Observation and implication of halide exchange beyond CsPbX3 perovskite nanocrystals

Nanoscale ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 3123-3128 ◽  
Author(s):  
Chao Jia ◽  
Hui Li ◽  
Longfei Tan ◽  
Xianwei Meng ◽  
Jianbo Gao ◽  
...  

Internanocrystal halide exchange between CsPbX3 perovskite nanocrystals and cesium based non-perovskite nanocrystals has been studied for the first time.

2018 ◽  
Vol 54 (49) ◽  
pp. 6300-6303 ◽  
Author(s):  
Chao Jia ◽  
Hui Li ◽  
Xianwei Meng ◽  
Hongbo Li

The synthesis of 3D/0D core/shell lead halide perovskite nanocrystals has been realized using the seeded growth approach for the first time.


2014 ◽  
Vol 50 (45) ◽  
pp. 6027-6030 ◽  
Author(s):  
Simin Yin ◽  
He Tian ◽  
Zhaohui Ren ◽  
Xiao Wei ◽  
Chunying Chao ◽  
...  

Octahedral-shaped perovskite PbTiO3 nanocrystals have been hydrothermally synthesized for the first time by the introduction of lithium nitride, demonstrating remarkable visible-light potocatalytic activity in the degradation of MB aqueous solution.


Nanoscale ◽  
2019 ◽  
Vol 11 (26) ◽  
pp. 12465-12470 ◽  
Author(s):  
Su Zhou ◽  
Yiwen Zhu ◽  
Jiasong Zhong ◽  
Feifan Tian ◽  
Hai Huang ◽  
...  

Chlorine-promoted doping of Mn(ii) in CsPbCl3 perovskites is achieved by employing manganese acetate as a Mn(ii) precursor for the first time.


2017 ◽  
Vol 29 (29) ◽  
pp. 1700095 ◽  
Author(s):  
Guangguang Huang ◽  
Chunlei Wang ◽  
Shuhong Xu ◽  
Shenfei Zong ◽  
Ju Lu ◽  
...  

Author(s):  
Tae Wook Kang ◽  
Young Ji Park ◽  
Gyu Jin Jeong ◽  
Jonghee Hwang ◽  
Jin Ho Kim ◽  
...  

Herein, we demonstrate the synthesis of green-emitting Cs4PbBr6 perovskite nanocrystals by the WASSR method for the first time.


2021 ◽  
Vol 5 (1) ◽  
pp. 3-10
Author(s):  
Guo-Bin Huang ◽  
Zhi-Yong Guo ◽  
Ting-Xiu Ye ◽  
Chen Zhang ◽  
Yan-Mei Zhou ◽  
...  

AbstractCubic phase CsPbBr3 perovskite nanocrystals (PNCs) was prepared by a high-temperature hot-injection method. The high photoluminescence quantum yield (PLQY) of as-prepared CsPbBr3 PNCs was 87%, which can be used for the determination of chloridion in domestic water samples based on their wavelength-shift characteristics via halide exchange. The proposal approach for the determination of chloridion reveals a linear correlation ranged from 10 to 200 μM of the chloridion concentration and the wavelength shift of CsPbBr3 PNCs with a correlation coefficient of R2 = 0.9956. The as-mentioned method reveals neglectable responses towards those co-existing ions in the water aside from chloridion, due to the quick exchange between Cl and Br and the outstanding color change caused by wavelength shift. The strategy has been applied to the determination of chloridion in water samples with the recoveries of 98.9–104.2% and the limit of detection (LOD) of 4 μM. These results show that the suggested approach is promising for the development of novel fluorescence detection for chloridion in water.


Nanoscale ◽  
2018 ◽  
Vol 10 (35) ◽  
pp. 16919-16927 ◽  
Author(s):  
Md Aslam Uddin ◽  
Rosemary L. Calabro ◽  
Doo-Young Kim ◽  
Kenneth R. Graham

Alkyltrichlorosilanes are demonstrated as efficient Cl-sources for rapid halide exchange with host CsPbBr3 nanocrystals. The resulting CsPbCl3 nanocrystals are encased in protective siloxane shells and are highly stable.


2018 ◽  
Vol 8 (16) ◽  
pp. 4257-4263 ◽  
Author(s):  
Wen-Bin Wu ◽  
Ying-Chieh Wong ◽  
Zhi-Kuang Tan ◽  
Jie Wu

Cesium lead halide perovskite nanocrystals have been the first time utilized as photocatalysts for organic bond formations.


2018 ◽  
Vol 6 (33) ◽  
pp. 8990-8998 ◽  
Author(s):  
Daqin Chen ◽  
Gaoliang Fang ◽  
Xiao Chen ◽  
Lei Lei ◽  
Jiasong Zhong ◽  
...  

Solvothermal synthesis of Mn-doped CsPbCl3 nanocrystals with dual-color luminescence and superior stability was reported for the first time.


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