Highly efficient charge transfer through a double Z-scheme mechanism by a Cu-promoted MoO3/g-C3N4 hybrid nanocomposite with superior electrochemical and photocatalytic performance

Nanoscale ◽  
2018 ◽  
Vol 10 (13) ◽  
pp. 5950-5964 ◽  
Author(s):  
Sulagna Patnaik ◽  
Gayatri Swain ◽  
K. M. Parida

A visible light-induced double Z-scheme charge transfer mechanism for H2 generation and Cr(vi) reduction over the Cu-MoO3/g-C3N4 composite.

Nanoscale ◽  
2018 ◽  
Vol 10 (39) ◽  
pp. 18540-18554 ◽  
Author(s):  
K. Hemalata Reddy ◽  
Satyabadi Martha ◽  
K. M. Parida

The multifarious nature of Au nanoparticles in Au/ZnTiO3nanocomposites plays an important role in the variation in the charge transfer mechanism and photocatalytic activities under UV and visible light.


RSC Advances ◽  
2017 ◽  
Vol 7 (1) ◽  
pp. 231-237 ◽  
Author(s):  
Di Li ◽  
Fenfen Shi ◽  
Deli Jiang ◽  
Min Chen ◽  
Weidong Shi

CdIn2S4/g-C3N4 heterojunction with excellent photocatalytic activities have been synthesized. The enhanced photocatalytic performance might be ascribed to the efficient photoinduced charge transfer derived from the heterojunction structure.


2019 ◽  
Vol 14 (1) ◽  
Author(s):  
Xiao-Dan Liu ◽  
Kai Chen ◽  
Song Ma ◽  
Zhong-Hua Hao ◽  
Shan Liang ◽  
...  

AbstractMetal-semiconductor heterostructures integrate multiply functionalities beyond those of their individual counterparts. Great efforts have been devoted to synthesize heterostructures with controlled morphologies for the applications ranging from photocatalysis to photonic nanodevices. Beyond the morphologies, the interface between two counterparts also significantly influences the performance of the heterostructures. Here, we synthesize Au/CdSe Janus nanostructures consisting of two half spheres of Au and CdSe separated by a flat and high-quality interface. Au/CdSe with other morphologies could also be prepared by adjusting the overgrowth conditions. The photocatalytic hydrogen generation of the Au/CdSe Janus nanospheres is measured to be 3.9 times higher than that of the controlled samples with CdSe half-shells overgrown on the Au nanospheres. The highly efficient charge transfer across the interface between Au and CdSe contributes to the improved photocatalytic performance. Our studies may find the applications in the design of heterostructures with highly efficient photocatalytic activity.


RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24218-24228 ◽  
Author(s):  
S. Zargari ◽  
R. Rahimi ◽  
A. Yousefi

Tin porphyrin intercalated between the TiO2–grphene nanocomposite. The inactivation of E. coli over the prepared compound was significantly increased via the interaction of tin porphyrin between the TiO2–graphene nanocomposite.


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Bandar Ali Al-Asbahi ◽  
Mohammad Hafizuddin Haji Jumali ◽  
Rashad Al-Gaashani

The optical properties and charge transfer mechanism of poly (9,9′-di-n-octylfluorenyl-2.7-diyl) (PFO)/ZnO thin films have been investigated. The ZnO nanorods (NRs) were prepared via a microwave technique. The solution blending method was used to prepare the PFO/ZnO nanocomposites. X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM) were used to determine the structural properties, while UV-Vis and photoluminescence (PL) were employed to investigate the optical properties of the films. XRD patterns confirmed that there was no variation in the structure of both PFO and ZnO NRs due to the blending process. FE-SEM micrographs displayed that ZnO NRs were well coated by PFO in all nanocomposite films. The absorption spectra of the nanocomposite thin films exhibited a red-shift indicating the increment in conjugation length of the PFO/ZnO nanocomposite. Significant quenching in the emission intensity of PFO was observed in fluorescence spectra of the nanocomposite films. This quenching was attributed to efficient charge transfer in the PFO/ZnO nanocomposites, which was further supported by the shorter PL lifetime of PFO/ZnO than that of the PFO thin film. The continuous decline in PL intensity of these nanocomposites is attributed to homogenous dynamic quenching between PFO and ZnO NRs.


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