scholarly journals Synthesis of a surface mounted metal–organic framework on gold using a Au–carbene self-assembled monolayer linkage

2019 ◽  
Vol 3 (4) ◽  
pp. 636-639 ◽  
Author(s):  
Esther Frederick ◽  
Travis W. Shaw ◽  
Matthew G. Frith ◽  
Steven L. Bernasek
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Self Assembled Monolayers ◽  
Self Assembled Monolayer ◽  
Stable Surface ◽  
Gold Substrates ◽  
Assembled Monolayers ◽  
Metal Organic ◽  
Self Assembled ◽  
Organic Framework

Carbene based self-assembled monolayers are demonstrated to be effective supports for forming highly stable surface-mounted metal–organic frameworks on gold substrates.

Coating a DNA self-assembled monolayer with a metal organic framework-based exoskeleton for improved sensing performance

The Analyst ◽  
2019 ◽  
Vol 144 (11) ◽  
pp. 3539-3545 ◽  
Author(s):  
Jiehua Ma ◽  
Wenxin Chai ◽  
Jianyang Lu ◽  
Tian Tian ◽  
Shuai Wu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Self Assembled Monolayers ◽  
Self Assembled Monolayer ◽  
New Strategy ◽  
Assembled Monolayers ◽  
Metal Organic ◽  
Self Assembled ◽  
Poor Stability ◽  
Sensing Performance ◽  
Organic Framework

The relatively poor stability of DNA self-assembled monolayers (SAMs) greatly limits their use in real applications. A new strategy is reported to protect the DNA SAMs by using a metal organic framework (MOF)-based exoskeleton.

scholarly journals Correction: Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer

2021 ◽  
Author(s):  
Purna Chandra Rao ◽  
Prabu Mani ◽  
Younghu Son ◽  
Jiyun Kim ◽  
Minyoung Yoon
Keyword(s):  
Guest Molecule ◽  
Metal Organic Framework ◽  
Self Assembled Monolayer ◽  
Metal Organic ◽  
Self Assembled ◽  
Organic Framework

Correction for ‘Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer’ by Purna Chandra Rao et al., Chem. Commun., 2021, DOI: 10.1039/d1cc03721h.

scholarly journals Implementing chemical functionality into oriented films of metal–organic frameworks on self-assembled monolayers

2011 ◽  
Vol 21 (38) ◽  
pp. 14849 ◽  
Author(s):  
Camilla Scherb ◽  
Jennifer J. Williams ◽  
Florian Hinterholzinger ◽  
Sebastian Bauer ◽  
Norbert Stock ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Self Assembled Monolayers ◽  
Oriented Films ◽  
Chemical Functionality ◽  
Assembled Monolayers ◽  
Metal Organic ◽  
Self Assembled

scholarly journals Helically structured metal–organic frameworks fabricated by using supramolecular assemblies as templates

2015 ◽  
Vol 6 (3) ◽  
pp. 1910-1916 ◽  
Author(s):  
Hui Wang ◽  
Wei Zhu ◽  
Jian Li ◽  
Tian Tian ◽  
Yue Lan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Supramolecular Assemblies ◽  
Metal Organic ◽  
Self Assembled ◽  
Organic Framework

Here we report on the use of a self-assembled organic object to template the first example of a nanoscale metal–organic framework (MOF) with a helical morphology.

Lysozyme-mediated fabrication of well-defined core–shell nanoparticle@metal–organic framework nanocomposites

2017 ◽  
Vol 5 (39) ◽  
pp. 20765-20770 ◽  
Author(s):  
Ke Wang ◽  
Nan Li ◽  
Xiaoman Hai ◽  
Fuquan Dang
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Core Shell ◽  
Metal Organic ◽  
Self Assembled ◽  
Organic Framework

We report a versatile strategy based on self-assembled lysozymes (LYZs) to prepare core–shell nanocomposites with nanoparticles (NPs) in metal–organic frameworks (MOFs).

scholarly journals The oriented and patterned growth of fluorescent metal–organic frameworks onto functionalized surfaces

2012 ◽  
Vol 3 ◽  
pp. 570-578 ◽  
Author(s):  
Jinliang Zhuang ◽  
Jasmin Friedel ◽  
Andreas Terfort
Keyword(s):  
Functional Groups ◽  
Microcontact Printing ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Self Assembled Monolayers ◽  
Patterned Growth ◽  
Functionalized Surfaces ◽  
Assembled Monolayers ◽  
Metal Organic ◽  
Different Shapes

A metal–organic framework (MOF) material, [Zn2(adc)2(dabco)] (adc = anthracene-9,10-dicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]­octane), the fluorescence of which depends on the loading of its nanopores, was synthesized in two forms: as free-flowing nanocrystals with different shapes and as surface-attached MOFs (SURMOFs). For the latter, we used self-assembled monolayers (SAMs) bearing functional groups, such as carboxylate and pyridyl groups, capable of coordinating to the constituents of the MOF. It could be demonstrated that this directed coordination also orients the nanocrystals deposited at the surface. Using two different patterning methods, i.e., microcontact printing and electron-beam lithography, the lateral distribution of the functional groups could be determined in such a way that the highly localized deposition of the SURMOF films became possible.

CURRENT-VOLTAGE CHARACTERIZATION OF ALKANETHIOL SELF-ASSEMBLED MONOLAYERS IN METAL NANOWIRES

2002 ◽  
Vol 16 (05n06) ◽  
pp. 161-169 ◽  
Author(s):  
IRENA KRATOCHVÍLOVÁ ◽  
ADRIANA ZAMBOVA ◽  
JEREMIAH MBINDYO ◽  
BAHARAK RAZAVI ◽  
JOSEF HOLAKOVSKÝ
Keyword(s):  
Electrical Characterization ◽  
Self Assembled Monolayers ◽  
Metal Nanowires ◽  
Published Data ◽  
Self Assembled Monolayer ◽  
Current Voltage ◽  
Assembled Monolayers ◽  
Metal Organic ◽  
Self Assembled

An electric-field assisted assembly has been used to place rod-shaped, metal-organic, molecule-metal nanowires onto lithographically defined metal pads allowing the electrical characterization of metal-molecule self-assembled monolayer-metal containing nanowires. Our results show that the parameters of metal-molecule metal junctions are close to previously published data, so we have constructed systems containing insulating monolayers with reasonable properties.

An Organic Guest Molecule Induced Ultrafast Breathing of Epitaxially Grown Metal-Organic Framework on Self-Assembled Monolayer

2021 ◽  
Author(s):  
Purna Chandra Rao ◽  
Mani Prabu ◽  
Younghu Son ◽  
Jiyun Kim ◽  
Minyoung Yoon
Keyword(s):  
Thin Films ◽  
Guest Molecule ◽  
Metal Organic Framework ◽  
Layer By Layer ◽  
Epitaxial Thin Films ◽  
Two Dimensional ◽  
Self Assembled Monolayer ◽  
Metal Organic ◽  
Self Assembled ◽  
Organic Framework

We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using the stepwise layer-by-layer seeding followed by solvothermal treatment. The...

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