Metal organic framework-derived CoZn alloy/N-doped porous carbon nanocomposites: tunable surface area and electromagnetic wave absorption properties

2018 ◽  
Vol 6 (1) ◽  
pp. 10-18 ◽  
Author(s):  
Wei Feng ◽  
Yaming Wang ◽  
Junchen Chen ◽  
Baoqiang Li ◽  
Lixin Guo ◽  
...  

CoZn alloy/N-doped porous carbon with tunable surface area and dielectric properties was synthesized and shows outstanding electromagnetic wave absorption properties.

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Jing Qiao ◽  
Xue Zhang ◽  
Chang Liu ◽  
Longfei Lyu ◽  
Yunfei Yang ◽  
...  

Highlights Non-magnetic bimetallic MOF-derived porous carbon-wrapped TiO2/ZrTiO4 composites are firstly used for efficient electromagnetic wave absorption. The electromagnetic wave absorption mechanisms including enhanced interfacial polarization and essential conductivity are intensively discussed. Abstract Modern communication technologies put forward higher requirements for electromagnetic wave (EMW) absorption materials. Metal–organic framework (MOF) derivatives have been widely concerned with its diverse advantages. To break the mindset of magnetic-derivative design, and make up the shortage of monometallic non-magnetic derivatives, we first try non-magnetic bimetallic MOFs derivatives to achieve efficient EMW absorption. The porous carbon-wrapped TiO2/ZrTiO4 composites derived from PCN-415 (TiZr-MOFs) are qualified with a minimum reflection loss of − 67.8 dB (2.16 mm, 13.0 GHz), and a maximum effective absorption bandwidth of 5.9 GHz (2.70 mm). Through in-depth discussions, the synergy of enhanced interfacial polarization and other attenuation mechanisms in the composites is revealed. Therefore, this work confirms the huge potentials of non-magnetic bimetallic MOFs derivatives in EMW absorption applications.


Author(s):  
Bin Du ◽  
Mei Cai ◽  
Xuan Wang ◽  
Junjie Qian ◽  
Chao He ◽  
...  

AbstractNowadays, metal oxide-based electromagnetic wave absorbing materials have aroused widely attentions in the application of telecommunication and electronics due to their selectable mechanical and outstanding dielectric properties. Herein, the binary ZnO/NiCo2O4 nanoparticles were successfully synthesized via hydrothermal reaction and the electromagnetic wave absorption properties of the composites were investigated in detail. As a result, benefiting from the dielectric loss, the as-obtained ZnO/NiCo2O4-7 samples possessed a minimum reflection loss value of −33.49 dB at 18.0 GHz with the thickness of 4.99 mm. This work indicates that ZnO/NiCo2O4 composites have the promising candidate applications in electromagnetic wave absorption materials in the future.


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