scholarly journals Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

2019 ◽  
Vol 10 (11) ◽  
pp. 3295-3299 ◽  
Author(s):  
Rubén Sáez ◽  
Ciaran McArdle ◽  
Fouad Salhi ◽  
Jordi Marquet ◽  
Rosa M. Sebastián
Keyword(s):  
Block Copolymers ◽  
Anionic Polymerization ◽  
Living Anionic Polymerization ◽  
Frustrated Lewis Pair ◽  
Hb C

Controlled living anionic polymerization of cyanoacrylates promoted by a hydrogenated frustrated Lewis pair ([TMPH+][HB(C6F5)3−]). Preparation of designed block copolymers.

scholarly journals A controlled synthesis method of alkyl methacrylate block copolymers via living anionic polymerization at ambient temperature

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16049-16056 ◽  
Author(s):  
Zheng Li ◽  
Jianding Chen ◽  
Guijin Zou ◽  
Tongyuan Zhang ◽  
Dafu Wei ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ambient Temperature ◽  
Anionic Polymerization ◽  
Diblock Copolymers ◽  
Synthesis Method ◽  
Controlled Synthesis ◽  
Living Anionic Polymerization ◽  
Alkyl Methacrylate ◽  
High Yields

A series of well-defined diblock copolymers containing PMMA, PEMA and PBMA blocks were synthesized with narrow MWDs and high yields via anionic polymerization, while t-BuOK was selected as initiator in THF at 0 °C. .

Recent Advances in Thermoplastic Elastomer Synthesis

1991 ◽  
Vol 64 (3) ◽  
pp. 450-468 ◽  
Author(s):  
Roderic P. Quirk ◽  
Jungahn Kim
Keyword(s):  
Block Copolymers ◽  
Anionic Polymerization ◽  
Structural Control ◽  
Thermoplastic Elastomer ◽  
Living Polymerization ◽  
Controlled Synthesis ◽  
Living Anionic Polymerization ◽  
Recent Advances ◽  
Living Polymerizations

Abstract A variety of living polymerization systems are now available for the controlled synthesis of block copolymers. Although living anionic polymerization remains as the method of choice for the most precise structural control, living polymerizations proceeding via other mechanistic types provide extremely useful extensions of this methodology to a wider variety of monomers.

Living anionic polymerization of 2-vinyldibenzothiophene: Homopolymer and block copolymers with styrene

2007 ◽  
Vol 45 (10) ◽  
pp. 1993-2003 ◽  
Author(s):  
A. Avila-Ortega ◽  
H. Vázquez-Torres
Keyword(s):  
Block Copolymers ◽  
Anionic Polymerization ◽  
Living Anionic Polymerization

scholarly journals Phosphonium-containing diblock copolymers from living anionic polymerization of 4-diphenylphosphino styrene

2016 ◽  
Vol 52 (5) ◽  
pp. 950-953 ◽  
Author(s):  
Alison R. Schultz ◽  
Gregory B. Fahs ◽  
Chainika Jangu ◽  
Mingtao Chen ◽  
Robert B. Moore ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Anionic Polymerization ◽  
Diblock Copolymers ◽  
Living Anionic Polymerization ◽  
Molecular Weights

Living anionic polymerization of 4-diphenylphosphino styrene (DPPS) achieved well-defined homopolymers, poly(DPPS-b-S) styrenic block copolymers, and poly(I-b-DPPS) diene-based diblock copolymers with predictable molecular weights and narrow polydispersities.

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