Synthesis, structures and photoluminescence properties of mixed ligand divalent metal–organic frameworks

Crystal engineering is an effective route for synthesis of mixed ligand metal–organic frameworks with attractive topologies and versatile potential applications.

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Recent advances in AIEgen-based luminescent metal–organic frameworks and covalent organic frameworks

Materials Chemistry Frontiers ◽

10.1039/c7qm00254h ◽

2017 ◽

Vol 1 (12) ◽

pp. 2474-2486 ◽

Cited By ~ 58

Author(s):

Li Ma ◽

Xiao Feng ◽

Shan Wang ◽

Bo Wang

Keyword(s):

Metal Organic Frameworks ◽

Covalent Organic Frameworks ◽

Photoluminescence Properties ◽

Recent Advances ◽

Potential Applications ◽

Metal Organic

This review gives a brief introduction to AIEgen-based MOFs and COFs and focuses on their photoluminescence properties and potential applications.

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Controlled Growth of the Non-centrosymmetric Zn(3-ptz)2 and Zn(Oh)(3-ptz) Metal-organic Frameworks

10.26434/chemrxiv.7588640.v1 ◽

2019 ◽

Author(s):

javier enriquez ◽

Ignacio Chi-Duran ◽

Carolina Manquian ◽

Felipe Herrera ◽

Ruben Fritz ◽

...

Keyword(s):

Single Crystal ◽

Nonlinear Optical ◽

Metal Organic Frameworks ◽

Molar Ratio ◽

Thermal Synthesis ◽

Small Crystals ◽

Alkaline Environments ◽

Potential Applications ◽

Metal Organic ◽

Long Rod

Non-centrosymmetric single-crystal metal-organic frameworks (MOF) are promising candidates for phase-matched nonlinear optical communication, but typical hydrothermal synthesis produces small crystals with relatively low transmittance and poor phase matching. We study the effect of the metal-to-ligand molar ratio and reaction pH on the hydro-thermal synthesis of the non-centrosymmetric Zn(3-ptz)2 and Zn(OH)(3-ptz) MOFs with in-situ ligand formation. In acidic environments, we find that decreasing the amount of ligand below the stoichiometric molar ratio 1:2 also produces highly transparent single-crystal octahedrons of Zn(3-ptz)2. In alkaline environments, we obtain long rod-like Zn(OH)(3-ptz) crystals whose length exceeds previous reports by up to four orders of magnitude. Potential applications of these results in the development of MOF-based nonlinear optical devices are discussed.

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Coligand-Rigidity Induced Interpenetration in Flexible Bis-imidazolyl Type Linker Based Mixed Ligand Metal–Organic Frameworks

Crystal Growth & Design ◽

10.1021/acs.cgd.9b00531 ◽

2019 ◽

Vol 19 (9) ◽

pp. 5152-5160 ◽

Cited By ~ 11

Author(s):

Fazle Haque ◽

Arijit Halder ◽

Saheli Ghosh ◽

Anupam Maiti ◽

Debajyoti Ghoshal

Keyword(s):

Metal Organic Frameworks ◽

Mixed Ligand ◽

Metal Organic

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Classification and role of modulators on crystal engineering of metal organic frameworks (MOFs)

Coordination Chemistry Reviews ◽

10.1016/j.ccr.2021.214064 ◽

2021 ◽

Vol 444 ◽

pp. 214064

Author(s):

Danni Jiang ◽

Chao Huang ◽

Jian Zhu ◽

Ping Wang ◽

Zhiming Liu ◽

...

Keyword(s):

Crystal Engineering ◽

Metal Organic Frameworks ◽

Metal Organic

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Synthesis, designing strategies and photocatalytic charge dynamics of Metal-Organic Frameworks (MOFs): A catalyzed Photo-degradation approach towards Organic Dyes

Catalysis Science & Technology ◽

10.1039/d0cy02275f ◽

2021 ◽

Author(s):

Ayushi Singh ◽

Ashish Kumar Singh ◽

Jian-Qiang Liu ◽

Abhinav Kumar

Keyword(s):

Small Molecule ◽

Coordination Polymers ◽

Organic Dyes ◽

Metal Organic Frameworks ◽

Gas Storage ◽

New Variety ◽

Photo Degradation ◽

Charge Dynamics ◽

Potential Applications ◽

Metal Organic

Metal-organic frameworks (MOFs) or coordination polymers (CPs) are regarded as new variety of materials that find potential applications in plethora of areas such as gas/small molecule absorption/separation, gas storage, membranes...

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