Three-dimensionally ordered mesoporous multicomponent (Ni, Mo) metal oxide/N-doped carbon composite with superior Li-ion storage performance

Nanoscale ◽  
2018 ◽  
Vol 10 (39) ◽  
pp. 18734-18741 ◽  
Author(s):  
Se Hwan Oh ◽  
Jin Koo Kim ◽  
Yun Chan Kang ◽  
Jung Sang Cho

A simple preparation method of mesoporous multicomponent metal oxides containing Ni and Mo components with N-doped carbon by spray pyrolysis process is introduced.

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4349
Author(s):  
Anupriya K. Haridas ◽  
Natarajan Angulakshmi ◽  
Arul Manuel Stephan ◽  
Younki Lee ◽  
Jou-Hyeon Ahn

Sodium-ion batteries (SIBs) are promising alternatives to lithium-based energy storage devices for large-scale applications, but conventional lithium-ion battery anode materials do not provide adequate reversible Na-ion storage. In contrast, conversion-based transition metal sulfides have high theoretical capacities and are suitable anode materials for SIBs. Iron sulfide (FeS) is environmentally benign and inexpensive but suffers from low conductivity and sluggish Na-ion diffusion kinetics. In addition, significant volume changes during the sodiation of FeS destroy the electrode structure and shorten the cycle life. Herein, we report the rational design of the FeS/carbon composite, specifically FeS encapsulated within a hierarchically ordered mesoporous carbon prepared via nanocasting using a SBA-15 template with stable cycle life. We evaluated the Na-ion storage properties and found that the parallel 2D mesoporous channels in the resultant FeS/carbon composite enhanced the conductivity, buffered the volume changes, and prevented unwanted side reactions. Further, high-rate Na-ion storage (363.4 mAh g−1 after 500 cycles at 2 A g−1, 132.5 mAh g−1 at 20 A g−1) was achieved, better than that of the bare FeS electrode, indicating the benefit of structural confinement for rapid ion transfer, and demonstrating the excellent electrochemical performance of this anode material at high rates.


2019 ◽  
Vol 6 (5) ◽  
pp. 1475-1484 ◽  
Author(s):  
Mei Wang ◽  
Yunhua H. Xu ◽  
Fei Lu ◽  
Zhian Zhu ◽  
Jinyang Y. Dong ◽  
...  

2018 ◽  
Vol 42 (9) ◽  
pp. 6626-6630 ◽  
Author(s):  
Ye Yuan ◽  
Bo Wang ◽  
Rensheng Song ◽  
Fei Wang ◽  
Hao Luo ◽  
...  

A LiFePO4/Li2Sn hybrid system was designed using a LiFePO4 cathode and a Li2Sn-added electrolyte to improve the Li-ion storage performance.


CrystEngComm ◽  
2019 ◽  
Vol 21 (12) ◽  
pp. 1862-1866 ◽  
Author(s):  
Hai-Yang Wu ◽  
Min Huang ◽  
Chao Qin ◽  
Xin-Long Wang ◽  
Hai Hu ◽  
...  

Three polyoxometalates have been synthesized to be utilized as anode materials for lithium ion batteries.


2020 ◽  
Vol 461 ◽  
pp. 228129 ◽  
Author(s):  
Jun Wang ◽  
Jinke Li ◽  
Xin He ◽  
Xiaofei Zhang ◽  
Bo Yan ◽  
...  

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