Lithium ion, lithium metal, and alternative rechargeable battery technologies: the odyssey for high energy density

2017 ◽  
Vol 21 (7) ◽  
pp. 1939-1964 ◽  
Author(s):  
Tobias Placke ◽  
Richard Kloepsch ◽  
Simon Dühnen ◽  
Martin Winter
Keyword(s):  
Energy Density ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Rechargeable Battery ◽  
Lithium Metal

High-energy-density lithium-ion battery using a carbon-nanotube–Si composite anode and a compositionally graded Li[Ni0.85Co0.05Mn0.10]O2 cathode

2016 ◽  
Vol 9 (6) ◽  
pp. 2152-2158 ◽  
Author(s):  
Joo Hyeong Lee ◽  
Chong S. Yoon ◽  
Jang-Yeon Hwang ◽  
Sung-Jin Kim ◽  
Filippo Maglia ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Energy Density ◽  
Lithium Ion Battery ◽  
State Of The Art ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Rechargeable Battery ◽  
Composite Anode ◽  
Battery System

A Li-rechargeable battery system based on state-of-the-art cathode and anode technologies demonstrated high energy density, meeting demands for vehicle application.

Approaching the maximum capacity of nickel-rich LiNi0.8Co0.1Mn0.1O2 cathodes by charging to high-voltage in a non-flammable electrolyte of propylene carbonate and fluorinated linear carbonates

2019 ◽  
Vol 55 (9) ◽  
pp. 1256-1258 ◽  
Author(s):  
Hieu Quang Pham ◽  
Eui-Hyung Hwang ◽  
Young-Gil Kwon ◽  
Seung-Wan Song
Keyword(s):  
Energy Density ◽  
Propylene Carbonate ◽  
High Voltage ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Maximum Capacity ◽  
Lithium Metal Batteries ◽  
First Time

We report for the first time a promising approach to achieve the maximum capacity of LiNi0.8Co0.1Mn0.1O2 cathodes in a non-flammable electrolyte for safe and high-energy density lithium-ion and lithium metal batteries.

scholarly journals Improving Cycle Life Through Fast Formation Using a Super-Concentrated Phosphonium Based Ionic Liquid Electrolyte for Anode-Free and Lithium Metal Batteries

2021 ◽  
Author(s):  
Thushan Pathirana ◽  
Dmitrii Rakov ◽  
Fangfang Chen ◽  
Maria Forsyth ◽  
Robert Kerr ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Energy Density ◽  
Electrochemical Impedance ◽  
Cell Formation ◽  
Lithium Ion ◽  
High Energy ◽  
Liquid Electrolyte ◽  
High Energy Density ◽  
Lithium Metal ◽  
Ionic Liquid Electrolyte

<p>ABSTRACT </p><p>Cell formation of lithium-ion cells impacts the evolution of the solid electrolyte interphase (SEI) and the cell cycle stability. Lithium metal anodes are an important step in the development of high energy density batteries owing to the high theoretical specific capacity of lithium metal. However, most lithium metal battery research has used a conventional lithium-ion formation protocol; this is time consuming, costly and does not account for the different properties of the lithium metal electrode. Here, we have used a recently reported promising phosphonium bis(fluorosulfonyl)imide ionic liquid electrolyte coupled with an NMC622 high areal capacity cathode (>3.5 mAh/cm2) to investigate the effect of cell formation rates. A faster formation protocol comprised of a pulsed 1.25C current decreased the formation time by 56 % and gave a 38 % greater capacity retention after 50 cycles when compared to formation at C/20. Electrochemical impedance spectroscopy measurements showed that the fast formation gave rise to a lower-resistance SEI. Column-like lithium deposits with reduced porous lithium domains between the particles were observed using scanning electron microscope imaging. To underline the excellent performance of these high energy-density cells, a 56 % greater stack specific energy was achieved compared to the analogous graphite-based lithium-ion cell chemistries. </p>

Carbon-rich Conjugated Framework PTEB Modified Cu Nanowires for Stabilizing Lithium Metal Anode

2021 ◽  
Author(s):  
Shan Yang ◽  
Ru Xiao ◽  
Tongwei Zhang ◽  
Yuan Li ◽  
Benhe Zhong ◽  
...  
Keyword(s):  
Energy Density ◽  
Dendritic Growth ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Cu Nanowires ◽  
Lithium Metal Anode

Lithium metal anode provides a direction for the development of high-energy-density lithium ion batteries. In order to solve lithium dendritic growth and low Coulombic efficiency in lithium plating/stripping process, designing...

Rechargeable Li//Br battery: a promising platform for post lithium ion batteries

2014 ◽  
Vol 2 (45) ◽  
pp. 19444-19450 ◽  
Author(s):  
Zheng Chang ◽  
Xujiong Wang ◽  
Yaqiong Yang ◽  
Jie Gao ◽  
Minxia Li ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Negative Electrode ◽  
Lithium Ion ◽  
High Energy ◽  
Positive Electrode ◽  
High Energy Density ◽  
Lithium Metal ◽  
Redox Pair

Li//Br battery, by using aqueous bromide/tribromide redox pair as positive electrode and a coated lithium metal as negative electrode, exhibits high energy density and good cycling.

Long-lifespan lithium–metal batteries obtained using a perovskite intercalation layer to stabilize the lithium electrode

2020 ◽  
Vol 8 (18) ◽  
pp. 9137-9145
Author(s):  
Nahid Kaisar ◽  
Anupriya Singh ◽  
Po-Yu Yang ◽  
Yu-Ting Chen ◽  
Shenghan Li ◽  
...  
Keyword(s):  
Energy Density ◽  
Reduction Potential ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Low Density ◽  
Lithium Metal ◽  
Lithium Electrode ◽  
Lithium Metal Batteries

Because it has the highest specific capacity and lowest reduction potential among the elements, as well as a low density, lithium (Li) metal has been the most practical anode material for high energy density lithium-ion batteries.

Stable liquid-solid interface of lithium metal anode enabled by micro-region meshing

Nanoscale ◽  
2021 ◽  
Author(s):  
Jianzong Man ◽  
Kun Liu ◽  
Yehong Du ◽  
Xinyu Wang ◽  
Song Li ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Battery Lifetime ◽  
Lithium Metal Anode ◽  
Solid Liquid Interface ◽  
Solid Liquid

Although lithium metal is regarded as the most promising anode for high energy density lithium ion batteries, the unstable solid-liquid interface during cycling severely shortens the battery lifetime. The Li...

scholarly journals Improving Cycle Life Through Fast Formation Using a Super-Concentrated Phosphonium Based Ionic Liquid Electrolyte for Anode-Free and Lithium Metal Batteries

2021 ◽  
Author(s):  
Thushan Pathirana ◽  
Dmitrii Rakov ◽  
Fangfang Chen ◽  
Maria Forsyth ◽  
Robert Kerr ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Energy Density ◽  
Electrochemical Impedance ◽  
Cell Formation ◽  
Lithium Ion ◽  
High Energy ◽  
Liquid Electrolyte ◽  
High Energy Density ◽  
Lithium Metal ◽  
Ionic Liquid Electrolyte

<p>ABSTRACT </p><p>Cell formation of lithium-ion cells impacts the evolution of the solid electrolyte interphase (SEI) and the cell cycle stability. Lithium metal anodes are an important step in the development of high energy density batteries owing to the high theoretical specific capacity of lithium metal. However, most lithium metal battery research has used a conventional lithium-ion formation protocol; this is time consuming, costly and does not account for the different properties of the lithium metal electrode. Here, we have used a recently reported promising phosphonium bis(fluorosulfonyl)imide ionic liquid electrolyte coupled with an NMC622 high areal capacity cathode (>3.5 mAh/cm2) to investigate the effect of cell formation rates. A faster formation protocol comprised of a pulsed 1.25C current decreased the formation time by 56 % and gave a 38 % greater capacity retention after 50 cycles when compared to formation at C/20. Electrochemical impedance spectroscopy measurements showed that the fast formation gave rise to a lower-resistance SEI. Column-like lithium deposits with reduced porous lithium domains between the particles were observed using scanning electron microscope imaging. To underline the excellent performance of these high energy-density cells, a 56 % greater stack specific energy was achieved compared to the analogous graphite-based lithium-ion cell chemistries. </p>

Si Nanowire Anode Prepared by Chemical Etching for High Energy Density Lithium-ion Battery

2013 ◽  
Vol 28 (11) ◽  
pp. 1207-1212 ◽  
Author(s):  
Jian-Wen LI ◽  
Ai-Jun ZHOU ◽  
Xing-Quan LIU ◽  
Jing-Ze LI
Keyword(s):  
Energy Density ◽  
Lithium Ion Battery ◽  
Chemical Etching ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Si Nanowire

scholarly journals Na0.76V6O15/Activated Carbon Hybrid Cathode for High-Performance Lithium-Ion Capacitors

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 122
Author(s):  
Renwei Lu ◽  
Xiaolong Ren ◽  
Chong Wang ◽  
Changzhen Zhan ◽  
Ding Nan ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Energy Density ◽  
Power Density ◽  
Cathode Materials ◽  
Low Cost ◽  
Lithium Ion ◽  
High Energy ◽  
Cycling Stability ◽  
High Energy Density ◽  
Artificial Graphite

Lithium-ion hybrid capacitors (LICs) are regarded as one of the most promising next generation energy storage devices. Commercial activated carbon materials with low cost and excellent cycling stability are widely used as cathode materials for LICs, however, their low energy density remains a significant challenge for the practical applications of LICs. Herein, Na0.76V6O15 nanobelts (NaVO) were prepared and combined with commercial activated carbon YP50D to form hybrid cathode materials. Credit to the synergism of its capacitive effect and diffusion-controlled faradaic effect, NaVO/C hybrid cathode displays both superior cyclability and enhanced capacity. LICs were assembled with the as-prepared NaVO/C hybrid cathode and artificial graphite anode which was pre-lithiated. Furthermore, 10-NaVO/C//AG LIC delivers a high energy density of 118.9 Wh kg−1 at a power density of 220.6 W kg−1 and retains 43.7 Wh kg−1 even at a high power density of 21,793.0 W kg−1. The LIC can also maintain long-term cycling stability with capacitance retention of approximately 70% after 5000 cycles at 1 A g−1. Accordingly, hybrid cathodes composed of commercial activated carbon and a small amount of high energy battery-type materials are expected to be a candidate for low-cost advanced LICs with both high energy density and power density.

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