Effect of intermediate phases on the optical properties of PbI2-rich CH3NH3PbI3 organic–inorganic hybrid perovskite

2019 ◽  
Vol 21 (9) ◽  
pp. 5253-5261 ◽  
Author(s):  
Alonso W. P. Sanches ◽  
Marco A. T. da Silva ◽  
Neusmar J. A. Cordeiro ◽  
Alexandre Urbano ◽  
Sidney A. Lourenço

Intermediate phases in the methylammonium lead halide perovskite (CH3NH3PbI3) films produced by the two-step spin coating method.




2021 ◽  
Vol 16 (6) ◽  
pp. 967-973
Author(s):  
Shuai Zhao ◽  
Dong-Xue Lin ◽  
Yu-Xin Wang

All of the TiO2 films including intrinsic TiO2 film, Zn single doped film with 2.0 at% content and N doped films with 4.0 at%, 6.0 at%, 8.0 at% and 10.0 at% content, were obtained by butyl titanate (Ti(OC4H9)4) as a titanium source, zinc nitrate (Zn(NO3)2·6H2O) as zinc source and urea (H2 NCONH2) as nitrogen source, which was calcined at 600 °C on the glass substrate and Si substrate using sol–gel spin coating method. The structures, morphology and optical properties of various films were analyzed and studied by X ray diffract meter (XRD), ultraviolet-visible spectrophotometer (UV-Vis) and scanning electron microscope (SEM). The results indicated that the main crystal plane of TiO2 film was (101) and any impurity crystal plane didn't appear. All samples had obvious red shifts in the absorbing edge overall and reduced significantly the width of forbidden band, especially, the N doping content with 8.0 at% was surprised to investigate the strongest (101) peak intensity, the sharpest peak type, the best meritocratic orientation, the greatest red shift of the absorption spectrum, the lowest optical band gap value of 3.356 eV, and the highest utilization rate of visible light of the sample. However, the surface morphology of the others films except the N doping content with 8.0 at% is not further improved by co-doping, that is, their surfaces were still rough, had obvious voids and uneven distribution between the grains. Meanwhile, the intensity of the (101) crystalline diffraction peaks of these samples were reduced and the crystalline spacing generally increased after co-doping.



2016 ◽  
Vol 12 (3) ◽  
pp. 224
Author(s):  
R. K. Alfahed ◽  
K. I. Ajeel ◽  
A. K. Hassan

Preparation of poly (o-toluidine) was doped by different volume ratios of cobalt chloride and characterized by (FT-IR, XRD and SEM). The results showed that the intensity of absorption increased while energy gaps of the prepared polymer decreased with respect to increasing ratio of the dopant where the direct and indirect energy gaps were calculated, in addition to edge of the absorption. Photovoltaic device was fabricated by deposit the prepared polymer on the n-type silicon by spin coating method, so the batter efficiency of the prepared devices was 3.02% which was tested under dark and illumination with intensity of 100mW/cm².



2017 ◽  
Vol 5 (39) ◽  
pp. 10114-10121 ◽  
Author(s):  
Swaminathan Venkatesan ◽  
Mehedhi Hasan ◽  
Junyoung Kim ◽  
Nader R. Rady ◽  
Sandeep Sohal ◽  
...  

The nucleation and growth of organic–inorganic hybrid perovskite films induced by the molar ratio of precursor components and their role in optoelectronic performance are investigated.



2017 ◽  
Vol 245 ◽  
pp. 734-741 ◽  
Author(s):  
Woochul Kim ◽  
Jiyoon Park ◽  
Hyeonghun Kim ◽  
Yusin Pak ◽  
Heon Lee ◽  
...  




Sign in / Sign up

Export Citation Format

Share Document