Intermolecular charge fluxes and far-infrared spectral intensities of liquid formamide

Intermolecular charge fluxes induced by hydrogen-bond length modulations occurring upon molecular librations lead to intensity enhancement of the far-infrared spectrum.

Download Full-text

Experimental and theoretical studies of the phosphorus-hydrogen bond length and stretching mode of the phosphite anion

The Journal of Physical Chemistry ◽

10.1021/j100118a011 ◽

1993 ◽

Vol 97 (16) ◽

pp. 3985-3989 ◽

Cited By ~ 6

Author(s):

T. C. Stringfellow ◽

J. D. Trudeau ◽

T. C. Farrar

Keyword(s):

Hydrogen Bond ◽

Bond Length ◽

Theoretical Studies ◽

Hydrogen Bond Length ◽

Experimental And Theoretical Studies

Download Full-text

Dependence of the distortion of the tetrahedra in acid phosphate groups H n PO4 (n = 1–3) on hydrogen-bond length

Acta Crystallographica Section B Structural Science ◽

10.1107/s0108768187098355 ◽

1987 ◽

Vol 43 (1) ◽

pp. 23-28 ◽

Cited By ~ 20

Author(s):

M. Ichikawa

Keyword(s):

Hydrogen Bond ◽

Bond Length ◽

Acid Phosphate ◽

Hydrogen Bond Length ◽

Phosphate Groups

Download Full-text

Near doubling of hydrogen-hydrogen bond length in the "stretched" osmium molecular hydrogen complex [Os(NH3)4OAc(.eta.2-H2)]+: a theoretical study

Inorganic Chemistry ◽

10.1021/ic00063a003 ◽

1993 ◽

Vol 32 (11) ◽

pp. 2230-2231 ◽

Cited By ~ 10

Author(s):

J. Simon Craw ◽

George B. Bacskay ◽

Noel S. Hush

Keyword(s):

Hydrogen Bond ◽

Bond Length ◽

Molecular Hydrogen ◽

Theoretical Study ◽

Hydrogen Bond Length

Download Full-text

Relation between the frequency of the hydroxyl out-of-plane deformation vibration and the hydrogen bond length in carboxylic acids

Spectrochimica Acta ◽

10.1016/0371-1951(64)80107-7 ◽

1964 ◽

Vol 20 (6) ◽

pp. 1071-1079 ◽

Cited By ~ 26

Author(s):

Ingrid Fischmeister

Keyword(s):

Hydrogen Bond ◽

Bond Length ◽

Carboxylic Acids ◽

Plane Deformation ◽

Deformation Vibration ◽

Hydrogen Bond Length ◽

Out Of Plane

Download Full-text

Hydrogen bond length and 15N NMR chemical shift of the glycine residue of some oligopeptides in the solid state

Journal of Molecular Structure ◽

10.1016/0022-2860(91)87007-5 ◽

1991 ◽

Vol 245 (1-2) ◽

pp. 69-80 ◽

Cited By ~ 32

Author(s):

Shigeki Kuroki ◽

Naoki Asakawa ◽

Shinji Ando ◽

Isao Ando ◽

Akira Shoji ◽

...

Keyword(s):

Hydrogen Bond ◽

Solid State ◽

Chemical Shift ◽

Bond Length ◽

15N Nmr ◽

Nmr Chemical Shift ◽

Glycine Residue ◽

Hydrogen Bond Length

Download Full-text

Hydrogen Bond Length as a Key To Understanding Sweetness

The Journal of Physical Chemistry Letters ◽

10.1021/acs.jpclett.8b01280 ◽

2018 ◽

Vol 9 (13) ◽

pp. 3667-3672 ◽

Cited By ~ 7

Author(s):

F. Bruni ◽

C. Di Mino ◽

S. Imberti ◽

S. E. McLain ◽

N. H. Rhys ◽

...

Keyword(s):

Hydrogen Bond ◽

Bond Length ◽

Hydrogen Bond Length

Download Full-text

Highly localized H2O librational motion as a far-infrared spectroscopic probe for microsolvation of organic molecules

Physical Chemistry Chemical Physics ◽

10.1039/c8cp05985c ◽

2019 ◽

Vol 21 (4) ◽

pp. 1717-1723 ◽

Cited By ~ 2

Author(s):

D. Mihrin ◽

J. Andersen ◽

P. W. Jakobsen ◽

R. Wugt Larsen

Keyword(s):

Hydrogen Bond ◽

Organic Compounds ◽

Organic Molecules ◽

Intermolecular Hydrogen Bond ◽

Far Infrared ◽

Hydrogen Bond Energy ◽

Band Origin ◽

Infrared Spectral ◽

Librational Motion ◽

Spectroscopic Probe

This work demonstrates how large-amplitude OH librational motion of H2O molecules directly reflects the microsolvation of organic compounds. The highly localized OH librational motion of the first solvating H2O molecule gives rise to a strong band origin νlib in the far-infrared spectral region, which is correlated quantitatively with the intermolecular hydrogen bond energy D0.

Download Full-text