Electrochemically activated solid synthesis: an alternative solid-state synthetic method

Electrochemical discharge followed by thermal treatments leads to the generation of unconventional phases upon heating, an alternative synthetic route.

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Synthetic route to [Fe6S9(SR)2]4- clusters (R = alkyl). Their spectroscopic and magnetic properties and the solid-state structures of [Fe6S9(SCH2Ph)2]4- and [(Fe6S9(SMe)2)2Na2]6-

Inorganic Chemistry ◽

10.1021/ic00181a008 ◽

1984 ◽

Vol 23 (13) ◽

pp. 1816-1825 ◽

Cited By ~ 39

Author(s):

Henry Strasdeit ◽

Bernt Krebs ◽

Gerald Henkel

Keyword(s):

Magnetic Properties ◽

Solid State ◽

Synthetic Route ◽

Solid State Structures

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Unprecedented Hexa- and Undecanuclear Frameworks of Two New Tin(IV) Oxo Clusters Resulting from Partial Debenzylation Reactions

Zeitschrift für Naturforschung B ◽

10.1515/znb-2010-1101 ◽

2010 ◽

Vol 65 (11) ◽

pp. 1293-s1308 ◽

Cited By ~ 5

Author(s):

Laurent Plasseraud ◽

Hélène Cattey ◽

Philippe Richard

Keyword(s):

Solid State ◽

1H Nmr Spectroscopy ◽

Trifluoromethanesulfonic Acid ◽

Synthetic Route ◽

State Structure ◽

X Ray Diffraction ◽

Neutral Cluster ◽

Broad Resonance ◽

X Ray ◽

The Core

A new and facile synthetic route to the known neutral cluster ((PhCH2)2SnO)6[((PhCH2)2SnOH)2- (CO3)]2 (2) as well as its reactivity toward trifluoromethanesulfonic acid (HO3SCF3, TfOH) are reported. The solid-state structure of the new solvate 2·6C7H8 has been determined by single-crystal X-ray diffraction. The core of 2 can be described as a pair of coplanar pentanuclear [(PhCH2)2SnO]5 ladders bridged at their ends by two carbonate groups. Successive additions of TfOH to a suspension of 2 in CD3CN were monitored by 119Sn{1H} NMR spectroscopy showing the transformation of the fingerprint of 2 (δ = −244, −246, −306 ppm), via new upfield signals, to a final broad resonance located at δ = −474 ppm. Thereafter, two unprecedented ionic monobenzyltin(IV) oxo clusters, 3 and 4, resulting from a debenzylation reaction and exhibiting unusual hexa- and undecanuclear frameworks, respectively, have been isolated as single crystals.

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Size-tunable and scalable synthesis of uniform copper nanocrystals

RSC Advances ◽

10.1039/c4ra09756d ◽

2015 ◽

Vol 5 (4) ◽

pp. 2756-2761 ◽

Cited By ~ 6

Author(s):

Hwansu Sim ◽

Jihwan Lee ◽

Taekyung Yu ◽

Kyungpil Kim ◽

Seong Jun Lee ◽

...

Keyword(s):

Ethylene Glycol ◽

Synthetic Method ◽

Synthetic Route ◽

Scalable Synthesis

A facile and scalable synthetic route to uniform Cu nanocrystals with tunable sizes in the range of 20–100 nm based on an ethylene glycol-assisted synthetic method was developed.

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Investigation of an LuAG:Ce translucent ceramic synthesized via spark plasma sintering: Towards a facile synthetic route, robust thermal performance, and high-power solid state laser lighting

Journal of the European Ceramic Society ◽

10.1016/j.jeurceramsoc.2017.07.036 ◽

2018 ◽

Vol 38 (1) ◽

pp. 343-347 ◽

Cited By ~ 34

Author(s):

Jian Xu ◽

Jian Wang ◽

Yuxuan Gong ◽

Xuefeng Ruan ◽

Zhiwen Liu ◽

...

Keyword(s):

Solid State ◽

Spark Plasma Sintering ◽

Thermal Performance ◽

High Power ◽

Solid State Laser ◽

Synthetic Route ◽

State Laser ◽

Plasma Sintering ◽

Spark Plasma

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Synthetic Route to Glycosyl β-1C-(phosphino)-phosphonates as Unprecedented Stable Glycosyl Diphosphate Analogs and Their Preliminary Biological Evaluation

Molecules ◽

10.3390/molecules25214969 ◽

2020 ◽

Vol 25 (21) ◽

pp. 4969

Author(s):

Michaël Bosco ◽

Su-Jin Paik ◽

Patricia Busca ◽

Stuart E. H. Moore ◽

Christine Gravier-Pelletier

Keyword(s):

Alkaline Phosphatase ◽

Double Bond ◽

Biological Evaluation ◽

Synthetic Method ◽

Synthetic Route ◽

Stereoselective Addition

The synthesis of glycosyl-β-1C-(phosphino)-phosphonates is a challenge since it has not yet been described. In this paper, we report an innovative synthetic method for their preparation from Glc-, Man-, and GlcNAc- lactone derivatives. The proposed original strategy involves the addition of the corresponding δ-hexonolactones onto the dianion of (methylphosphino) phosphonate as a key step, followed by dehydration and stereoselective addition of dihydrogen on the resulting double bond. Final deprotection provides the new glycosyl diphosphate analogs in 35%, 36%, and 10% yield over 6 steps from the corresponding δ-hexonolactones. The synthetized compounds were evaluated as inhibitors of phosphatase and diphosphatase activities and found to have complex concentration-dependent activatory and inhibitory properties on alkaline phosphatase. The synthetized tools should be useful to study other enzymes such as transferases.

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A novel synthetic route to obtain RUB-15 phase by pseudo solid-state conversion

Microporous and Mesoporous Materials ◽

10.1016/j.micromeso.2016.03.032 ◽

2016 ◽

Vol 228 ◽

pp. 116-122 ◽

Cited By ~ 1

Author(s):

Fethi Kooli ◽

Yan Liu ◽

Kais Hbaieb ◽

Rawan Al-Faze

Keyword(s):

Solid State ◽

Synthetic Route

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Ecofriendly and Simplified Synthetic Route for Polysulfone-based Solid-State Alkaline Electrolyte Membrane

American Journal of Applied Sciences ◽

10.3844/ajassp.2012.1577.1582 ◽

2012 ◽

Vol 9 (10) ◽

pp. 1577-1582 ◽

Cited By ~ 8

Author(s):

Mohammed

Keyword(s):

Solid State ◽

Alkaline Electrolyte ◽

Synthetic Route ◽

Electrolyte Membrane

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Efficient and Eco-Friendly Synthesis of Fluorenone Azines by Using Sulphated Titania Acid Catalyst

International Letters of Chemistry Physics and Astronomy ◽

10.18052/www.scipress.com/ilcpa.58.137 ◽

2015 ◽

Vol 58 ◽

pp. 137-143 ◽

Cited By ~ 1

Author(s):

V. Arun ◽

K.R. Sankaran

Keyword(s):

Reaction Time ◽

Acid Catalyst ◽

Recyclable Catalyst ◽

Synthetic Method ◽

Synthetic Route ◽

Operating Method

Conjugated unsymmetrical azines have been synthesized in the presence of acid catalyst sulphated-titania (TiO2-SO42-) from fluorenone hydrazone with substituted aldehydes and acetophenones by using mortar and pestle. The scope of present synthetic route avoid in solvents, simple operating method and shorter reaction time. Special feature of synthetic method is recyclable catalyst for all in reactions.

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