Tuning of the exchange interaction and the Curie temperature by mixed crystal formation of the bridging anionic ligands
Keyword(s):
A strategy to continuously tune the exchange constant J and the critical temperature Tc in the 1D coordination polymers [Co(NCS)x(NCSe)2−x(pyridine)2]n is reported. For such mixed crystals, prepared by annealing and from solution, an increase of J and Tc with increasing selenocyanate content is observed.
2018 ◽
Vol 18
(5)
◽
pp. 3117-3123
◽
Keyword(s):
1985 ◽
Vol 50
(5)
◽
pp. 1153-1160
◽
Keyword(s):
2002 ◽
Vol 58
(6)
◽
pp. 986-997
◽
Keyword(s):
1942 ◽
Vol 46
(6)
◽
pp. 616-620
◽
Keyword(s):
1936 ◽
Vol 40
(5)
◽
pp. 637-643
◽
Keyword(s):
1948 ◽
Vol 70
(1)
◽
pp. 421-423
◽