Mesoporous silica supported cobalt catalysts for gas phase hydrogenation of nitrobenzene: role of pore structure on stable catalytic performance

2018 ◽  
Vol 42 (19) ◽  
pp. 15714-15725 ◽  
Author(s):  
Murali Kondeboina ◽  
Siva Sankar Enumula ◽  
Venkata Ramesh Babu Gurram ◽  
Jyothi Yadagiri ◽  
David Raju Burri ◽  
...  

Mesoporous silica supported Co catalysts (Co/COK-12 and Co/SBA-16) are active for hydrogenation of nitrobenzene to aniline. The support pore architecture is decisive in maintaining stable catalytic performance.

2016 ◽  
Vol 40 (5) ◽  
pp. 4325-4334 ◽  
Author(s):  
Estelle Juère ◽  
Justyna Florek ◽  
Dominic Larivière ◽  
Kyoungsoo Kim ◽  
Freddy Kleitz

The work aims at exploring the role of pore structure, texture and morphology of various DGA-functionalized mesoporous silica materials on their rare earth element (REE) adsorption performances, both in batch and flow-through systems.


2009 ◽  
Vol 52 (13-20) ◽  
pp. 1826-1831 ◽  
Author(s):  
G. Di Carlo ◽  
L. F. Liotta ◽  
G. Pantaleo ◽  
A. M. Venezia ◽  
G. Deganello

ACS Nano ◽  
2010 ◽  
Vol 4 (3) ◽  
pp. 1759-1767 ◽  
Author(s):  
Nan Li ◽  
Xiaoming Wang ◽  
Salim Derrouiche ◽  
Gary L. Haller ◽  
Lisa D. Pfefferle

Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 736
Author(s):  
Xianchi Lei ◽  
Guoding Gu ◽  
Yafei Hu ◽  
Haoshang Wang ◽  
Zhaoxia Zhang ◽  
...  

Ethylene glycol is regarded as a promising C2 platform molecule due to the fast development of its production from sustainable biomass. This study inquired the structural requirements of Co-based catalysts for the liquid-phase ammonolysis of ethylene glycol to value-added ethanolamine. We showed that the rate and selectivity of ethylene glycol ammonolysis on γ-Al2O3-supported Co catalysts were strongly affected by the metal particle size within the range of 2–10 nm, among which Co nanoparticles of ~4 nm exhibited both the highest ethanolamine selectivity and the highest ammonolysis rate based on the total Co content. Doping of a moderate amount of Ag further promoted the catalytic activity without affecting the selectivity. Combined kinetic and infrared spectroscopic assessments unveiled that the addition of Ag significantly destabilized the adsorbed NH3 on the Co surface, which would otherwise be strongly bound to the active sites and inhibit the rate-determining dehydrogenation step of ethylene glycol.


ChemCatChem ◽  
2017 ◽  
Vol 9 (5) ◽  
pp. 782-797 ◽  
Author(s):  
Sylwia Turczyniak ◽  
Magdalena Greluk ◽  
Grzegorz Słowik ◽  
Wojciech Gac ◽  
Spyridon Zafeiratos ◽  
...  

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