Role of a 3D Structure in Energy Transfer in Mixed-Ligand Metal–Organic Frameworks

2021 ◽  
Author(s):  
Shaunak M. Shaikh ◽  
Stefan Ilic ◽  
Bradley J. Gibbons ◽  
Xiaozhou Yang ◽  
Elena Jakubikova ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Metal Organic Frameworks ◽  
3D Structure ◽  
Mixed Ligand ◽  
Metal Organic

scholarly journals Role of Spin–Orbit Coupling in Long Range Energy Transfer in Metal–Organic Frameworks

2020 ◽  
Vol 142 (48) ◽  
pp. 20434-20443
Author(s):  
Arnab Chakraborty ◽  
Stefan Ilic ◽  
Meng Cai ◽  
Bradley J. Gibbons ◽  
Xiaozhou Yang ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Long Range ◽  
Metal Organic Frameworks ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Metal Organic

Efficient Energy Transfer (EnT) in Pyrene- and Porphyrin-Based Mixed-Ligand Metal–Organic Frameworks

2017 ◽  
Vol 9 (44) ◽  
pp. 38670-38677 ◽  
Author(s):  
Kyoung Chul Park ◽  
Changwon Seo ◽  
Gajendra Gupta ◽  
Jeongyong Kim ◽  
Chang Yeon Lee
Keyword(s):  
Energy Transfer ◽  
Metal Organic Frameworks ◽  
Mixed Ligand ◽  
Efficient Energy Transfer ◽  
Efficient Energy ◽  
Metal Organic

Coligand-Rigidity Induced Interpenetration in Flexible Bis-imidazolyl Type Linker Based Mixed Ligand Metal–Organic Frameworks

2019 ◽  
Vol 19 (9) ◽  
pp. 5152-5160 ◽  
Author(s):  
Fazle Haque ◽  
Arijit Halder ◽  
Saheli Ghosh ◽  
Anupam Maiti ◽  
Debajyoti Ghoshal
Keyword(s):  
Metal Organic Frameworks ◽  
Mixed Ligand ◽  
Metal Organic

Classification and role of modulators on crystal engineering of metal organic frameworks (MOFs)

2021 ◽  
Vol 444 ◽  
pp. 214064
Author(s):  
Danni Jiang ◽  
Chao Huang ◽  
Jian Zhu ◽  
Ping Wang ◽  
Zhiming Liu ◽  
...  
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Metal Organic

Dual Intrareticular Oxidation of Mixed-Ligand Metal–Organic Frameworks for Stepwise Electrochemiluminescence

2021 ◽  
Vol 143 (8) ◽  
pp. 3049-3053
Author(s):  
Da Zhu ◽  
Yong Zhang ◽  
Songsong Bao ◽  
Ningning Wang ◽  
Siqi Yu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Mixed Ligand ◽  
Metal Organic

scholarly journals Porphyrin and phthalocyanine-based Metal Organic Frameworks beyond metal-carboxylates

2020 ◽  
Author(s):  
Siddhartha De ◽  
Thomas Devic ◽  
Alexandra Fateeva
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Metal Carboxylates ◽  
Natural Systems ◽  
Metal Organic

Given the ubiquitous role of porphyrins in natural systems, these molecules and related derivatives such as phthalocyanines are fascinating building units to achieve functional porous materials. Porphyrin-based MOFs have been...

scholarly journals A Facile One-Pot Approach to the Synthesis of Gd-Eu Based Metal-Organic Frameworks and Applications to Sensing of Fe3+ and Cr2O72− Ions

Sensors ◽  
2021 ◽  
Vol 21 (5) ◽  
pp. 1679
Author(s):  
Roberta Puglisi ◽  
Anna L. Pellegrino ◽  
Roberto Fiorenza ◽  
Salvatore Scirè ◽  
Graziella Malandrino
Keyword(s):  
Surface Area ◽  
Metal Organic Frameworks ◽  
3D Structure ◽  
Inorganic Ions ◽  
Total Surface Area ◽  
One Pot ◽  
Green Approach ◽  
Metal Organic ◽  
Ft Ir ◽  
Xrd Patterns

Gadolinium metal-organic frameworks (Gd-MOFs) and Eu-doped Gd-MOFs have been synthesized through a one-pot green approach using commercially available reagents. The 1,4-benzenedicarboxylic acid (H2-BDC) and 2,6-naphthalenedicarboxylic acid (H2-NDC) were chosen as ditopic organic linkers to build the 3D structure of the network. The Gd-MOFs were characterized using powder X-ray diffraction (XRD), FT-IR spectroscopy, field emission scanning electron microscopy (FE-SEM) and N2 adsorption–desorption analysis. The Gd-MOF structures were attributed comparing the XRD patterns, supported by the FT-IR spectra, with data reported in the literature for Ln-MOFs of similar lanthanide ionic radius. FE-SEM characterization points to the effect of the duration of the synthesis to a more crystalline and organized structure, with grain dimensions increasing upon increasing reaction time. The total surface area of the MOFs has been determined from the application of the Brunauer–Emmett–Teller method. The study allowed us to correlate the processing conditions and ditopic linker dimension to the network surface area. Both Gd-MOF and Eu-doped Gd-MOF have been tested for sensing of the inorganic ions such as Fe3+ and Cr2O72−.

Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers

2020 ◽  
Vol 40 ◽  
pp. 156-170 ◽  
Author(s):  
Ping Shao ◽  
Luocai Yi ◽  
Shumei Chen ◽  
Tianhua Zhou ◽  
Jian Zhang
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Metal Organic Frameworks ◽  
Metal Centers ◽  
Metal Organic
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