Thiol–ene click chemistry: a modular approach to solid-state triplet–triplet annihilation upconversion

2018 ◽  
Vol 6 (15) ◽  
pp. 3876-3881 ◽  
Author(s):  
Abagail K. Williams ◽  
Brad J. Davis ◽  
Erin R. Crater ◽  
Joseph R. Lott ◽  
Yoan C. Simon ◽  
...  
Keyword(s):  
Solid State ◽  
Click Chemistry ◽  
Modular Approach ◽  
Synthetic Route ◽  
On Demand ◽  
Host Materials ◽  
Triplet Triplet Annihilation

Thiol–ene click chemistry can be used as a facile cure-on-demand synthetic route to access robust host materials for solid-state upconversion.

A synthetic route to 2,6-bis-triazolyl purine deoxynucleosides via click chemistry

2014 ◽  
Author(s):  
Dace Cīrule ◽  
Kristers Ozols ◽  
Irina Novosjolova ◽  
Māris Turks ◽  
Ērika Bizdēna
Keyword(s):  
Click Chemistry ◽  
Synthetic Route

Unprecedented Hexa- and Undecanuclear Frameworks of Two New Tin(IV) Oxo Clusters Resulting from Partial Debenzylation Reactions

2010 ◽  
Vol 65 (11) ◽  
pp. 1293-s1308 ◽  
Author(s):  
Laurent Plasseraud ◽  
Hélène Cattey ◽  
Philippe Richard
Keyword(s):  
Solid State ◽  
1H Nmr Spectroscopy ◽  
Trifluoromethanesulfonic Acid ◽  
Synthetic Route ◽  
State Structure ◽  
X Ray Diffraction ◽  
Neutral Cluster ◽  
Broad Resonance ◽  
X Ray ◽  
The Core

A new and facile synthetic route to the known neutral cluster ((PhCH2)2SnO)6[((PhCH2)2SnOH)2- (CO3)]2 (2) as well as its reactivity toward trifluoromethanesulfonic acid (HO3SCF3, TfOH) are reported. The solid-state structure of the new solvate 2·6C7H8 has been determined by single-crystal X-ray diffraction. The core of 2 can be described as a pair of coplanar pentanuclear [(PhCH2)2SnO]5 ladders bridged at their ends by two carbonate groups. Successive additions of TfOH to a suspension of 2 in CD3CN were monitored by 119Sn{1H} NMR spectroscopy showing the transformation of the fingerprint of 2 (δ = −244, −246, −306 ppm), via new upfield signals, to a final broad resonance located at δ = −474 ppm. Thereafter, two unprecedented ionic monobenzyltin(IV) oxo clusters, 3 and 4, resulting from a debenzylation reaction and exhibiting unusual hexa- and undecanuclear frameworks, respectively, have been isolated as single crystals.

Erbium Tris(Amide) Compounds as Source Molecules FOR Rare Earth Doping of Semiconducting Materials

1995 ◽  
Vol 415 ◽  
Author(s):  
Oliver Just ◽  
Anton C. Greenwald ◽  
William S. Rees
Keyword(s):  
Rare Earth ◽  
Solid State ◽  
Earth Element ◽  
Optoelectronic Devices ◽  
Analytical Techniques ◽  
Optically Active ◽  
Rare Earth Doping ◽  
Semiconducting Materials ◽  
Host Materials ◽  
Erbium Doped

ABSTRACTThe homoleptic compound erbium{tris[bis (trimethylsilyl)]amide} displays high doping ability for incorporation of the rare earth element into epitaxially grown semiconducting host materials for fabrication of temperature-independent, monochromatic solid state optoelectronic devices. Electronic characteristics derived from erbium doped semiconducting films have been obtained. Several more volatile and lower melting representatives of this class of compounds have been synthesized, characterized by various analytical techniques and examined for their suitability to incorporate optically-active erbium centers into a semiconducting environment.

State-of-the-art Laser Ceramics for the Next-generation Solid-state Laser

2021 ◽  
Vol 30 (10) ◽  
pp. 22-27
Author(s):  
Ho Jin MA ◽  
Ha-Neul KIM
Keyword(s):  
Solid State ◽  
Mechanical Characteristics ◽  
High Energy ◽  
Solid State Lasers ◽  
Laser Ceramics ◽  
Host Materials ◽  
Laser Systems ◽  
Energy Laser ◽  
High Energy Laser ◽  
Gain Media

Solid-state lasers have aroused many researchers’ interests for a variety of applications in military and industrial fields. Because of the preference for increased output power, Nd:YAG single crystals, which are the most widely used gain media, should be replaced by other more suitable candidates. Polycrystalline sesquioxide ceramics show great potential for use as gain media because their thermal and mechanical characteristics are suitable for use with high-energy laser systems. Recently, novel concepts of the gain media were also introduced. Herein, while briefly looking back on the progress of polycrystalline laser ceramics, we will discuss new interests in host materials and systems.

scholarly journals Nanopore design for exceptional rectification of DNA translocation

2021 ◽  
Author(s):  
Ngan Pham ◽  
Yao Yao ◽  
Chenyu Wen ◽  
Shiyu Li ◽  
Shuangshuang Zeng ◽  
...  
Keyword(s):  
Numerical Simulation ◽  
Solid State ◽  
Surface Charge ◽  
Dna Translocation ◽  
Sensor Applications ◽  
Sensor Performance ◽  
On Demand ◽  
Dna Strands ◽  
Large Opening ◽  
Shape And Size

Abstract Solid-state nanopores (SSNPs) of on-demand shape and size can facilitate desired sensor performance. However, reproducible production of arrayed nanopores of predefined geometry is yet to demonstrate despite of numerous methods explored. Here, bowl-shape SSNPs combining unique properties of ultrathin membrane and tapering geometry are demonstrated. The bowl-SSNP upper opening is 100-120 nm in diameter, with the bottom opening reaching sub-5 nm. Numerical simulation reveals the formation of multiple electroosmotic vortexes (EOVs) originating from distributed surface charge around the pore-bowl. The EOVs determine, collaboratively with electrophoretic force, how nanoscale objects translocate the bowl-SSNPs. Exceptional rectification with higher frequencies, longer duration and larger amplitude is found when DNA strands translocate downwards from the upper large opening than upwards from the bottom smallest restriction. The rectification is a manifestation of the interplay between electrophoresis and electroosmosis. The resourceful silicon nanofabrication technology is ingeniously shown to enable innovative nanopore designs targeting unprecedented sensor applications.

LiCaAlF6 and LiSrAlF6: tunable solid state laser host materials

2005 ◽  
Vol 43 (3-5) ◽  
pp. 251-262 ◽  
Author(s):  
Till A. Samtleben ◽  
Jürg Hulliger
Keyword(s):  
Solid State ◽  
Solid State Laser ◽  
State Laser ◽  
Host Materials

Precise synthesis of thermoresponsive polyvinylphosphonate-biomolecule conjugatesviathiol–ene click chemistry

2018 ◽  
Vol 9 (3) ◽  
pp. 284-290 ◽  
Author(s):  
Christina Schwarzenböck ◽  
Andreas Schaffer ◽  
Philipp Pahl ◽  
Peter J. Nelson ◽  
Ralf Huss ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Synthetic Route

Herein we present the first smart polyvinylphosphonate-bioconjugates obtainedviaan efficient modular synthetic route.

scholarly journals Enhanced sub-bandgap efficiency of a solid-state organic intermediate band solar cell using triplet–triplet annihilation

2017 ◽  
Vol 10 (6) ◽  
pp. 1465-1475 ◽  
Author(s):  
YunHui L. Lin ◽  
Marius Koch ◽  
Alyssa N. Brigeman ◽  
David M. E. Freeman ◽  
Lianfeng Zhao ◽  
...  
Keyword(s):  
Solar Cell ◽  
Solid State ◽  
Intermediate Band ◽  
Intermediate Band Solar Cell ◽  
Triplet Triplet Annihilation

A novel solid-state design is presented for an organic intermediate band solar cell with electrically integrated triplet–triplet annihilation upconversion.

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