scholarly journals Visualization of structural evolution and phase distribution of a lithium vanadium oxide (Li1.1V3O8) electrode via an operando and in situ energy dispersive X-ray diffraction technique

2017 ◽  
Vol 19 (21) ◽  
pp. 14160-14169 ◽  
Author(s):  
Qing Zhang ◽  
Andrea M. Bruck ◽  
David C. Bock ◽  
Jing Li ◽  
Varun Sarbada ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Vanadium Oxide ◽  
Phase Distribution ◽  
Structural Evolution ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Spatial Phase ◽  
Lithium Vanadium Oxide

EDXRD was used to profile the phase transitions and spatial phase distribution of a Li1.1V3O8electrode.

Effects of High Pressure on Structural Evolution of Polyurea: An In-Situ Energy Dispersive X-Ray Diffraction Study

2021 ◽  
Author(s):  
Tyler Eastmond ◽  
Jing Hu ◽  
Vahidreza Alizadeh ◽  
Jay Oswald ◽  
Alireza Vakil Amirkhizi ◽  
...  
Keyword(s):  
High Pressure ◽  
Diffraction Study ◽  
Structural Evolution ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray

Electrochemically Induced Phase Evolution of Lithium Vanadium Oxide: Complementary Insights Gained viaEx-Situ,In-Situ, andOperandoExperiments and Density Functional Theory

MRS Advances ◽  
2018 ◽  
Vol 3 (22) ◽  
pp. 1255-1260 ◽  
Author(s):  
Jiefu Yin ◽  
Wenzao Li ◽  
Mikaela Dunkin ◽  
Esther S. Takeuchi ◽  
Kenneth J. Takeuchi ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Structural Evolution ◽  
Phase Evolution ◽  
X Ray Diffraction ◽  
Functional Theory ◽  
X Ray ◽  
Α Phase ◽  
Lithium Vanadium Oxide

ABSTRACTUnderstanding the structural evolution of electrode material during electrochemical activity is important to elucidate the mechanism of (de)lithiation, and improve the electrochemical function based on the material properties. In this study, lithium vanadium oxide (LVO, LiV3O8) was investigated using ex-situ, in-situ, and operando experiments. Via a combination of in-situ X-ray diffraction (XRD) and density functional theory results, a reversible structural evolution during lithiation was revealed: from Li poor α phase (LiV3O8) to Li rich α phase (Li2.5V3O8) and finally β phase (Li4V3O8). In-situ and operando energy dispersive X-ray diffraction (EDXRD) provided tomographic information to visualize the spatial location of the phase evolution within the LVO electrode while inside a sealed lithium ion battery.

In situ observations of temperature- and pressure-induced phase transitions in TiH2: Angle-dispersive and synchrotron energy-dispersive X-ray diffraction studies

2008 ◽  
Vol 69 (9) ◽  
pp. 2240-2244 ◽  
Author(s):  
Patricia E. Kalita ◽  
Andrew L. Cornelius ◽  
Kristina E. Lipinska-Kalita ◽  
Cédric L. Gobin ◽  
H. Peter Liermann
Keyword(s):  
Phase Transitions ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
In Situ Observations ◽  
Temperature And Pressure

STRUCTURAL EVOLUTION OF EXCEPTIONALLY IRON-DEFICIENT HEMATITE NANOCRYSTALS AS OBSERVED BY IN SITU SYNCHROTRON X-RAY DIFFRACTION

2019 ◽  
Author(s):  
Si Athena Chen ◽  
◽  
Peter Heaney ◽  
Jeffrey E. Post ◽  
Peter J. Eng ◽  
...  
Keyword(s):  
Structural Evolution ◽  
X Ray Diffraction ◽  
X Ray ◽  
Iron Deficient

Structural evolution of NASICON-type Li1+xAlxGe2−x(PO4)3 using in situ synchrotron X-ray powder diffraction

2016 ◽  
Vol 4 (20) ◽  
pp. 7718-7726 ◽  
Author(s):  
Dorsasadat Safanama ◽  
Neeraj Sharma ◽  
Rayavarapu Prasada Rao ◽  
Helen E. A. Brand ◽  
Stefan Adams
Keyword(s):  
Solid Electrolyte ◽  
Diffraction Study ◽  
Powder Diffraction ◽  
Structural Evolution ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nasicon Type ◽  
Precursor Glass

In situ synchrotron X-ray diffraction study of the synthesis of solid-electrolyte Li1+xAlxGe2−x(PO4)3 (LAGP) from the precursor glass reveals that an initially crystallized dopant poor phase transforms into the Al-doped LAGP at 800 °C.

In situ strain profiling of elastoplastic bending in Ti–6Al–4V alloy by synchrotron energy dispersive x-ray diffraction

2009 ◽  
Vol 105 (9) ◽  
pp. 093505 ◽  
Author(s):  
M. Croft ◽  
V. Shukla ◽  
E. K. Akdoğan ◽  
N. Jisrawi ◽  
Z. Zhong ◽  
...  
Keyword(s):  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Elastoplastic Bending

scholarly journals Elucidating the Structural Evolution of a Highy Porous Responsive Metal-Organic Framework (DUT-49(M)) upon Guests Desorption by Time-Resolved In-Situ Powder X-Ray Diffraction

2020 ◽  
Author(s):  
Bikash Garai ◽  
Volodymyr Bon ◽  
Francesco Walenszus ◽  
Azat Khadiev ◽  
Dmitri Novikov ◽  
...  
Keyword(s):  
Adsorption Isotherms ◽  
Metal Organic Framework ◽  
Structural Evolution ◽  
Structural Transformations ◽  
X Ray Diffraction ◽  
Time Resolved ◽  
X Ray ◽  
Metal Organic ◽  
Subcritical Fluid

Variation in the metal centres of M-M paddle-wheel SBU results in the formation of isostructural DUT-49(M) frameworks. However, the porosity of the framework was found to be different for each of the structures. While a high and moderate porosity was obtained for DUT-49(Cu) and DUT-49(Ni), respectively, other members of the series [DUT-49(M); M= Mn, Fe, Co, Zn, Cd] show very low porosity and shapes of the adsorption isotherms which is not expected for op phases of these MOFs. Investigation on those MOFs revealed that those frameworks undergo structural collapse during the solvent removal at the activation step. Thus, herein, we aimed to study the detailed structural transformations that are possibly occurring during the removal of the subcritical fluid from the framework.

Sign in / Sign up

Export Citation Format

Share Document