Approaching the maximum capacity of nickel-rich LiNi0.8Co0.1Mn0.1O2 cathodes by charging to high-voltage in a non-flammable electrolyte of propylene carbonate and fluorinated linear carbonates

2019 ◽  
Vol 55 (9) ◽  
pp. 1256-1258 ◽  
Author(s):  
Hieu Quang Pham ◽  
Eui-Hyung Hwang ◽  
Young-Gil Kwon ◽  
Seung-Wan Song
Keyword(s):  
Energy Density ◽  
Propylene Carbonate ◽  
High Voltage ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Maximum Capacity ◽  
Lithium Metal Batteries ◽  
First Time

We report for the first time a promising approach to achieve the maximum capacity of LiNi0.8Co0.1Mn0.1O2 cathodes in a non-flammable electrolyte for safe and high-energy density lithium-ion and lithium metal batteries.

Long-lifespan lithium–metal batteries obtained using a perovskite intercalation layer to stabilize the lithium electrode

2020 ◽  
Vol 8 (18) ◽  
pp. 9137-9145
Author(s):  
Nahid Kaisar ◽  
Anupriya Singh ◽  
Po-Yu Yang ◽  
Yu-Ting Chen ◽  
Shenghan Li ◽  
...  
Keyword(s):  
Energy Density ◽  
Reduction Potential ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Low Density ◽  
Lithium Metal ◽  
Lithium Electrode ◽  
Lithium Metal Batteries

Because it has the highest specific capacity and lowest reduction potential among the elements, as well as a low density, lithium (Li) metal has been the most practical anode material for high energy density lithium-ion batteries.

A high-voltage aqueous lithium ion capacitor with high energy density from an alkaline–neutral electrolyte

2019 ◽  
Vol 7 (8) ◽  
pp. 4110-4118 ◽  
Author(s):  
Chunyang Li ◽  
Wenzhuo Wu ◽  
Shuaishuai Zhang ◽  
Liang He ◽  
Yusong Zhu ◽  
...  
Keyword(s):  
Energy Density ◽  
High Voltage ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Carbon Anode ◽  
Biomass Carbon ◽  
Proof Of Concept ◽  
Lithium Ion Capacitor ◽  
Neutral Electrolyte

A proof-of-concept lithium ion capacitor comprising LiMn2O4 nanorods as the cathode, a nitrogen-rich biomass carbon anode and a stable alkaline–neutral electrolyte was designed and fabricated.

Slow surface diffusion on Cu substrates in Li metal batteries

2021 ◽  
Author(s):  
Ingeborg Treu Røe ◽  
Sondre K. Schnell
Keyword(s):  
Crystal Structure ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anode ◽  
Slow Surface ◽  
Cu Substrates

Dendrite growth on the lithium metal anode still obstructs a widespread commercialization of high energy density lithium metal batteries. In this work, we investigate how the crystal structure of the...

Recent Advancements of Functional Gel Polymer Electrolytes for Rechargeable Lithium Metal Batteries

2021 ◽  
Author(s):  
Sha Fu ◽  
Lan-Lan Zuo ◽  
Peng-Sheng Zhou ◽  
Xue-Jiao Liu ◽  
Qiang Ma ◽  
...  
Keyword(s):  
Energy Density ◽  
Polymer Electrolytes ◽  
High Energy ◽  
High Energy Density ◽  
Gel Polymer Electrolytes ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metallic Lithium ◽  
Electrochemical Storage ◽  
Storage Technologies

Lithium metal batteries (LMBs) as the next generation promising high energy density alternatives among electrochemical storage technologies have received worldwide attention. However, the incompatibility between metallic lithium and traditional liquid...

A dual lithiated alloy interphase layer for high-energy-density lithium metal batteries

2022 ◽  
pp. 134637
Author(s):  
Chengwei Ma ◽  
Chengcai Liu ◽  
Yuanxing Zhang ◽  
Xinyu Zhang ◽  
Zhikun Zhao ◽  
...  
Keyword(s):  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Interphase Layer ◽  
Lithium Metal ◽  
Lithium Metal Batteries

Hexamethylene diisocyanate as an electrolyte additive for high-energy density lithium ion batteries

2015 ◽  
Vol 3 (16) ◽  
pp. 8246-8249 ◽  
Author(s):  
Yang Liu ◽  
Yinping Qin ◽  
Zhe Peng ◽  
Jingjing Zhou ◽  
Changjin Wan ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Propylene Carbonate ◽  
Interfacial Layer ◽  
Lithium Ion ◽  
High Energy ◽  
Hexamethylene Diisocyanate ◽  
High Energy Density ◽  
Electrolyte Additive

Hexamethylene diisocyanate can chemically react with the onium ion produced by the oxidation of propylene carbonate andin situgenerate a novel interfacial layer that is stable at high potential.

High energy density lithium metal batteries enabled by a porous graphene/MgF2 framework

2020 ◽  
Vol 26 ◽  
pp. 73-82 ◽  
Author(s):  
Qingshuai Xu ◽  
Xianfeng Yang ◽  
Mumin Rao ◽  
Dingchang Lin ◽  
Kai Yan ◽  
...  
Keyword(s):  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Porous Graphene ◽  
Lithium Metal Batteries

scholarly journals Improving Cycle Life Through Fast Formation Using a Super-Concentrated Phosphonium Based Ionic Liquid Electrolyte for Anode-Free and Lithium Metal Batteries

2021 ◽  
Author(s):  
Thushan Pathirana ◽  
Dmitrii Rakov ◽  
Fangfang Chen ◽  
Maria Forsyth ◽  
Robert Kerr ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Energy Density ◽  
Electrochemical Impedance ◽  
Cell Formation ◽  
Lithium Ion ◽  
High Energy ◽  
Liquid Electrolyte ◽  
High Energy Density ◽  
Lithium Metal ◽  
Ionic Liquid Electrolyte

<p>ABSTRACT </p><p>Cell formation of lithium-ion cells impacts the evolution of the solid electrolyte interphase (SEI) and the cell cycle stability. Lithium metal anodes are an important step in the development of high energy density batteries owing to the high theoretical specific capacity of lithium metal. However, most lithium metal battery research has used a conventional lithium-ion formation protocol; this is time consuming, costly and does not account for the different properties of the lithium metal electrode. Here, we have used a recently reported promising phosphonium bis(fluorosulfonyl)imide ionic liquid electrolyte coupled with an NMC622 high areal capacity cathode (>3.5 mAh/cm2) to investigate the effect of cell formation rates. A faster formation protocol comprised of a pulsed 1.25C current decreased the formation time by 56 % and gave a 38 % greater capacity retention after 50 cycles when compared to formation at C/20. Electrochemical impedance spectroscopy measurements showed that the fast formation gave rise to a lower-resistance SEI. Column-like lithium deposits with reduced porous lithium domains between the particles were observed using scanning electron microscope imaging. To underline the excellent performance of these high energy-density cells, a 56 % greater stack specific energy was achieved compared to the analogous graphite-based lithium-ion cell chemistries. </p>

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