp. 9959-9959
Author(s):  
Paul Schanda ◽  
Matthias Huber ◽  
Jérôme Boisbouvier ◽  
Beat H. Meier ◽  
Matthias Ernst
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Dipolar Couplings ◽  
Side Chain ◽  
Side Chain Motion ◽  
Insight Into

Charge transport properties of co-evaporated organic–inorganic thin film charge transfer complexes: effects of intermolecular interactions

2020 ◽  
Vol 8 (47) ◽  
pp. 16725-16729
Author(s):  
Dong Shen ◽  
Yan Wu ◽  
Ming-Fai Lo ◽  
Chun-Sing Lee
Keyword(s):  
Thin Film ◽  
Charge Transfer ◽  
Charge Transport ◽  
Transport Properties ◽  
Intermolecular Interactions ◽  
Charge Transfer Complexes

Charge transport properties of the organic–inorganic MoO3 : 6T CTC thin film can be dramatically tuned via rubbing. The effects of intermolecular interactions on these changes are studied in detail.

What could be the Highest Hopping Mobility in Organic Thin-Film Transistors?

MRS Advances ◽  
2016 ◽  
Vol 1 (38) ◽  
pp. 2659-2664
Author(s):  
Varsha Rani ◽  
Akanksha Sharma ◽  
Subhasis Ghosh
Keyword(s):  
Thin Film ◽  
Charge Transport ◽  
Transport Properties ◽  
Thin Film Transistors ◽  
Weak Coupling ◽  
Theoretical Study ◽  
Schottky Diodes ◽  
Organic Thin Film Transistors ◽  
Electronic Coupling ◽  
Organic Thin Film

ABSTRACTCharge transport properties of pentacene have been investigated by a joint experimental and theoretical study. The growth of pentacene on the substrates shows mainly two different polymorphic phases, a bulk phase and a thin-film phase. The thin-film phase is crucial for the charge transport in two-terminal and three-terminal devices such as organic Schottky diodes and organic thin film transistors, respectively. Experimentally, mobility in two-terminal devices is less by five orders of magnitude than that in three-terminal devices. We show here that this difference can be explained on the basis of strong electronic coupling between molecular dimers located in the ab-plane and relatively weak coupling between the planes (along the c-axis).

Solid-State NMR Measurements of Asymmetric Dipolar Couplings Provide Insight into Protein Side-Chain Motion

2011 ◽  
Vol 50 (46) ◽  
pp. 11005-11009 ◽  
Author(s):  
Paul Schanda ◽  
Matthias Huber ◽  
Jérôme Boisbouvier ◽  
Beat H. Meier ◽  
Matthias Ernst
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Dipolar Couplings ◽  
Side Chain ◽  
Side Chain Motion ◽  
Insight Into

Modulating the rate of charge transport in a metal–organic framework thin film using host:guest chemistry

2016 ◽  
Vol 52 (8) ◽  
pp. 1705-1708 ◽  
Author(s):  
Idan Hod ◽  
Omar K. Farha ◽  
Joseph T. Hupp
Keyword(s):  
Thin Film ◽  
Charge Transport ◽  
Transport Properties ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Host:guest chemistry is used to control and manipulate charge transport properties of metal–organic framework (MOF) thin film.

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