scholarly journals Efficient carbazole-based small-molecule organic solar cells with an improved fill factor

RSC Advances ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 4867-4871 ◽  
Author(s):  
Yongtao Liu ◽  
Yanna Sun ◽  
Miaomiao Li ◽  
Huanran Feng ◽  
Wang Ni ◽  
...  

In this study, a new acceptor–donor–acceptor (A–D–A) small molecule, DI3TCz, with carbazole as the central unit and 1,3-indanedione as the end group, was designed and synthesized for application in organic solar cells.

2017 ◽  
Vol 5 (33) ◽  
pp. 17204-17210 ◽  
Author(s):  
Yuan-Qiu-Qiang Yi ◽  
Huanran Feng ◽  
Meijia Chang ◽  
Hongtao Zhang ◽  
Xiangjian Wan ◽  
...  

A series of new non-fullerene small molecule acceptors (NTIC, NTIC-Me, NTIC-OMe and NTIC-F) based on the acceptor–donor–acceptor (A–D–A) architecture, using hexacyclic naphthalene-(cyclopentadithiophene) as the central unit, were designed and synthesized.


2019 ◽  
Vol 29 (47) ◽  
pp. 1808429 ◽  
Author(s):  
Andrew Wadsworth ◽  
Helen Bristow ◽  
Zeinab Hamid ◽  
Maxime Babics ◽  
Nicola Gasparini ◽  
...  

2013 ◽  
Vol 109 ◽  
pp. 33-39 ◽  
Author(s):  
Liang-Chen Chi ◽  
Hsiao-Fan Chen ◽  
Wen-Yi Hung ◽  
Yu-Hsiang Hsu ◽  
Ping-Chi Feng ◽  
...  

2020 ◽  
Vol 13 (7) ◽  
pp. 2134-2141 ◽  
Author(s):  
Dingqin Hu ◽  
Qianguang Yang ◽  
Haiyan Chen ◽  
Friso Wobben ◽  
Vincent M. Le Corre ◽  
...  

A fullerene additive adjusts the miscibility between donor and acceptor for morphology optimization and reduces bimolecular recombination, assisting significant improvement of fill factor and efficiency.


2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ruimin Zhou ◽  
Zhaoyan Jiang ◽  
Chen Yang ◽  
Jianwei Yu ◽  
Jirui Feng ◽  
...  

AbstractThe high efficiency all-small-molecule organic solar cells (OSCs) normally require optimized morphology in their bulk heterojunction active layers. Herein, a small-molecule donor is designed and synthesized, and single-crystal structural analyses reveal its explicit molecular planarity and compact intermolecular packing. A promising narrow bandgap small-molecule with absorption edge of more than 930 nm along with our home-designed small molecule is selected as electron acceptors. To the best of our knowledge, the binary all-small-molecule OSCs achieve the highest efficiency of 14.34% by optimizing their hierarchical morphologies, in which the donor or acceptor rich domains with size up to ca. 70 nm, and the donor crystals of tens of nanometers, together with the donor-acceptor blending, are proved coexisting in the hierarchical large domain. All-small-molecule photovoltaic system shows its promising for high performance OSCs, and our study is likely to lead to insights in relations between bulk heterojunction structure and photovoltaic performance.


2019 ◽  
Vol 7 (14) ◽  
pp. 4013-4019 ◽  
Author(s):  
Yuan-Qiu-Qiang Yi ◽  
Huanran Feng ◽  
Xin Ke ◽  
Jing Yan ◽  
Meijia Chang ◽  
...  

A cyclopentadithiophene (DTC)-bridged acceptor–donor–acceptor (A–D–A) backboned small molecule acceptor (SMA), namely IDTC-4Cl, was designed and synthesized.


2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Pao-Hsun Huang ◽  
Chien-Jung Huang ◽  
Kan-Lin Chen ◽  
Jhong-Ciao Ke ◽  
Yeong-Her Wang ◽  
...  

An optimized hybrid planar heterojunction (PHJ) of small molecule organic solar cells (SM-OSCs) based on copper phthalocyanine (CuPc) as donor and fullerene (C60) as acceptor was fabricated, which obviously enhanced the performance of device by sequentially using both MoO3and pentacene as double anode buffer layers (ABL), also known as hole extraction layer (HEL). A series of the vacuum-deposited ABL, acting as an electron and exciton blocking layer, were examined for their characteristics in SM-OSCs. The performance and reliability were compared between conventional ITO/ABL/CuPc/C60/BCP/Ag cells and the new ITO/double ABL/CuPc/C60/BCP/Ag cells. The effect on the electrical properties of these materials was also investigated to obtain the optimal thickness of ABL. The comparison shows that the modified cell has an enhanced reliability compared to traditional cells. The improvement of lifetime was attributed to the idea of double layers to prevent humidity and oxygen from diffusing into the active layer. We demonstrated that the interfacial extraction layers are necessary to avoid degradation of device. That is to say, in normal temperature and pressure, a new avenue for the device within double buffer layers has exhibited the highest values of open circuit voltage (Voc), fill factor (FF), and lifetime in this work compared to monolayer of ABL.


2017 ◽  
Vol 44 ◽  
pp. 11-19 ◽  
Author(s):  
Ming Chen ◽  
Maoheng Yi ◽  
Jinduo Yi ◽  
Minjie Li ◽  
Chenchen Du ◽  
...  

2014 ◽  
Vol 15 (10) ◽  
pp. 2270-2276 ◽  
Author(s):  
Pei Cheng ◽  
Xingang Zhao ◽  
Weiyi Zhou ◽  
Jianhui Hou ◽  
Yongfang Li ◽  
...  

2016 ◽  
Vol 2 (1) ◽  
pp. 14-21 ◽  
Author(s):  
Jun Yan ◽  
Quanbin Liang ◽  
Kaikai Liu ◽  
Jingsheng Miao ◽  
Hui Chen ◽  
...  

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