Design of naturally derived lead phytate as an electrocatalyst for highly efficient CO2 reduction to formic acid

2018 ◽  
Vol 20 (20) ◽  
pp. 4602-4606 ◽  
Author(s):  
Haoran Wu ◽  
Jinliang Song ◽  
Chao Xie ◽  
Yue Hu ◽  
Jun Ma ◽  
...  
Keyword(s):  
Formic Acid ◽  
Electrochemical Reduction ◽  
Phytic Acid ◽  
Co2 Reduction ◽  
Highly Efficient ◽  
Naturally Occurring

Lead phytate (Pb-PhyA) derived from naturally occurring phytic acid showed highly efficient activity in the electrochemical reduction of CO2 to formic acid.

Mo–Bi–Cd Ternary Metal Chalcogenides: Highly Efficient Photocatalyst for CO2 Reduction to Formic Acid Under Visible Light

2018 ◽  
Vol 6 (5) ◽  
pp. 5754-5759 ◽  
Author(s):  
Baowen Zhou ◽  
Jinliang Song ◽  
Chao Xie ◽  
Chunjun Chen ◽  
Qingli Qian ◽  
...  
Keyword(s):  
Formic Acid ◽  
Visible Light ◽  
Co2 Reduction ◽  
Metal Chalcogenides ◽  
Highly Efficient ◽  
Ternary Metal

scholarly journals Highly efficient, selective, and durable photocatalytic system for CO2 reduction to formic acid

2015 ◽  
Vol 6 (12) ◽  
pp. 7213-7221 ◽  
Author(s):  
Yusuke Tamaki ◽  
Kazuhide Koike ◽  
Osamu Ishitani
Keyword(s):  
Formic Acid ◽  
High Efficiency ◽  
Co2 Reduction ◽  
Photocatalytic Reduction ◽  
Highly Efficient ◽  
Photocatalytic System

Photocatalytic reduction of CO2 to formic acid with high efficiency, durability, and rate.

scholarly journals Highly efficient and autocatalytic H2O dissociation for CO2 reduction into formic acid with zinc

2014 ◽  
Vol 4 (1) ◽  
Author(s):  
Fangming Jin ◽  
Xu Zeng ◽  
Jianke Liu ◽  
Yujia Jin ◽  
Lunying Wang ◽  
...  
Keyword(s):  
Formic Acid ◽  
Co2 Reduction ◽  
Highly Efficient

Highly Efficient Electrochemical Reduction of Carbon Dioxide to Formate on Sn Modified Bi2O3 Heterostructure

2021 ◽  
Author(s):  
Doufeng Wu ◽  
Pengzuo Chen ◽  
Dongmei Feng ◽  
Jiajia Song ◽  
Yun Tong
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Co2 Reduction ◽  
Highly Efficient ◽  
Electrocatalytic Performance

In this work, the Sn species are deposited onto the surface of Bi2O3 material by a facile disproportionated reaction and the prepared catalyst shows superior electrocatalytic performance for CO2 reduction....

Highly efficient electrochemical reduction of CO2 into formic acid over lead dioxide in an ionic liquid–catholyte mixture

2018 ◽  
Vol 20 (8) ◽  
pp. 1765-1769 ◽  
Author(s):  
Haoran Wu ◽  
Jinliang Song ◽  
Chao Xie ◽  
Yue Hu ◽  
Buxing Han
Keyword(s):  
Ionic Liquid ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Lead Dioxide ◽  
Highly Efficient ◽  
Reduction Of Co2

The combination of commercial lead dioxide and ionic liquid based catholytes showed highly efficient electrochemical reduction of CO2 into formic acid.

In/ZnO@C hollow nanocubes for efficient electrochemical reduction of CO2 to formate and rechargeable Zn-CO2 batteries

2021 ◽  
Author(s):  
Xue Teng ◽  
Yanli Niu ◽  
Shuaiqi Gong ◽  
Mingze Xu ◽  
Xuan Liu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Electrochemical Reduction ◽  
Current Density ◽  
Co2 Reduction ◽  
Reduction Of Co2 ◽  
Poor Stability

Indium (In)-based materials are considered promising electrocatalysts for CO2 reduction to formic acid, but their performances are usually limited by low current density and poor stability. Here, we describe In/ZnO@C...

scholarly journals The inchoate horizon of electrolyzer designs, membranes and catalysts towards highly efficient electrochemical reduction of CO2 to formic acid

RSC Advances ◽  
2022 ◽  
Vol 12 (3) ◽  
pp. 1287-1309
Author(s):  
P. Senthilkumar ◽  
Mamata Mohapatra ◽  
Suddhasatwa Basu
Keyword(s):  
Formic Acid ◽  
Electrochemical Reduction ◽  
Energy Efficient ◽  
Highly Efficient ◽  
Recent Advances ◽  
Reduction Of Co2

This review explores the recent advances in CO2 reactor configurations, components, membranes and electrocatalysts for HCOOH generation and draw readers attention to construct the economic, scalable and energy efficient CO2R electrolyzers.

Photochemical and Electrochemical Reduction of Carbon Dioxide Catalyzed by a Polyoxometalate-Organic Photosensitizer Complex

2018 ◽  
Author(s):  
Chandan Dey ◽  
Ronny Neumann
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Voltammetry ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Mass Spectroscopy ◽  
Photochemical Reactions ◽  
Reducing Agent ◽  
Covalent Attachment ◽  
Hybrid Complex ◽  
Open Face

<p>A manganese substituted Anderson type polyoxometalate, [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup>, tethered with an anthracene photosensitizer was prepared and used as catalyst for CO<sub>2</sub> reduction. The polyoxometalate-photosensitizer hybrid complex, obtained by covalent attachment of the sensitizer to only one face of the planar polyoxometalate, was characterized by NMR, IR and mass spectroscopy. Cyclic voltammetry measurements show a catalytic response for the reduction of carbon dioxide, thereby suggesting catalysis at the manganese site on the open face of the polyoxometalate. Controlled potentiometric electrolysis showed the reduction of CO<sub>2</sub> to CO with a TOF of ~15 sec<sup>-1</sup>. Further photochemical reactions showed that the polyoxometalate-anthracene hybrid complex was active for the reduction of CO<sub>2</sub> to yield formic acid and/or CO in varying amounts dependent on the reducing agent used. Control experiments showed that the attachment of the photosensitizer to [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup> is necessary for photocatalysis.</p><div><br></div>

Graphene Supported Tungsten Carbide as Catalyst for Electrochemical Reduction of CO2

2019 ◽  
Author(s):  
Sahithi Ananthaneni ◽  
Rees Rankin
Keyword(s):  
Tungsten Carbide ◽  
Electrochemical Reduction ◽  
Low Cost ◽  
Co2 Reduction ◽  
Platinum Group Metal ◽  
Reduction Reaction ◽  
Metal Carbides ◽  
Depth Study ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction

<div>Electrochemical reduction of CO2 to useful chemical and fuels in an energy efficient way is currently an expensive and inefficient process. Recently, low-cost transition metal-carbides (TMCs) are proven to exhibit similar electronic structure similarities to Platinum-Group-Metal (PGM) catalysts and hence can be good substitutes for some important reduction reactions. In this work, we test graphenesupported WC (Tungsten Carbide) nanocluster as an electrocatalyst for the CO2 reduction reaction. Specifically, we perform DFT studies to understand various possible reaction mechanisms and determine the lowest thermodynamic energy landscape of CO2 reduction to various products such as CO, HCOOH, CH3OH, and CH4. This in-depth study of reaction energetics could lead to improvements and develop more efficient electrocatalysts for CO2 reduction.<br></div>

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