Photoresponsive supramolecular polymers based on quadruple hydrogen-bonding and a photochromic azobenzene motif

2018 ◽  
Vol 9 (44) ◽  
pp. 5395-5401 ◽  
Author(s):  
Shaobo Tan ◽  
Ye Sha ◽  
Tianyu Zhu ◽  
Md Anisur Rahman ◽  
Chuanbing Tang

A photoresponsive quadruple hydrogen-bonded supramolecular polymer was constructed using photochromic azobenzene and ureidopyrimidinone motifs.

RSC Advances ◽  
2019 ◽  
Vol 9 (16) ◽  
pp. 8905-8911 ◽  
Author(s):  
Lei Kan ◽  
Peng Zhang ◽  
Hongkun Jiang ◽  
Shuai Zhang ◽  
Zhengdao Liu ◽  
...  

The supramolecular polymers based on 2-ureido-4[1H]-pyrimidone (UPy) with different structure were prepared and the effects of microtopography on the viscoelasticity were investigated.


2018 ◽  
Vol 47 (40) ◽  
pp. 14195-14203 ◽  
Author(s):  
Shota Oka ◽  
Hiroaki Ozawa ◽  
Kai Yoshikawa ◽  
Tomiki Ikeda ◽  
Masa-aki Haga

Selective extraction of semiconducting SWNT via entangled surface modification by H-bonded metallo-supramolecular polymer was achieved.


2004 ◽  
Vol 76 (7-8) ◽  
pp. 1345-1351 ◽  
Author(s):  
M.-Č. Perron ◽  
F. Monchamp ◽  
Hugues Duval ◽  
Danielle Boils-Boissier ◽  
J. D. Wuest

Studies of how hydrogen bonding can be used to control molecular association continue to yield exciting discoveries in supramolecular chemistry. A simple way to make molecules that associate predictably is to link carefully selected cores to functional groups that form multiple hydrogen bonds according to reliable patterns. Bifunctional molecules constructed according to this strategy can associate to form linear aggregates robust enough to warrant the name supramolecular polymers, even though the bifunctional monomers are joined only by hydrogen bonds. More complex molecules with multiple hydrogen-bonding sites can be devised so that neighbors are held in predetermined positions, giving crystalline solids with predictable architectures and properties not previously seen in other materials. Initial studies of the ability of such compounds to associate in solution and in the molten state suggest that hydrogen-bonded networks can be purposefully designed to create novel par- tially ordered liquid materials, including liquid crystals, gels, and fluids with unusual rheological properties.


2007 ◽  
Vol 45 (23) ◽  
pp. 3181-3188 ◽  
Author(s):  
Kyung Ju Lee ◽  
Yong Woo Kim ◽  
Joo Hwan Koh ◽  
Jong Hak Kim

2016 ◽  
Vol 52 (39) ◽  
pp. 6597-6600 ◽  
Author(s):  
Xue Huang ◽  
Yan-Chao Zhao ◽  
Bao-Hang Han

A rigid triptycene derivative with three 2-ureido-4[1H]-pyrimidinone (UPy) terminals was employed to construct a supramolecular hydrogen-bonded organic polymer (HOP-1).


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