scholarly journals Crystallographic characterization of Lu2C2n (2n = 76–90): cluster selection by cage size

2019 ◽  
Vol 10 (3) ◽  
pp. 829-836 ◽  
Author(s):  
Wangqiang Shen ◽  
Lipiao Bao ◽  
Shuaifeng Hu ◽  
Le Yang ◽  
Peng Jin ◽  
...  

Lu2C2n (2n = 76–90): the decisive size effect of the carbon cage on the configuration of the internal metallic cluster.

2015 ◽  
Vol 44 (9) ◽  
pp. 4207-4214 ◽  
Author(s):  
Jia-Jun Wang ◽  
Zhong-Jun Zhou ◽  
Yang Bai ◽  
Hui-Min He ◽  
Di Wu ◽  
...  

A new strategy of utilizing the cage size effect for simultaneously enhancing the β0 and the VIP.


2008 ◽  
Vol 130 (36) ◽  
pp. 11844-11845 ◽  
Author(s):  
Steven Stevenson ◽  
Mary A. Mackey ◽  
Melissa A. Stuart ◽  
J. Paige Phillips ◽  
Michael L. Easterling ◽  
...  

ChemInform ◽  
2006 ◽  
Vol 37 (28) ◽  
Author(s):  
Zhi-Qiang Shi ◽  
Xin Wu ◽  
Chun-Ru Wang ◽  
Xin Lu ◽  
Hisanori Shinohara

1996 ◽  
Vol 218 (1-4) ◽  
pp. 77-80 ◽  
Author(s):  
I.K. Yanson ◽  
V.V. Fisun ◽  
R. Hesper ◽  
J.M. Krans ◽  
J.A. Mydosh ◽  
...  

2004 ◽  
Vol 79 (7) ◽  
pp. 1753-1756 ◽  
Author(s):  
M.F. Zhang ◽  
J.-M. Liu ◽  
Z.G. Liu

2006 ◽  
Vol 45 (13) ◽  
pp. 2107-2111 ◽  
Author(s):  
Zhi-Qiang Shi ◽  
Xin Wu ◽  
Chun-Ru Wang ◽  
Xin Lu ◽  
Hisanori Shinohara

Author(s):  
Rachid Chaouadi ◽  
Marlies Lambrecht ◽  
Robert Gérard

The use of miniature compact tension (mini-CT) specimens for fracture mechanics was experimentally demonstrated to allow the characterization of ferritic steels in the transition regime. In particular, the master curve transition temperature T0 can confidently be determined according to the ASTM E1921 standard using mini-CT specimens. This means that specimen size effect is well taken into account if loss of constraint is limited by restricting the test temperature range to remain below the allowed maximum loading level. In the upper shelf ductile regime, where stable crack growth occurs, a number of challenges should be overcome to use such a geometry to derive the crack resistance curve, or JR-curve, transferrable to a structure. Indeed, despite a large scatter, the experimental data on several materials suggest a size effect that underestimates the crack resistance when reducing specimen size. The crack resistance behavior of several reactor pressure vessel materials was investigated with square-sized ligament compact tension specimens of various size ranging from 1 inch-thickness (B = 25 mm) to the smallest thickness (B = 4.2 mm) of the mini-CT. The main objective of this paper is to estimate the crack resistance behavior of RPV steels that would be obtained with a standard 1T-CT specimen by using mini-CT with the appropriate specimen size correction. After a series of scaling attempts that were not successful, based on a simple dimensional analysis, a simple analytical formulation based on specimen thickness and ligament is suggested to account for specimen size effect for the CT geometry. Reasonable agreement could generally be found on a number of RPV materials between crack resistance measured with mini-CT and standard 1T-CT specimens.


2013 ◽  
Vol 586 ◽  
pp. 23-26 ◽  
Author(s):  
Annamária Duszová ◽  
Radoslav Halgaš ◽  
Pavol Priputen ◽  
Marek Bľanda ◽  
Pavol Hvizdoš ◽  
...  

The nanohardness of WC – Co hardmetals has been investigated using instrumented indentation and Berkovich tip indenter. The nanohardness, HIT, and indentation modulus, EIT, of Co phase and individual WC grains and the influence of their crystalographic orientation have been studied. SEM, AFM and EBSD methods were used for the characterization of the microstructures and indents and for the identification of crystallographic orientation of WC grains, respectively. Strong indentation load-size effect and significant influence of the crystallographic orientation of WC crystals on HIT and EIT have been found. The nanohardness of Co binder was approximately 10 GPa and that of WC grains varied between 25 and 50 GPa, depending on the grain orientation and load. The nanohardness values of the basal and prismatic planes of individual WC grains at load of 10 mN were 40.4 ± 1.6 GPa and 32.8 ± 2.0 GPa, respectively.


2021 ◽  
Author(s):  
Xinye Liu ◽  
Bo Li ◽  
Wei Yang ◽  
Yang-Rong Yao ◽  
Le Yang ◽  
...  

Photochemical reaction of Th@C3v(8)-C82 and U@C2v(9)-C82 with 2-adamantane-2,3′-[3H]-diazirine (AdN2, 1) afforded three isomers of Th@C3v(8)-C82Ad and four isomers of U@C2v(9)-C82Ad (Ad = adamantylidene), respectively.


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